公开(公告)号：US5084263A

公开(公告)日：1992-01-28

申请号：US384815

申请日：1989-07-24

申请人： Charles R. McCoy ,  Frank G. Defalco

发明人： Charles R. McCoy ,  Frank G. Defalco

IPC分类号： A61K33/02 ,  A61K33/04 ,  A61K33/14 ,  A61K33/16 ,  A61K33/42 ,  C01C1/28 ,  C07C51/41 ,  C07C53/02 ,  C07C53/08

CPC分类号： A61K33/42 ,  A61K33/02 ,  A61K33/04 ,  A61K33/14 ,  A61K33/16 ,  C01C1/28 ,  C07C51/418 ,  C07C53/02 ,  C07C53/08

摘要： The present invention provides aqueous processes which create new chemical compositions of matter prepared by reacting, in the presence of aqueous ammonia or other source of reactive NH.sub.2 groups, an alkali metal hydroxide to raise pH above 12, and further reacting with the addition of a mineral acid. The reactants are added as quickly as possible to obtain a highly exothermic reaction which, when reacted in the described manner will then contain ammonia in solution and form new polymeric water complexes. The mineral acid can be selected from, a phosphorus species, or a halogen species, or a nitrogen species, or a sulfur species, or a carbon species, or a combination of these acid species. Chemical complexes formed by these reactions are stable over a wide pH range from 0 to 14+ and can be used to perform many functions in the metal finishing industry; for removing soils from metals; for removing rust from metals; for complexing metal ions; for reducing metallic ores; to act as buffering agents for all acids and alkalis; as broad spectrum germicidal agents; for releasing of organic matter from soils; to act as therapeutic agents for healing of cuts, wounds and burns and abrasions; for healing of topical infections caused by bacteria, viruses, fungi or parasites; as growth stimulators for plants; to precipitate metallic salts from saline solutions; as anti-oxidants for stabilization of free radicals.

摘要翻译： 本发明提供了水性方法，其产生新的化学组成，其通过在氨水或其它反应性NH 2源的存在下使碱金属氢氧化物反应以使pH高于12，并进一步与添加矿物 酸。 尽可能快地加入反应物以获得高度放热的反应，当以所述方式反应时，其将在溶液中含有氨并形成新的聚合水络合物。 无机酸可以选自磷类，卤素类，氮物种，硫物种，碳类，或这些酸类的组合。 通过这些反应形成的化合物在0至14+的宽pH范围内是稳定的，并且可用于在金属整理工业中执行许多功能; 用于从金属中去除土壤; 用于从金属中除锈; 用于络合金属离子; 用于减少金属矿石; 作为所有酸​​和碱的缓冲剂; 作为广谱杀菌剂; 从土壤中释放有机物; 作为治疗切口，伤口和烧伤和擦伤的治疗剂; 用于治疗由细菌，病毒，真菌或寄生虫引起的局部感染; 作为植物的生长刺激剂; 从盐溶液中沉淀金属盐; 作为稳定自由基的抗氧化剂。

公开(公告)号：US20080302267A1

公开(公告)日：2008-12-11

申请号：US12025506

申请日：2008-02-04

申请人： Frank G. Defalco

发明人： Frank G. Defalco

IPC分类号： C23C20/04

CPC分类号： C23C22/42 ,  C23C18/00 ,  C23C22/03 ,  C23C22/05 ,  C23C22/08

摘要： The present invention provides compositions and processes for preparing metallic ions for deposition on and/or into conductive substrates, such as metals, to substantially eliminate friction from metal to metal contact. It is used in the aqueous embodiment to form new metal surfaces on all metal substrates. The processes form stable aqueous solutions of metal and metalloid ions that can be adsorbed or absorbed on and/or into conductive substrates. The aqueous solutions consist of ammonium alkali metal phosphate salts, and/or ammonium alkali metal sulfate salts mixed with a water soluble metal or metalloid salt from Group I through Group VIII of the periodic table of elements. The aqueous solutions allow for a nano deposition of the metal ions on and/or into the surfaces of conductive substrates. The surfaces created by the deposited metal ions will provide metal passivation and substantially eliminate friction in metal-to-metal contact without the use of hydrocarbon based lubricants.

摘要翻译： 本发明提供用于制备金属离子以用于沉积在导电基底（例如金属）上和/或导电基底（例如金属）中的组合物和方法，以基本上消除金属与金属接触的摩擦。 在水性实施方案中用于在所有金属基材上形成新的金属表面。 该方法形成可以吸附或吸收在导电基材上和/或导电基材上的稳定的金属和准金属离子水溶液。 水溶液由铵碱金属磷酸盐和/或碱金属硫酸铵盐与碱金属元素周期表第I族至第VIII族的水溶性金属或准金属盐混合。 水溶液允许金属离子在导电基底表面上和/或表面上的纳米沉积。 由沉积的金属离子产生的表面将提供金属钝化，并且基本上消除金属与金属之间的摩擦，而不使用烃基润滑剂。

公开(公告)号：US20100154673A1

公开(公告)日：2010-06-24

申请号：US12720395

申请日：2010-03-09

申请人： Frank G. Defalco

发明人： Frank G. Defalco

IPC分类号： C23C18/40 ,  B05D1/02

CPC分类号： C23C18/00 ,  C23C18/31 ,  C23C22/08 ,  C23C22/42 ,  C23C22/60 ,  C23C22/68

摘要： The present invention provides compositions and processes for preparing metallic ions for deposition on and/or into conductive substrates, such as metals, to substantially eliminate friction from metal to metal contact. It is used in the aqueous embodiment to form new metal surfaces on all metal substrates. The processes form stable aqueous solutions of metal and metalloid ions that can be adsorbed or absorbed on and/or into conductive substrates. The aqueous solutions consist of ammonium alkali metal phosphate salts, and/or ammonium alkali metal sulfate salts mixed with a water soluble metal or metalloid salt from Group I through Group VIII of the periodic table of elements. The aqueous solutions allow for a nano deposition of the metal ions on and/or into the surfaces of conductive substrates. The surfaces created by the deposited metal ions will provide metal passivation and substantially eliminate friction in metal-to-metal contact without the use of hydrocarbon based lubricants.

摘要翻译： 本发明提供用于制备金属离子以用于沉积在导电基底（例如金属）上和/或导电基底（例如金属）中的组合物和方法，以基本上消除金属与金属接触的摩擦。 在水性实施方案中用于在所有金属基材上形成新的金属表面。 该方法形成可以吸附或吸收在导电基材上和/或导电基材上的稳定的金属和准金属离子水溶液。 水溶液由铵碱金属磷酸盐和/或碱金属硫酸铵盐与碱金属元素周期表第I族至第VIII族的水溶性金属或准金属盐混合。 水溶液允许金属离子在导电基底表面上和/或表面上的纳米沉积。 由沉积的金属离子产生的表面将提供金属钝化，并且基本上消除金属与金属之间的摩擦，而不使用烃基润滑剂。

公开(公告)号：US5540788A

公开(公告)日：1996-07-30

申请号：US393664

申请日：1995-02-24

申请人： Frank G. Defalco ,  Charles R. McCoy

发明人： Frank G. Defalco ,  Charles R. McCoy

IPC分类号： C23C22/07 ,  C23C22/03 ,  C23F11/14 ,  C23F11/18 ,  F01M9/02 ,  F02B75/02

CPC分类号： C23C22/03 ,  F01M9/02 ,  F02B2075/027

摘要： The present invention provides for forming an iron-phosphate conversion surface, or an iron-phosphate bi-metallic surface on metals, in situ, in internal combustion engines, pumps, hydraulic systems, compressors and other mechanical equipment and machinery, using the lubricating oil as the medium for bringing the phosphate and bi-metallic inorganic polymeric water complexes into contact with the metals in the machinery. The inorganic polymeric water complexes can be formed in accordance with U.S. Pat. Nos. 5,084,263 and 5,310,419 which are incorporated herein by reference. The bimetallic component can be any metal from Classes I through VIII of the Periodic Table. The phosphate and/or phosphate bi-metallic complexes are added to the lubricating oil while the engine is running. The iron-phosphate film that is formed reduces co-efficient of friction, reduces metal wear and extends engine life, increases mileage, reduces hydrocarbon emissions, and extends oil drainage intervals on all lubricated machinery and equipment.

摘要翻译： 本发明提供在现场，在内燃机，泵，液压系统，压缩机和其它机械设备和机械中的金属上形成磷酸铁转化表面或磷酸铁双金属表面，使用润滑油 作为使磷酸盐和双金属无机聚合物水配合物与机械中的金属接触的介质。 无机聚合物水复合物可以根据美国专利号 5,084,263和5,310,419号，其通过引用并入本文。 双金属组分可以是元素周期表I至VIII族中的任何金属。 在发动机运行时，将磷酸盐和/或磷酸盐双金属络合物加入到润滑油中。 形成的磷酸铁膜会降低摩擦系数，降低金属磨损，延长发动机寿命，增加里程，减少碳氢化合物排放，并在所有润滑的机械和设备上延长排油间隔。

公开(公告)号：US5310419A

公开(公告)日：1994-05-10

申请号：US819137

申请日：1992-01-10

申请人： Charles R. McCoy ,  Frank G. Defalco

发明人： Charles R. McCoy ,  Frank G. Defalco

IPC分类号： A61K33/02 ,  A61K33/04 ,  A61K33/14 ,  A61K33/16 ,  A61K33/42 ,  C01C1/28 ,  C07C51/41 ,  C07C53/02 ,  C07C53/08 ,  C09D1/00 ,  C01D13/00 ,  C01G5/00 ,  C01G7/00

CPC分类号： A61K33/42 ,  A61K33/02 ,  A61K33/04 ,  A61K33/14 ,  A61K33/16 ,  C01C1/28 ,  C07C51/418 ,  C07C53/02 ,  C07C53/08

摘要： The present invention provides aqueous processes which create new chemical compositions of matter prepared by reacting, in the presence of aqueous ammonia or other source of reactive NH.sub.2 groups, an alkali metal hydroxide to raise pH above 12, and further reacting with the addition of a mineral acid. The reactants are added as quickly as possible to obtain a highly exothermic reaction which, when reacted in the described manner will then contain ammonia in solution and form new polymeric water complexes. The mineral acid can be selected from, a phosphorus species, or a halogen species, or a nitrogen species, or a sulfur species, or a carbon species, or a combination of these acid species. Chemical complexes formed by these reactions are stable over a wide pH range from 0 to 14+ and can be used to perform many functions in the metal finishing industry; for removing soils from metals; for removing rust from metals; for complexing metal ions; for reducing metallic ores; to act as buffering agents for all acids and alkalis; as broad spectrum germicidal agents; for releasing of organic matter from soils; to act as therapeutic agents for healing of cuts, wounds and burns and abrasions; for healing of topical infections caused by bacteria, viruses, fungi or parasites; as growth stimulators for plants; to precipitate metallic salts from saline solutions; as anti-oxidants for stabilization of free radicals.

摘要翻译： 本发明提供了水性方法，其产生新的化学组成，其通过在氨水或其它反应性NH 2源的存在下使碱金属氢氧化物反应以使pH高于12，并进一步与添加矿物 酸。 尽可能快地加入反应物以获得高度放热的反应，当以所述方式反应时，其将在溶液中含有氨并形成新的聚合水络合物。 无机酸可以选自磷类，卤素类，氮物种，硫物种，碳类，或这些酸类的组合。 通过这些反应形成的化合物在0至14+的宽pH范围内是稳定的，并且可用于在金属整理工业中执行许多功能; 用于从金属中去除土壤; 用于从金属中除锈; 用于络合金属离子; 用于减少金属矿石; 作为所有酸​​和碱的缓冲剂; 作为广谱杀菌剂; 从土壤中释放有机物; 作为治疗切口，伤口和烧伤和擦伤的治疗剂; 用于治疗由细菌，病毒，真菌或寄生虫引起的局部感染; 作为植物的生长刺激剂; 从盐溶液中沉淀金属盐; 作为稳定自由基的抗氧化剂。

公开(公告)号：US08317909B2

公开(公告)日：2012-11-27

申请号：US12720395

申请日：2010-03-09

申请人： Frank G. Defalco

发明人： Frank G. Defalco

IPC分类号： C23C18/31 ,  C23C18/32 ,  C23C18/38 ,  C23C18/42

CPC分类号： C23C18/00 ,  C23C18/31 ,  C23C22/08 ,  C23C22/42 ,  C23C22/60 ,  C23C22/68

摘要： The present invention provides compositions and processes for preparing metallic ions for deposition on and/or into conductive substrates, such as metals, to substantially eliminate friction from metal to metal contact. It is used in the aqueous embodiment to form new metal surfaces on all metal substrates. The processes form stable aqueous solutions of metal and metalloid ions that can be adsorbed or absorbed on and/or into conductive substrates. The aqueous solutions consist of ammonium alkali metal phosphate salts, and/or ammonium alkali metal sulfate salts mixed with a water soluble metal or metalloid salt from Group I through Group VIII of the periodic table of elements. The aqueous solutions allow for a nano deposition of the metal ions on and/or into the surfaces of conductive substrates. The surfaces created by the deposited metal ions will provide metal passivation and substantially eliminate friction in metal-to-metal contact without the use of hydrocarbon based lubricants.

摘要翻译： 本发明提供用于制备金属离子以用于沉积在导电基底（例如金属）上和/或导电基底（例如金属）中的组合物和方法，以基本上消除金属与金属接触的摩擦。 在水性实施方案中用于在所有金属基材上形成新的金属表面。 该方法形成可以吸附或吸收在导电基材上和/或导电基材上的稳定的金属和准金属离子水溶液。 水溶液由铵碱金属磷酸盐和/或碱金属硫酸铵盐与碱金属元素周期表第I族至第VIII族的水溶性金属或准金属盐混合。 水溶液允许金属离子在导电基底表面上和/或表面上的纳米沉积。 由沉积的金属离子产生的表面将提供金属钝化，并且基本上消除金属与金属之间的摩擦，而不使用烃基润滑剂。

公开(公告)号：US08252734B1

公开(公告)日：2012-08-28

申请号：US12634502

申请日：2009-12-09

申请人： Harry F. Schramm ,  Frank G. Defalco ,  Lloyd L. Starks, Sr.

发明人： Harry F. Schramm ,  Frank G. Defalco ,  Lloyd L. Starks, Sr.

IPC分类号： C10M125/24 ,  C10M125/26

CPC分类号： C10M177/00 ,  C10M125/00 ,  C10M125/26 ,  C10M2201/062 ,  C10M2201/082 ,  C10M2201/085 ,  C10M2201/102 ,  C10M2219/044 ,  C10N2210/01 ,  C10N2210/04 ,  C10N2210/05 ,  C10N2210/06 ,  C10N2210/08 ,  C10N2230/06 ,  C10N2240/04 ,  C10N2240/08 ,  C10N2240/10 ,  C23C22/03

摘要： A process for creating conversion coatings and spin, drawing, and extrusion finishes for surfaces, wherein the conversion coatings and spin, drawing, and extrusion finishes contain potassium, phosphorus, nitrogen, silicon, and one or more non-alkaline metals. The process comprises forming a first aqueous solution of silicate, potassium hydroxide, and ammonium hydroxide; forming a second aqueous solution of water, phosphoric acid, ammonium hydroxide, an alkali metal hydroxide, and one or more non-alkaline metals, and then combining the first solution with the second solution to form a final solution. This final solution forms an anti-friction multi-layer conversion coating or a spin, drawing, and extrusion finish on a surface when applied to the surface, either directly or as an additive in lubricating fluids.

摘要翻译： 用于生产转化涂层和用于表面的旋转，拉伸和挤出表面处理的方法，其中转化涂层和旋涂，拉伸和挤出成品包含钾，磷，氮，硅和一种或多种非碱性金属。 该方法包括形成硅酸盐，氢氧化钾和氢氧化铵的第一水溶液; 形成水，磷酸，氢氧化铵，碱金属氢氧化物和一种或多种非碱金属的第二水溶液，然后将第一溶液与第二溶液组合以形成最终溶液。 当最终溶液直接或作为润滑液中的添加剂施加到表面时，该最终溶液在表面上形成抗摩擦多层转化涂层或旋涂，拉伸和挤出涂饰。