公开(公告)号：US06770377B2

公开(公告)日：2004-08-03

申请号：US10170852

申请日：2002-06-12

申请人： Frank Hegner ,  Elke Maria Schmidt ,  Volker Güther ,  Anobecs Allo ,  Jürgen Breme ,  Heinz Müller ,  Jürgen Peter Turnsek

发明人： Frank Hegner ,  Elke Maria Schmidt ,  Volker Güther ,  Anobecs Allo ,  Jürgen Breme ,  Heinz Müller ,  Jürgen Peter Turnsek

IPC分类号： C22C1600

CPC分类号： B23K35/32 ,  B22F9/023 ,  C04B37/006 ,  C04B2237/122 ,  C04B2237/127 ,  C04B2237/343

摘要： The active brazing solder for brazing ceramic parts of alumina, particularly of high-purity alumina, contains a maximum of 12 wt. % Ti, a maximum of 8 wt. % Be, and less than 16.5 wt. % Fe, the remainder being Zr and any impurities that may be present. The active brazing solder has the following behaviour/features: Brazing temperature: lower than 1,000° C.; the brazed joint is high-vacuum-tight over a long period of time; the coefficient of thermal expansion of the active brazing alloy is substantially identical to that of the alumina ceramic in the entire temperature range covered during the brazing process; the strength of the brazed joint between the two ceramic parts is so high that under tensile loading, fracture will result not at the joint, but in the adjacent ceramic; the pressure resistance of the active brazing solder is greater than 2 GPa; the active brazing solder is very good processable into powders having particle sizes on the order of 10 &mgr;m.

摘要翻译： 用于钎焊氧化铝陶瓷部件，特别是高纯度氧化铝的活性钎焊焊料最多含有12wt。 ％Ti，最多8wt。 ％Be，小于16.5wt。 ％Fe，其余为Zr和可能存在的任何杂质。 活性钎焊焊料具有以下特点：钎焊温度低于1000℃。 钎焊接头长时间高真空密封; 活性钎焊合金的热膨胀系数在钎焊过程中覆盖的整个温度范围内基本上与氧化铝陶瓷的热膨胀系数相同; 两个陶瓷部件之间的钎焊接头的强度如此之高，以至于在拉伸载荷下，不会在接头处产生断裂，而是在相邻的陶瓷中产生断裂; 活性钎焊焊料的耐压大于2 GPa; 活性钎焊焊料可以非常好地加工成具有10um数量级的粒度的粉末。

公开(公告)号：US06595064B2

公开(公告)日：2003-07-22

申请号：US09863271

申请日：2001-05-24

申请人： Ulfert Drewes ,  Andreas Rossberg ,  Frank Hegner ,  Elke Maria Schmidt ,  Jürgen Breme ,  Thomas Velten

发明人： Ulfert Drewes ,  Andreas Rossberg ,  Frank Hegner ,  Elke Maria Schmidt ,  Jürgen Breme ,  Thomas Velten

IPC分类号： G01L912

CPC分类号： G01L9/0075 ,  G01L9/0048 ,  G01L9/0073

摘要： A diaphragm 30 and basic body 20 of a pressure sensor 10 are interconnected via a joint F. A groove 26 is provided in the basic body 20 in order to reduce the stress concentration in the region of the joint F.

摘要翻译： 压力传感器10的隔膜30和基体20经由接头F相互连接。在基体20中设置有槽26，以便减小接头F的区域内的应力集中。

公开(公告)号：US06039918A

公开(公告)日：2000-03-21

申请号：US896481

申请日：1997-07-18

申请人： Frank Hegner ,  Elke Maria Schmidt ,  Volker Guther ,  Andreas Otto ,  Jurgen Breme ,  Heinz Muller ,  Jurgen Peter Turnsek

发明人： Frank Hegner ,  Elke Maria Schmidt ,  Volker Guther ,  Andreas Otto ,  Jurgen Breme ,  Heinz Muller ,  Jurgen Peter Turnsek

IPC分类号： B22F9/02 ,  B23K35/32 ,  C04B37/00 ,  C22C16/00

CPC分类号： B23K35/32 ,  B22F9/023 ,  C04B37/006 ,  C04B2237/122 ,  C04B2237/127 ,  C04B2237/343

摘要： The active brazing solder for brazing ceramic parts of alumina, particularly of high-purity alumina, contains a maximum of 12 wt. % Ti, a maximum of 8 wt. % Be, and less than 16.5 wt. % Fe, the remainder being Zr and any impurities that may be present. The active brazing solder has the following behaviour/features: Brazing temperature: lower than 1,000.degree. C.; the brazed joint is high-vacuum-tight over a long period of time; the coefficient of thermal expansion of the active brazing alloy is substantially identical to that of the alumina ceramic in the entire temperature range covered during the brazing process; the strength of the brazed joint between the two ceramic parts is so high that under tensile loading, fracture will result not at the joint, but in the adjacent ceramic; the pressure resistance of the active brazing solder is greater than 2 GPa; the active brazing solder is very good processable into powders having particle sizes on the order of 10 .mu.m.

摘要翻译： 用于钎焊氧化铝陶瓷部件，特别是高纯度氧化铝的活性钎焊焊料最多含有12wt。 ％Ti，最多8wt。 ％Be，小于16.5wt。 ％Fe，其余为Zr和可能存在的任何杂质。 活性钎焊焊料具有以下特点：钎焊温度低于1000℃。 钎焊接头长时间高真空密封; 活性钎焊合金的热膨胀系数在钎焊过程中覆盖的整个温度范围内基本上与氧化铝陶瓷的热膨胀系数相同; 两个陶瓷部件之间的钎焊接头的强度如此之高，以至于在拉伸载荷下，不会在接头处产生断裂，而是在相邻的陶瓷中产生断裂; 活性钎焊焊料的耐压大于2 GPa; 活性钎焊焊料对于粒径在10微米左右的粉末是非常好的可加工性的。

公开(公告)号：US06427900B1

公开(公告)日：2002-08-06

申请号：US09455690

申请日：1999-12-07

申请人： Frank Hegner ,  Elke Maria Schmidt ,  Volker Güther ,  Andreas Otto ,  Jürgen Breme ,  Heinz Müller ,  Jürgen Peter Turnsek

发明人： Frank Hegner ,  Elke Maria Schmidt ,  Volker Güther ,  Andreas Otto ,  Jürgen Breme ,  Heinz Müller ,  Jürgen Peter Turnsek

IPC分类号： B23K3102

CPC分类号： B23K35/32 ,  B22F9/023 ,  C04B37/006 ,  C04B2237/122 ,  C04B2237/127 ,  C04B2237/343

摘要： The active brazing solder for brazing ceramic parts of alumina, particularly of high-purity alumina, contains a maximum of 12 wt. % Ti, a maximum of 8 wt. % Be, and less than 16.5 wt. % Fe, the remainder being Zr and any impurities that may be present. The active brazing solder has the following behaviour/features: Brazing temperature: lower than 1,000° C.; the brazed joint is high-vacuum-tight over a long period of time; the coefficient of thermal expansion of the active brazing alloy is substantially identical to that of the alumina ceramic in the entire temperature range covered during the brazing process; the strength of the brazed joint between the two ceramic parts is so high that under tensile loading, fracture will result not at the joint, but in the adjacent ceramic; the pressure resistance of the active brazing solder is greater than 2 GPa; the active brazing solder is very good processable into powders having particle sizes on the order of 10 &mgr;m.

摘要翻译： 用于钎焊氧化铝陶瓷部件，特别是高纯度氧化铝的活性钎焊焊料最多含有12wt。 ％Ti，最多8wt。 ％Be，小于16.5wt。 ％Fe，其余为Zr和可能存在的任何杂质。 活性钎焊焊料具有以下特点：钎焊温度低于1000℃。 钎焊接头长时间高真空密封; 活性钎焊合金的热膨胀系数在钎焊过程中覆盖的整个温度范围内基本上与氧化铝陶瓷的热膨胀系数相同; 两个陶瓷部件之间的钎焊接头的强度如此之高，以至于在拉伸载荷下，不会在接头处产生断裂，而是在相邻的陶瓷中产生断裂; 活性钎焊焊料的耐压大于2 GPa; 活性钎焊焊料可以非常好地加工成具有10um数量级的粒度的粉末。

公开(公告)号：US6156130A

公开(公告)日：2000-12-05

申请号：US385790

申请日：1999-08-30

申请人： Frank Hegner ,  Elke Maria Schmidt ,  Theophil Eicher ,  Peter Otschick ,  Winfried Schaffrath

发明人： Frank Hegner ,  Elke Maria Schmidt ,  Theophil Eicher ,  Peter Otschick ,  Winfried Schaffrath

IPC分类号： B23K35/02 ,  B23K35/14 ,  B23K35/22 ,  B23K35/32 ,  B23K35/36 ,  C04B37/00 ,  B23K35/363

CPC分类号： C04B37/026 ,  B23K35/025 ,  B23K35/22 ,  B23K35/32 ,  C04B37/006 ,  B23K35/3613 ,  C04B2237/122 ,  C04B2237/343 ,  C04B2237/40 ,  C04B2237/592 ,  C04B2237/62

摘要： These active brazing pastes satisfy the requirements for screen printing or dispensing particularly well and are well suited for brazing one aluminum oxide ceramic body to another one or to a metal body. This can be done by means of respective regions of brazing paste applied by screen printing to the ceramic bodies, with the coverage of one region matching the coverage of the other region or by inserting the metal body into a hole in the ceramic body and using a pad of brazing paste applied to the ceramic body and to the metal body by dispensing. The printable paste comprises as the active brazing material a hydrogenated powder of a Zr/Ni/Ti alloy or a Zr/Fe/Ti/Be alloy and as an organic vehicle poly(butyl-methyl methacrylate) or poly(n-decyl methacrylate) as the polymer and the camphor ketal of 2,2,4-trime-thylpentane-1,3-diol and/or 5-nonyl-methyl ether as the solvent for the polymer. The dispensable paste comprises as the active brazing material the same powder and as the organic vehicle a mixture of poly (butylmethyl methacrylate) dissolved in the camphor ketal of 2,2,4-trimethylpentane-1,3-diol as a first solvent, as a first component of the mixture and poly(butylmethacrylate) dissolved in 5-nonyl methyl ether, as a second solvent, as a second component of the mixture.

摘要翻译： 这些活性钎焊膏满足丝网印刷或分配的要求特别好，并且非常适合于将一种氧化铝陶瓷体钎焊到另一种或金属体上。 这可以通过丝网印刷施加到陶瓷体上的钎焊膏的各个区域来完成，一个区域的覆盖范围与另一个区域的覆盖范围相匹配，或者通过将金属体插入到陶瓷体的孔中并使用 通过分配施加到陶瓷体和金属体的钎焊膏垫。 可印刷糊料包括Zr / Ni / Ti合金或Zr / Fe / Ti / Be合金的氢化粉末作为活性钎料，作为有机载体聚（甲基丙烯酸丁酯）或聚（甲基丙烯酸正癸酯） 作为2,2,4-三甲基戊烷-1,3-二醇和/或5-壬基 - 甲基醚的聚合物和樟脑缩酮作为聚合物的溶剂。 该可分配糊料包括作为活性钎焊材料的相同粉末，并且作为有机载体，溶解在作为第一溶剂的2,2,4-三甲基戊烷-1,3-二醇的樟脑缩醛中的聚（丁基甲基丙烯酸甲酯）的混合物作为 混合物的第一组分和溶于5-壬基甲基醚的聚（甲基丙烯酸丁酯）作为第二溶剂作为混合物的第二组分。

公开(公告)号：US5750899A

公开(公告)日：1998-05-12

申请号：US929030

申请日：1997-09-15

申请人： Frank Hegner ,  Elke Maria Schmidt ,  Ulfert Drewes ,  Rainer Martin

发明人： Frank Hegner ,  Elke Maria Schmidt ,  Ulfert Drewes ,  Rainer Martin

IPC分类号： G01L9/12 ,  G01L9/00 ,  G01L19/04 ,  G01L19/14 ,  G01L7/00 ,  G01L7/08

CPC分类号： G01L19/14 ,  G01L9/0075

摘要： To provide a flush-mounted and corrosion-resistant pressure sensor for measuring the pressure of a medium which, on the one hand, is very rugged and, on the other hand, has a casing (2) mechanically isolated from the sensing element (1) as perfectly as possible, and whose measured values exhibit little temperature dependence and little hysteresis, the casing (2) has an internal space (21) and is preferably pot-shaped for receiving the sensing element (1). An annular, particularly annular-disk-shaped, flexible connecting element (3), disposed between the casing (2) and the sensing element (1), and the sensing element close the interior space (21) toward the medium to be measured, and a liquid (4) fills the enclosed interior space (21).

摘要翻译： 为了提供一种用于测量介质的压力的嵌入式和耐腐蚀的压力传感器，其一方面非常坚固，另一方面具有与传感元件（1）机械隔离的壳体（2） ），并且其测量值显示出很小的温度依赖性和很小的滞后，所以壳体（2）具有内部空间（21），并且优选地是盆形以用于接收感测元件（1）。 设置在壳体（2）和感测元件（1）之间的环形的，特别是环形的盘形的柔性连接元件（3），并且感测元件朝向要测量的介质关闭内部空间（21） 并且液体（4）填充封闭的内部空间（21）。

公开(公告)号：US5954900A

公开(公告)日：1999-09-21

申请号：US935417

申请日：1997-09-23

申请人： Frank Hegner ,  Elke Maria Schmidt ,  Andreas Rossberg ,  Barbel Voigtsberger ,  Ingolf Voigt ,  Henry Ludwig

发明人： Frank Hegner ,  Elke Maria Schmidt ,  Andreas Rossberg ,  Barbel Voigtsberger ,  Ingolf Voigt ,  Henry Ludwig

IPC分类号： C04B37/00 ,  G01L9/00 ,  B32B31/26 ,  G01L9/12

CPC分类号： C04B35/645 ,  C04B37/005 ,  G01L9/0075 ,  C04B2235/656 ,  C04B2237/064 ,  C04B2237/343

摘要： This process serves to form a long-time-vacuum-tight, high-strength, and corrosion-resistant joint, by means of a joining material, between a first body and a second body each made of sintered, polycrystalline alumina ceramic with a purity greater than 92 wt. % or of sapphire. The joining material is interposed in the form of a paste, a foil, or a slip between the first body and the second body. The joining material has been made from 1) an agglomerate-free, highly disperse, high-purity .alpha.-alumina powder with particles of as high a degree of calcination as possible and of a size not exceeding 100 nm (=10.sup.-7 m), 2) an anorganic oxidic powder of an auxiliary sintering agent with particles of approximately the same size as the particle size of the .alpha.-alumina powder, 3) an organic vehicle which is dissolved or suspended in an organic or aqueous solvant and in which the particles of the respective powder are distributed as evenly as possible. Instead of the anorganic oxidic powder of an auxiliary sintering agent an anorganic oxidic auxiliary sintering agent produced chemically as envelopes around or attachment to the particles of the .alpha.-alumina powder can be used, the total .alpha.-alumina and auxiliary-sintering-agent content of the paste, the foil, or the slip ranging between 50% and 70%. After interposing the joining material the bodies are heated to a temperature of not more than 1,300.degree. C. and then allowing them to cool down.

摘要翻译： 该方法用于通过连接材料在第一主体和第二主体之间形成长时间真空密封，高强度和耐腐蚀的接头，每个第一主体和第二主体由具有纯度的烧结多晶氧化铝陶瓷制成 大于92wt。 ％或蓝宝石。 接合材料以第一主体和第二主体之间的糊状物，箔片或滑动片的形式插入。 接合材料由1）无聚集高分散，高纯度的α-氧化铝粉末制成，该粉末具有尽可能高的煅烧程度且尺寸不超过100nm（=10-7μm） 2）一种辅助烧结剂的无机氧化粉末，其颗粒大小与α-氧化铝粉末的粒度大致相同，3）有机载体，其溶解或悬浮在有机或水溶液中，其中 各粉末的颗粒尽可能均匀地分布。 代替辅助烧结剂的无机氧化物粉末，可以使用以α-氧化铝粉末的颗粒包围或附着于其上化学形成的无机氧化物辅助烧结剂，总α-氧化铝和辅助烧结剂的总量 糊，箔或滑差在50％至70％之间。 在插入接合材料之后，将本体加热至不高于1300℃的温度，然后使其冷却。