公开(公告)号：US07521029B2

公开(公告)日：2009-04-21

申请号：US10541698

申请日：2003-01-31

Applicant: Friedrich Guetlhuber ,  Manfred Lehr

Inventor： Friedrich Guetlhuber ,  Manfred Lehr

IPC: F28D7/00 ,  B01J19/00 ,  B01J10/00 ,  B01J8/04 ,  G05D16/00

CPC classification number: B01J8/008 ,  B01J3/02 ,  B01J3/03 ,  B01J3/042 ,  B01J4/002 ,  B01J8/0085 ,  B01J8/065 ,  B01J8/067 ,  B01J19/002 ,  B01J19/0053 ,  B01J19/26 ,  B01J2208/00203 ,  B01J2208/00212 ,  B01J2208/00495 ,  B01J2208/0053 ,  B01J2208/00548 ,  B01J2208/00716 ,  B01J2208/00849 ,  B01J2219/00263 ,  B01J2219/00265 ,  C07C51/21 ,  F28D7/16 ,  F28F9/0229 ,  F28F9/0265 ,  F28F2225/08 ,  Y10T137/043 ,  Y10T137/1654

Abstract: The invention relates to a tubular reactor for carrying out catalytic gas-phase reactions, containing a catalyst tube bundle (8) that is traversed by the relevant reaction gas mixture, is filled with a catalyst, extends between two tube sheets (4, 148) and around which flows a heat transfer medium contained within a surrounding reactor jacket (6). The reactor also comprises gas entry and discharge hoods (2; 60) that cover the two tube sheets for supplying the relevant process gas to the catalyst tubes and for discharging the reacted process gas from the catalyst tubes. Together with all the parts that come into contact with the process gas mixture, the reactor is designed to have an appropriate strength for withstanding the deflagration and explosive pressures that are to be taken into account during its operation. The volume available to the process gas mixture prior to its entry into the catalyst tubes is restricted as much as possible in construction and flow engineering terms.

Abstract translation: 本发明涉及一种用于进行催化气相反应的管式反应器，其中包含由相关反应气体混合物穿过的催化剂管束（8），填充有催化剂，在两个管板（4,148）之间延伸， 并且在其周围流过包含在周围的反应器夹套（6）内的传热介质。 反应器还包括气体进入和排出罩（2; 60），其覆盖两个管板，用于将相关工艺气体供应到催化剂管并从催化剂管排出反应的工艺气体。 连同与工艺气体混合物接触的所有部件，反应器被设计为具有适当的强度，以承受在其操作期间要考虑的爆燃和爆炸压力。 过程气体混合物在其进入催化剂管之前可用的体积在结构和流程工程方面尽可能地受到限制。

公开(公告)号：US20060133972A1

公开(公告)日：2006-06-22

申请号：US10541698

申请日：2003-01-31

Applicant: Friedrich Guetlhuber ,  Manfred Lehr

Inventor： Friedrich Guetlhuber ,  Manfred Lehr

IPC: B01J8/04 ,  F28D7/00

CPC classification number: B01J8/008 ,  B01J3/02 ,  B01J3/03 ,  B01J3/042 ,  B01J4/002 ,  B01J8/0085 ,  B01J8/065 ,  B01J8/067 ,  B01J19/002 ,  B01J19/0053 ,  B01J19/26 ,  B01J2208/00203 ,  B01J2208/00212 ,  B01J2208/00495 ,  B01J2208/0053 ,  B01J2208/00548 ,  B01J2208/00716 ,  B01J2208/00849 ,  B01J2219/00263 ,  B01J2219/00265 ,  C07C51/21 ,  F28D7/16 ,  F28F9/0229 ,  F28F9/0265 ,  F28F2225/08 ,  Y10T137/043 ,  Y10T137/1654

Abstract: The invention relates to a tubular reactor for carrying out catalytic gas-phase reactions, containing a catalyst tube bundle (8) that is traversed by the relevant reaction gas mixture, is filled with a catalyst, extends between two tube sheets (4, 148) and around which flows a heat transfer medium contained within a surrounding reactor jacket (6). The reactor also comprises gas entry and discharge hoods (2; 60) that cover the two tube sheets for supplying the relevant process gas to the catalyst tubes and for discharging the reacted process gas from the catalyst tubes. Together with all the parts that come into contact with the process gas mixture, the reactor is designed to have an appropriate strength for withstanding the deflagration and explosive pressures that are to be taken into account during its operation. The volume available to the process gas mixture prior to its entry into the catalyst tubes is restricted as much as possible in construction and flow engineering terms.

Abstract translation: 本发明涉及一种用于进行催化气相反应的管式反应器，其中包含由相关反应气体混合物穿过的催化剂管束（8），填充有催化剂，在两个管板（4,148）之间延伸， 并且在其周围流过包含在周围的反应器夹套（6）内的传热介质。 反应器还包括气体进入和排出罩（2; 60），其覆盖两个管板，用于将相关工艺气体供应到催化剂管并从催化剂管排出反应的工艺气体。 连同与工艺气体混合物接触的所有部件，反应器被设计为具有适当的强度，以承受在其操作期间要考虑的爆燃和爆炸压力。 过程气体混合物在其进入催化剂管之前可用的体积在结构和流程工程方面尽可能地受到限制。

公开(公告)号：US4265223A

公开(公告)日：1981-05-05

申请号：US943373

申请日：1978-09-18

Applicant: Constantine D. Miserlis ,  Albert G. Luke, Jr. ,  Walter Laber ,  Friedrich Guetlhuber

Inventor： Constantine D. Miserlis ,  Albert G. Luke, Jr. ,  Walter Laber ,  Friedrich Guetlhuber

IPC: F03G6/00 ,  F22B1/00 ,  F24S90/00 ,  F24J3/02

CPC classification number: F24J2/34 ,  F22B1/006 ,  F24J2/07 ,  F24J2/42 ,  F24J2/4649 ,  Y02E10/41 ,  Y02E10/46

Abstract: A process and system are provided for economic utilization of solar energy. Solar energy is absorbed and converted to thermal energy by means of at least two systems, operating in different temperature ranges, for circulating a primary fluid heat transfer medium through separate collector sections of a solar receiver to recover solar heat and through separate output heat exchangers to supply heat to a second heat transfer medium functioning as a working medium, with heat storage means being associated with each system for the purpose of satisfying the heat requirements of the working fluid and also to prevent cooling down of the collector during the time that little or no solar radiation is available.

Abstract translation: 为太阳能的经济利用提供了一个过程和系统。 通过在不同温度范围内工作的至少两个系统吸收太阳能并将其转化为热能，用于使主流体传热介质通过太阳能接收器的单独的收集器部分循环，以回收太阳能热量并通过单独的输出热交换器 向作为工作介质起作用的第二传热介质供热，为了满足工作流体的热量要求，并且在少量或 没有太阳辐射可用。

公开(公告)号：US06932950B1

公开(公告)日：2005-08-23

申请号：US09622301

申请日：1999-02-17

Applicant: Friedrich Guetlhuber

Inventor： Friedrich Guetlhuber

IPC: B01J8/06 ,  B01J8/00 ,  F28D21/00

CPC classification number: B01J8/067 ,  B01J2208/00212 ,  B01J2208/00221 ,  B01J2208/00256 ,  B01J2208/00495 ,  B01J2208/00522 ,  B01J2208/025 ,  B01J2219/00099 ,  B01J2219/00155 ,  B01J2219/00777 ,  F28F2270/00

Abstract: A tubular reactor (2) for catalytic reactions with a heat carrier that inside a reactor jacket (10) circulates around a contact tube bundle (8), which extends between a tube plate (4; 6; 80; 82) at the reaction gas inlet side and one at the reaction gas outlet side with gas inlet and gas outlet hoods (12, 14) spanning the face sides of the two tube plates and containing reaction-inhibiting media in the zone of the tube plate on the gas inlet side, characterize themselves in that the reaction-inhibiting media consist entirely or in part of a heat insulation layer (46; 50; 64; 80) with openings for the tube cross-sections on at least one of the two sides of the respective tube plate (4; 60; 82). In this manner, either the respective tube plate (4; 60; 82) is insulated against the hot heat carrier or the reaction gas entering into the reactor is prevented from having contact with the comparatively hot tube plate in order to prevent harmful secondary reactions at the reactor inlet.

Abstract translation: 一种用于与反应器夹套（10）内部的热载体进行催化反应的管状反应器（2），所述反应器夹套（10）围绕在反应气体管板（4; 6; 80; 82） 入口侧和一个在反应气体出口侧的气体入口和气体出口罩（12,14）跨越两个管板的正面，并在气体入口侧的管板区域中含有反应抑制介质， 其特征在于反应抑制介质完全或部分地由具有用于相应管板的两侧中的至少一个上的管横截面的开口的隔热层（46; 50; 64; 80） 4; 60; 82）。 以这种方式，相应的管板（4; 60; 82）与热热载体绝缘，或者防止进入反应器的反应气体与较热的管板接触，以防止有害的次级反应 反应器入口。

公开(公告)号：US4549032A

公开(公告)日：1985-10-22

申请号：US613595

申请日：1984-05-23

Applicant: Friedrich-Wilhelm Moeller ,  Henning Buchold ,  Helmut Klein ,  Otto-Ludwig Garkisch ,  Friedrich Guetlhuber ,  Walter Laber

Inventor： Friedrich-Wilhelm Moeller ,  Henning Buchold ,  Helmut Klein ,  Otto-Ludwig Garkisch ,  Friedrich Guetlhuber ,  Walter Laber

IPC: B01J23/86 ,  C07B61/00 ,  C07C1/00 ,  C07C5/333 ,  C07C15/46 ,  C07C67/00

CPC classification number: C07C5/333

Abstract: A process for producing styrene by the dehydrogenation of ethyl benzene whereby the ethyl benzene in a mixture with steam is introduced into a tubular reactor, the tubes of which are heated by molten salts. The structural parameters of this process are the tube diameter which should be 20 to 35 millimeters, the temperature of the molten salts which should be 580.degree. to 660.degree. C. and at most 20.degree. C. higher than the reaction temperature at the catalyst and the weight ratio of steam to ethyl benzene of the feed stock which should be 0.5 to 1. The process saves energy and increases efficiency by reducing the steam consumption.

Abstract translation: 通过乙苯的脱氢生产苯乙烯的方法，由此将与蒸汽的混合物中的乙苯引入管式反应器中，其管被熔融盐加热。 该方法的结构参数是管直径应为20至35毫米，熔盐温度应为580至660℃，最高为20℃，高于催化剂的反应温度， 原料的蒸汽与乙苯的重量比应为0.5至1.该方法通过降低蒸汽消耗来节省能源并提高效率。