Cyclohexenone derivatives and their use as herbicides
    1.
    发明授权
    Cyclohexenone derivatives and their use as herbicides 失效
    环己烯酮衍生物及其作为除草剂的用途

    公开(公告)号:US5034047A

    公开(公告)日:1991-07-23

    申请号:US572357

    申请日:1990-08-24

    摘要: Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 : hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl or substituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 : hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A: a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m: 0 or 1;B: a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom; substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n: 1, 2 or 3;Y: not denoting hydrogen when m is O, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.

    摘要翻译: 通式I的环己烯酮衍生物,其中取代基具有以下含义:R 1:取代或未取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,苯基,苄基或异丁基; R2:取代或未取代的C1-C6-烯基,C3-C6-烯基,C3-C6-炔基或苯基; R3:氢,C1-C6-烷基,C1-C10-烷基羰基,C1-C6-烷基磺酰基,C1-C4-三烷基甲硅烷基,C1-C4-二烷基膦酰基,C1-C4-二烷基硫代膦酰基,C3-C6-烯基,C3-C6- 烯基羰基,C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R4:氢,氰基,卤素,C1-C6-烷基或C1-C6-烷氧基羰基; A:取代或未取代的亚甲基可被氧或硫原子代替的C 1 -C 4 - 亚烷基链; m:0或1; B:含有至多2个氮原子和/或至多一个氧或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n:1,2或3; Y:当m为O时不表示氢,B为异唑-5-基,X为3-(C 3 -C 6环烷基),其环保可接受的盐,其制备方法及其作为除草剂的用途。

    Herbicidal tetrahydropyran-2,4-diones
    5.
    发明授权
    Herbicidal tetrahydropyran-2,4-diones 失效
    除草四氢吡喃-2,4-二酮

    公开(公告)号:US5389602A

    公开(公告)日:1995-02-14

    申请号:US76687

    申请日:1993-06-15

    摘要: Tetrahydropyran-2,4-diones of the formula ##STR1## where R.sup.1 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; substituted or unsubstituted phenyl; C.sub.1 -C.sub.6 -alkylsulfonyl; substituted or unsubstituted benzenesulfonyl; C.sub.3 -C.sub.6 -alkenylcarbonyl; or substituted or unsubstituted benzoyl;R.sup.2 is C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -haloalkyl; or C.sub.3 -C.sub.6 -cycloalkyl;A, B and D are each .dbd.CH-- or .dbd.N--;E is oxygen, sulfur or --NR.sup.7 --.R.sup.7 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkanoyl; substituted or unsubstituted benzoyl; benzyl; or substituted or unsubstituted phenyl;X is halogen; C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.3 -C.sub.6 -cycloalkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -alkoxy; C.sub.2 -C.sub.6 -alkenyloxy; C.sub.1 -C.sub.6 -alkylthio; C.sub.1 -C.sub.6 -alkoxycarbonyl; C.sub.2 -C.sub.6 -alkanoyloxy; substituted or unsubstituted benzyloxy; substituted or unsubstituted NR.sup.5 R.sup.6 ; formyl; C.sub.2 -C.sub.6 -alkanoyl or its imine, oxime or Schiff's base; or substituted or unsubstituted phenyl;n is 0, 1 or 2;R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, phenyl, C.sub.2 -C.sub.6 -alkanoyl, benzoyl and/or benzyl;Z is oxygen or --NOR.sup.8 ; andR.sup.8 is substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.2 -C.sub.6 -haloalkynyl; or substituted or unsubstituted thenyl;their environmentally compatible salts, and agents containing them.

    摘要翻译: 其中R 1是氢的式(VI)的四氢吡喃-2,4-二酮: C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C2-C6-炔基; 取代或未取代的苯基; C 1 -C 6烷基磺酰基; 取代或未取代的苯磺酰基; C 3 -C 6 - 烯基羰基; 或取代或未取代的苯甲酰基; R2是C1-C6-烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C 1 -C 6 - 卤代烷基; 或C 3 -C 6 - 环烷基; A,B和D各自为= CH-或= N-; E是氧,硫或-NR7-。 R7是氢; C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C 2 -C 6烷酰基; 取代或未取代的苯甲酰基; 苄基; 或取代或未取代的苯基; X是卤素; C 1 -C 6 - 烷基; 取代或未取代的C 3 -C 6 - 环烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C1-C6-烷氧基; C 2 -C 6 - 烯氧基; C1-C6-烷硫基; C1-C6烷氧基羰基; C2-C6-烷酰氧基; 取代或未取代的苄氧基; 取代或未取代的NR5R6; 甲酰基 C2-C6-烷酰基或其亚胺,肟或席夫碱; 或取代或未取代的苯基; n为0,1或2; R 3,R 4,R 5和R 6各自为氢,C 1 -C 6 - 烷基,苯基,C 2 -C 6 - 烷酰基,苯甲酰基和/或苄基; Z是氧或-NOR8; 且R 8为取代或未取代的C 1 -C 6 - 烷基; C 2 -C 6 - 烯基; C2-C6-炔基; C 2 -C 6 - 卤代炔基; 或取代或未取代的噻吩基; 它们与环境相容的盐和含有它们的试剂。

    Cyclohexenone compounds, their preparation and their use for controlling
undesirable plant growth
    6.
    发明授权
    Cyclohexenone compounds, their preparation and their use for controlling undesirable plant growth 失效
    环己烯酮化合物,它们的制备及其用于控制​​不期望的植物生长的用途

    公开(公告)号:US4994106A

    公开(公告)日:1991-02-19

    申请号:US321063

    申请日:1989-03-09

    摘要: Cyclohexenone compounds of the formula I ##STR1## where the substituents have the following meanings: R.sup.1 is C.sub.3 -C.sub.4 -alkenyl, C.sub.3 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkenyl, C.sub.2 -C.sub.4 -alkoxyalkyl or a radical CH.sub.2 --R.sup.3, whereR.sup.3 is a 5 ring heterocycle with one to three nitrogen atoms and/or one to two oxygen atoms and/or one sulfur atom as hetero-atoms, which may bear up to two double bonds and one or two of the following substituents: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, halogen, trifluoromethyl, C.sub.1 -C.sub.4 -alkoxymethyl, C.sub.1 -C.sub.4 -alkylthiomethyl and/or vinyl, or phenyl which may bear one to three of the following groups: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, halogen, trifluoromethyl, nitro and/or C.sub.1 -C.sub.4 -dialkylamino, andR.sup.2 is C.sub.1 -C.sub.4 -alkyl,and their agriculturally acceptable salts, processes for their manufacture, and their use.

    摘要翻译: 式I的环己烯酮化合物其中取代基具有以下含义:R 1为C 3 -C 4 - 烯基,C 3 -C 4 - 炔基,C 2 -C 4 - 卤代烷基,C 2 -C 4 - 卤代烯基,C 2 -C 4 - 烷氧基烷基或 基团CH 2 -R 3,其中R 3是具有一至三个氮原子和/或一个至两个氧原子和/或一个硫原子作为杂原子的5环杂环,其可以带有多达两个双键和一个或两个 以下取代基:C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,卤素,三氟甲基,C 1 -C 4 - 烷氧基甲基,C 1 -C 4 - 烷硫基甲基和/或乙烯基,或可以具有一至三个 的C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,卤素,三氟甲基,硝基和/或C 1 -C 4 - 二烷基氨基,R 2是C 1 -C 4烷基, 盐,其制造方法及其用途。

    Cyclohexenone derivatives
    7.
    发明授权
    Cyclohexenone derivatives 失效
    环己烯酮衍生物

    公开(公告)号:US5201935A

    公开(公告)日:1993-04-13

    申请号:US934304

    申请日:1992-08-26

    摘要: Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl orsubstituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m 0 or 1;B a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom;substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl;C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n 1, 2 or 3;Y not denoting hydrogen when m is 0, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.

    摘要翻译: 通式I的环己烯酮衍生物,其中取代基具有以下含义:R 1取代或未取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,苯基,苄基或异丁基; R2取代或未取代的C1-C6-烷基,C3-C6-烯基,C3-C6-炔基或苯基; R3,C1-C6-烷基,C1-C10-烷基羰基,C1-C6-烷基磺酰基,C1-C4-三烷基甲硅烷基,C1-C4-二烷基膦酰基,C1-C4-二烷基硫代膦酰基,C3-C6-烯基,C3-C6-烯基羰基 ,C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R 4氢,氰基,卤素,C 1 -C 6 - 烷基或C 1 -C 6 - 烷氧基羰基; 取代或未取代的C1-C4亚烷基链,其中亚甲基可被氧或硫原子代替; m 0或1; B是含有至多2个氮原子和/或至多一个氧原子或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n 1,2或3; 当m为0时,Y不表示氢,B为异唑-5-基,X为3-(C 3 -C 6 - 环烷基)及其环境可接受的盐,其制备方法及其作为除草剂的用途。