公开(公告)号：US4496715A

公开(公告)日：1985-01-29

申请号：US88733

申请日：1979-10-29

申请人： Frank A. Sattler

发明人： Frank A. Sattler

IPC分类号： C08G73/16 ,  H01B3/30 ,  C08G63/12

CPC分类号： C08G73/16 ,  H01B3/306 ,  Y10T428/31547 ,  Y10T428/31551 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31786

摘要： Polymeric amide-imide-ester wire enameling compositions are prepared from (1) a monoanhydride of an aromatic tricarboxylic acid, e.g. trimellitic anhydride, (2) an aromatic primary diamine compound and (3) either polyfunctional acids and polyhydroxy compounds or the polyesters thereof. At least a portion of the polyol or polyhydroxy compound is a tris (hydroxyalkyl) isocyanurate, e.g. tris (hydroxyethyl) isocyanurate. The polyfunctional acids (3) comprise an acid component selected from the group consisting of trimellitic anhydride, isophthalic acid and esters of isophthalic and terephthalic acid. The polymeric amide-imide-ester may be blended with terephthalate or isophthalate polyesters, polyisocyanates and other materials. One particularly suitable polyisocyanate is prepared from dimethylterephthalate, tris (2-hydroxyethyl) isocyanurate and tolylene diisocyanate. Small amounts of aliphatic amino compounds, aliphatic polyols and other flexibilizing materials may be incorporated into either the polymeric amide-imide-ester or the polyester blended therewith. A variety of block and modified block polymers may be made. Imidization occurs during the preparation of the polymeric amide-imide-ester so that the condensed water is removed before the fluid compositions are applied and cured.

摘要翻译： 聚合酰胺 - 酰亚胺酯丝线搪瓷组合物由（1）芳族三羧酸的单酸酐，例如 偏苯三酸酐，（2）芳族伯二胺化合物和（3）多官能酸和多羟基化合物或其聚酯。 至少一部分多元醇或多羟基化合物是三（羟烷基）异氰脲酸酯，例如 三（羟乙基）异氰脲酸酯。 多官能酸（3）包含选自偏苯三酸酐，间苯二甲酸和间苯二甲酸和对苯二甲酸的酯的酸成分。 聚合酰胺 - 酰亚胺酯可以与对苯二甲酸酯或间苯二甲酸酯聚酯，多异氰酸酯和其它材料共混。 一种特别合适的多异氰酸酯由对苯二甲酸二甲酯，三（2-羟乙基）异氰脲酸酯和甲苯二异氰酸酯制备。 少量的脂肪族氨基化合物，脂肪族多元醇和其他柔性物质可以掺入聚合酰胺 - 酰亚胺酯或与其混合的聚酯中。 可以制备各种嵌段和改性嵌段聚合物。 在制备聚合酰胺 - 酰亚胺酯期间发生酰亚胺化，使得在施加和固化流体组合物之前除去冷凝的水。

公开(公告)号：US4357219A

公开(公告)日：1982-11-02

申请号：US163900

申请日：1980-06-27

申请人： Frank A. Sattler

发明人： Frank A. Sattler

IPC分类号： C08F299/00 ,  C08F2/50 ,  C08F290/00 ,  C08F299/02 ,  C08F299/06 ,  C09D4/06 ,  C09D5/00 ,  C09D163/00 ,  C09D163/10 ,  C09D175/14 ,  H01B3/44

CPC分类号： C08F299/028 ,  C09D4/06

摘要： Disclosed is a solvent-free wire enamel cement coat which is curable to the B-stage with ultraviolet light. The wire can then be formed into a coil and cured with heat to the C-stage. The cement coat composition comprises a mixture of a UV photosensitizer and a curing agent with either an acrylated epoxy or an amine terminated acrylated epoxy or an acrylated urethane, or mixtures thereof, all dissolved in a monoacrylate. The composition can also include an end-blocked urethane, an acrylated hexamethoxymethyl melamine, or a low molecular weight cresol formaldehyde resin.

摘要翻译： 公开了一种无溶剂的搪瓷水泥涂层，其通过紫外线固化到B阶段。 然后可以将导线形成线圈并用热固化到C级。 水泥涂层组合物包括UV光敏剂和固化剂与丙烯酸酯化环氧树脂或胺封端的丙烯酸酯化环氧树脂或丙烯酸酯化氨基甲酸酯或其混合物的混合物，其全部溶解在单丙烯酸酯中。 该组合物还可包括端封氨基甲酸酯，丙烯酸酯化的六甲氧基甲基三聚氰胺或低分子量甲酚甲醛树脂。

公开(公告)号：US4206098A

公开(公告)日：1980-06-03

申请号：US942578

申请日：1978-09-15

申请人： Frank A. Sattler ,  James R. Kwiecinski

发明人： Frank A. Sattler ,  James R. Kwiecinski

IPC分类号： C08G73/00 ,  C08G63/66 ,  C08G63/685 ,  C08G73/16 ,  C08L79/08 ,  C09D5/25 ,  C09D179/08 ,  H01B3/30 ,  C09D3/56 ,  C09D3/64 ,  C09D3/70

CPC分类号： C08L79/08 ,  C08G63/66 ,  C08G63/685 ,  C08G73/16 ,  H01B3/305 ,  H01B3/306 ,  H01B3/308 ,  Y10T428/31681 ,  Y10T428/31688

摘要： A polyester-amide-imide wire enamel blend is disclosed which is made up of four components--a cross-linkable polyester, a linear polyester, a polyester amide-imide component, and a cresol formaldehyde resin. The cross-linkable polyester is the reaction product of a polyol which is mixture of diol and a triol, a polyfunctional carboxylic compound, and a catalyst. The linear polyester is the reaction product of a diol, a polyfunctional carboxylic compound, and a catalyst. The polyester-amide-imide component is the reaction product of a diamine, trimellitic anhydride, and a polyester which in turn is the reaction product of a polyol, a polyfunctional carboxylic compound, and a catalyst. The cresol formaldehyde resin is the reaction product of a phenol, formaldehyde, and a amine catalyst. All of the four components are in a solution of a carbitol. The polyester-amide-imide wire enamel blend also contains a fatty acid component which may be reacted into any of its polyester components.

摘要翻译： 公开了由四种组分 - 可交联聚酯，线性聚酯，聚酯酰胺 - 酰亚胺组分和甲酚甲醛树脂组成的聚酯 - 酰胺 - 酰亚胺线搪瓷共混物。 可交联聚酯是二醇和三醇，多官能羧酸化合物和催化剂的混合物的多元醇的反应产物。 线性聚酯是二醇，多官能羧酸化合物和催化剂的反应产物。 聚酯 - 酰胺 - 酰亚胺组分是二胺，偏苯三酸酐和聚酯的反应产物，其又是多元醇，多官能羧酸化合物和催化剂的反应产物。 甲酚甲醛树脂是苯酚，甲醛和胺催化剂的反应产物。 所有这四个组分都是卡泊醇的溶液。 聚酯 - 酰胺 - 酰亚胺线搪瓷共混物还含有可以反应成其任何聚酯组分的脂肪酸组分。

公开(公告)号：US4077925A

公开(公告)日：1978-03-07

申请号：US745727

申请日：1976-11-26

申请人： Frank A. Sattler

发明人： Frank A. Sattler

IPC分类号： C08F299/00 ,  C08F283/01 ,  C08G63/00 ,  C08G63/48 ,  C08G63/52 ,  C09D4/00 ,  C09D5/25 ,  C09D167/08 ,  H01B3/42 ,  C09D3/66

CPC分类号： H01B3/421 ,  C08G63/48 ,  C09D167/08 ,  Y10T428/31616 ,  Y10T428/31681

摘要： A high temperature capability, non-aqueous insulating composition is made by admixing: (A) about 40 wt.% to about 90 wt.% of an alkyd component consisting essentially of: the reaction product of a polyhydric alcohol; a fatty acid or its corresponding monoglyceride; and a dibasic aromatic and aliphatic acid mixture, with (B) about 10 wt.% to about 60 wt.% of an alkyl acrylate monomer having a molecular weight of over about 110; the composition characterized by having a flash point of over 45.degree. C.

摘要翻译： 通过混合来制备高温能力的非水绝缘组合物：（A）约40重量％至约90重量％的基本上由以下组成的醇酸组分：多元醇的反应产物; 脂肪酸或其相应的单甘油酯; 和二元芳族和脂族酸混合物，其中（B）约10重量％至约60重量％的分子量超过约110的丙烯酸烷基酯单体; 该组合物的闪点高于45℃。

公开(公告)号：US4317858A

公开(公告)日：1982-03-02

申请号：US163899

申请日：1980-06-27

申请人： Frank A. Sattler

发明人： Frank A. Sattler

IPC分类号： C08F299/00 ,  C08F2/48 ,  C08F290/00 ,  C08F299/02 ,  C08G59/00 ,  C08G59/40 ,  C09D5/25 ,  C09D163/00 ,  C09D163/10 ,  H01B3/30 ,  H01B3/44 ,  B32B15/08 ,  C08F283/04 ,  C08L61/34 ,  C08L79/08

CPC分类号： C08F299/024 ,  Y10S525/92 ,  Y10S525/921 ,  Y10S525/922 ,  Y10T428/294

摘要： Disclosed is a wire enamel blend which is curable to the B-stage with UV light then to the C stage with heat. The blend comprises up to about 40% of an acrylated epoxy dissolved in a monoacrylate, about 2 to about 26% of an acrylated polybutadiene, about 3 to about 26% of an acrylated polyester-amide-imide dissolved in a monoacrylate and in an unsatured diester, about 30 to about 65% of an end-blocked urethane dissolved in a monoacrylate and hydroxy terminated unsaturated diesters, up to about 15% of a cresol formaldehyde dissolved in monoacrylates, about 1.5 to about 5% of a UV photoinitiator, up to about 5% of an acrylated methoxymethyl melamine, and up to about 0.1% of a flow control agent.

摘要翻译： 公开了一种线搪瓷混合物，其可用紫外光固化至B阶段，然后加热至C阶段。 共混物包含溶解在单丙烯酸酯中的至多约40％的丙烯酸酯化环氧化物，约2至约26％的丙烯酸酯化聚丁二烯，约3至约26％的溶解在单丙烯酸酯中的丙烯酸酯化聚酯 - 酰胺 - 酰亚胺和未成型的 溶解在单丙烯酸酯和羟基封端的不饱和二酯中的约30至约65％的端部封端的聚氨酯，最多约15％的溶解在单丙烯酸酯中的甲酚甲醛，约1.5至约5％的UV光引发剂，直至 约5％的丙烯酸酯化甲氧基甲基三聚氰胺，以及最多约0.1％的流动控制剂。

公开(公告)号：US4154896A

公开(公告)日：1979-05-15

申请号：US878858

申请日：1978-02-17

申请人： Frank A. Sattler ,  George D. Dixon

发明人： Frank A. Sattler ,  George D. Dixon

IPC分类号： C08F299/00 ,  C08F2/50 ,  C08F283/01 ,  C08F299/04 ,  C08G63/00 ,  C08G63/52 ,  C08G63/685 ,  C09D4/00 ,  C09D167/00 ,  B32B15/08

CPC分类号： C08F299/0478 ,  C08F283/01 ,  C08G63/6854 ,  C09D167/00 ,  Y10T428/31681

摘要： A photosensitive, solventless, low viscosity, oil free coating composition is made by admixing: (A) about 40 wt.% to about 90 wt.% of an alkyd component, consisting essentially of a polyhydric alcohol and a dibasic aromatic and aliphatic acid mixture with (B) about 10 wt.% to about 60 wt.% of an acrylate monomer and (C) an effective amount of a photoinitiator; the composition characterized by having a viscosity of up to about 2,000 cps. at 25.degree. C., and being capable of forming an ultraviolet radiation cured, hard, pin hole free film, having a thickness of under about 5 mils.

摘要翻译： 通过混合（A）约40重量％至约90重量％的醇酸组分（其基本上由多元醇和二元芳族和脂族酸混合物组成）混合制备感光性，无溶剂，低粘度的无油涂料组合物 （B）约10重量％至约60重量％的丙烯酸酯单体和（C）有效量的光引发剂; 该组合物的特征在于具有高达约2,000cps的粘度。 并且能够形成具有低于约5密耳的厚度的紫外线辐射固化，硬的无针孔的膜。

公开(公告)号：US4481258A

公开(公告)日：1984-11-06

申请号：US433324

申请日：1982-10-07

申请人： Frank A. Sattler ,  William S. Gorton, Jr.

发明人： Frank A. Sattler ,  William S. Gorton, Jr.

IPC分类号： C08G18/00 ,  C08F2/48 ,  C08F2/50 ,  C08F290/00 ,  C08F299/02 ,  C08F299/06 ,  C08G18/67 ,  C08G18/81 ,  C08G59/14 ,  C09D163/10 ,  C09D175/14

CPC分类号： C09D163/10 ,  C08F299/028 ,  C08G18/6705 ,  C08G18/8175 ,  C08G59/1433 ,  Y10S525/92 ,  Y10S525/921 ,  Y10S525/922 ,  Y10S525/923 ,  Y10T428/2925 ,  Y10T428/31529

摘要： Disclosed is a UV-curable coating composition and method of preparing it, a method of coating a conductor with it, and the resulting coated conductor. The composition comprises about 20 to about 40% by weight of an acrylated epoxy which is the reaction product of an epoxy resin and an acrylate adduct. The acrylate adduct is the reaction product of an acrylate which may be either 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate or mixture thereof, and either an anhydride or a diisocyanate. The anhydride may be phthalic anhydride, maleic anhydride, trimellitic anhydride, or mixtures thereof. The diisocyanate can be toluene diisocyanate, 4,4'-diisocyanato diphenyl methane, or mixtures thereof. The composition also includes about 4 to about 15% by weight of an acrylated blocked isocyanate which is the reaction product of caprolactam and an acrylated isocyanate. The acrylated isocyanate is the reaction product of an acrylate which can be 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2-hydroxyethyl methacrylate, or mixtures thereof, with an isocyanate which can be toluene diisocyanate, 4,4'-diisocyanato diphenyl methane, or mixtures thereof. The composition also includes about 45 to about 65% by weight of a mono-acrylate of which at least 60% by weight is phenoxyethyl acrylate, about 5 to about 20% by weight of a polyacrylate of which at least about 50% is triethylene glycol diacrylate, about 2 to about 5% of a photoinitiator, and about 0.05 to about 0.3% by weight of an inhibitor.

摘要翻译： 公开了一种UV可固化涂料组合物及其制备方法，一种涂布导体的方法和所得的涂覆导体。 组合物包含约20至约40重量％的丙烯酸酯化环氧树脂，其是环氧树脂和丙烯酸酯加合物的反应产物。 丙烯酸酯加合物是丙烯酸酯的反应产物，其可以是丙烯酸2-羟乙酯，丙烯酸2-羟丙酯，甲基丙烯酸2-羟乙酯或其混合物，以及酸酐或二异氰酸酯。 酸酐可以是邻苯二甲酸酐，马来酸酐，偏苯三酸酐或其混合物。 二异氰酸酯可以是甲苯二异氰酸酯，4,4'-二异氰酸酯二苯甲烷或其混合物。 组合物还包括约4至约15重量％的丙烯酸酯化的封端异氰酸酯，其是己内酰胺和丙烯酸酯化的异氰酸酯的反应产物。 丙烯酸酯化的异氰酸酯是可以是丙烯酸2-羟基乙酯，丙烯酸2-羟丙酯，甲基丙烯酸2-羟乙酯或其混合物的丙烯酸酯与可以是甲苯二异氰酸酯，4,4'-二异氰酸酯二苯基甲烷， 或其混合物。 组合物还包括约45至约65重量％的单丙烯酸酯，其中至少60重量％为丙烯酸苯氧基乙酯，约5至约20重量％的聚丙烯酸酯，其至少约50重量％为三甘醇 约2至约5％的光引发剂和约0.05至约0.3重量％的抑制剂。

公开(公告)号：US4401962A

公开(公告)日：1983-08-30

申请号：US438425

申请日：1982-11-02

申请人： Wei-Fang A. Su ,  Frank A. Sattler

发明人： Wei-Fang A. Su ,  Frank A. Sattler

IPC分类号： B65D63/10 ,  C09J4/06 ,  H01B3/42 ,  H01F27/32 ,  H02K3/30 ,  H01F27/30

CPC分类号： H02K3/30 ,  C09J4/06 ,  H01B3/421 ,  H01F27/323 ,  H01F27/327 ,  Y10T428/31616 ,  Y10T428/31786 ,  Y10T442/2992

摘要： A tape useful for bonding electrical coils can be made flexible upon cure by using an impregnating varnish composition comprising a blend of (A) an alkyd component reaction mixture containing at least 29 equivalent % of fatty acid, and (B) an alkyl acrylate monomer.

摘要翻译： 通过使用包含（A）含有至少29当量脂肪酸的醇酸组分反应混合物和（B）丙烯酸烷基酯单体的共混物的浸渍清漆组合物，可以使用于粘结电线圈的胶带柔软。