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公开(公告)号:US4386200A
公开(公告)日:1983-05-31
申请号:US306966
申请日:1981-09-30
申请人: Fritz Fleck
发明人: Fritz Fleck
IPC分类号: C07D311/16 , C07D311/80 , C07F9/655 , C09B23/10
CPC分类号: C07D311/16 , C07D311/80 , C07F9/65522
摘要: A non-chromophoric conjugated derivative of 7-styryl coumarin for use as an optical brightener in which the lactone ring of the coumarinyl group may have a benzene ring fused to it to form a 3,4-benzocoumarinyl-7 group, the phenyl group of the styryl is substituted by a conjugated group which contains a group derived from an acid in its conjugation and which group is so located as to conjugate with the ethylene group.
摘要翻译: 用作荧光增白剂的7-苯乙烯基香豆素的非发色共轭衍生物,其中香豆素基的内酯环可以具有与其稠合的苯环以形成3,4-苯并香豆素基团,苯基 苯乙烯基被共轭基团取代,所述共轭基团在其共轭中含有衍生自酸的基团,并且该基团位于与乙烯基团结合的位置。
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公开(公告)号:US4025507A
公开(公告)日:1977-05-24
申请号:US483009
申请日:1974-06-25
申请人: Fritz Fleck , Hans-Rudolf Schmid
发明人: Fritz Fleck , Hans-Rudolf Schmid
IPC分类号: C08K5/00 , C07C39/18 , C07D20060101 , C07D251/00 , C07D251/68 , C07D403/02 , C07F20060101 , C08K5/41 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C09B57/00 , C09K13/00 , D01F2/10 , D06L20060101 , D06L3/12 , D06M13/44 , D21H21/28
CPC分类号: C07D251/68
摘要: Disclosed are compounds of formula I, ##STR1## in which THE R.sub.1 's are the same and signify hydrogen or methyl,The R.sub.2 's are the same and signify hydrogen; C.sub.1-6 alkyl; cyclohexyl, unsubstituted or substituted by up to three C.sub.1-6 alkyl radicals; or benzyl, unsubstituted or substituted by up to two substituents selected from halogen, C.sub.1-6 alkoxy and C.sub.1-6 alkyl, andThe M's signify hydrogen or a nonchromophoric cation,Their production and use as optical brightening agents for cellulosic substrates, particularly paper substrates.
摘要翻译: 公开了式I化合物,其中R 1相同并且表示氢或甲基,其中R2是相同的并且表示氢; C 1-6烷基; 环己基,未被取代或被至多三个C 1-6烷基取代; 或苄基,未被取代或被至多两个选自卤素,C 1-6烷氧基和C 1-6烷基的取代基取代,并且M表示氢或非消色阳离子。它们的生产和用作细胞核基质,特别是纸基质的光学加工剂。
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公开(公告)号:US3956280A
公开(公告)日:1976-05-11
申请号:US534799
申请日:1974-12-20
IPC分类号: C07D231/06
摘要: The invention provides novel pyrazoline derivatives which are useful as optical brighteners.
摘要翻译: 本发明提供了可用作荧光增白剂的新颖的吡唑啉衍生物。
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公开(公告)号:US4252604A
公开(公告)日:1981-02-24
申请号:US829241
申请日:1977-08-30
申请人: Fritz Fleck , Hans R. Schmid
发明人: Fritz Fleck , Hans R. Schmid
IPC分类号: C07D251/68 , C07D403/12 , C09B23/00 , D21H3/80
CPC分类号: C07D251/68
摘要: Bis-(triazinylamino)-stilbenesulphonic acids ##STR1## wherein X is optionally substituted NH.sub.2 ##STR2## Y is a radical of formula Z is --COOR.sub.4, --CO--C.sub.m H.sub.2m+1, --CN or ##STR3## R.sub.1 is H, halogen, alkyl or alkoxy, R.sub.2 is H or alkyl,R.sub.3 is H, optionally substituted alkyl, cycloalkyl or phenyl or ##STR4## R.sub.4 is optionally substituted alkyl, R.sub.3 and R.sub.6 are H, alkyl, hydroxyalkyl or form together with N a heterocyclem is a whole number from 1 to 5 andn is 1 or 2,are optical brighteners suitable for cellulosic fibres, polyamide and polyurethane fibres and paper.
摘要翻译: 双(三嗪基氨基) - 二苯磺酸其中X是任选取代的NH 2 Y是式Z的基团是-COOR 4,-CO-Cm H 2m + 1,-CN或R 1 R 2为H,卤素,烷基或烷氧基,R 2为H或烷基,R 3为H,任选取代的烷基,环烷基或苯基或R 4为任选取代的烷基,R 3和R 6为H,烷基,羟基烷基或与N 杂环m为1至5的整数,n为1或2,为适用于纤维素纤维,聚酰胺和聚氨酯纤维和纸的荧光增白剂。
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公开(公告)号:US4167629A
公开(公告)日:1979-09-11
申请号:US521642
申请日:1974-11-07
申请人: Fritz Fleck , Horst Schmid
发明人: Fritz Fleck , Horst Schmid
IPC分类号: C07D249/24 , C07D403/10 , C09B23/14
CPC分类号: C07D249/24
摘要: This invention relates to new di-triazolylstyrene derivatives, useful as optical brighteners for organic polymeric materials, especially when applied to or incorporated in synthetic fibres.
摘要翻译: 本发明涉及新的二 - 三唑基苯乙烯衍生物,其可用作有机聚合物材料的荧光增白剂,特别是当应用于或掺入合成纤维中时。
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公开(公告)号:US4003889A
公开(公告)日:1977-01-18
申请号:US480128
申请日:1974-06-17
IPC分类号: C07D231/06 , C07D231/42 , C07D233/00 , C07D235/00 , C07D261/16
CPC分类号: C07D231/06
摘要: Disclosed are compounds of formula I, ##STR1## in which either R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each signifies a hydrogen atom, a chlorine or fluorine atom, an alkyl radical of 1 to 4 carbon atoms, an alkoxy radical of 1 to 4 carbon atoms, a cyano group, a group --SO.sub.3 M, an unsubstituted phenyl radical or a phenyl radical substituted by up to 2 substituents selected from chlorine, fluorine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms and the group --SO.sub.3 M, with the proviso that only one of R.sub.1, R.sub.2 and R.sub.3 signifies an unsubstituted or substituted phenyl radical,Or two ofR.sub.1, r.sub.2 and R.sub.3 together form a methylenedioxy group, the other of R.sub.1, R.sub.2 and R.sub.3 having one of the above significances,R.sub.4 signifies a hydrogen atom, a chlorine or fluorine atom, an alkyl radical of 1 to 4 carbon atoms or an alkoxy radical of 1 to 4 carbon atoms,R.sub.5 signifies a hydrogen atom, an alkyl radical of 1 to 4 carbon atoms, an unsubstituted phenyl radical or a phenyl radical substituted by 1 or 2 substituents selected from chlorine, fluorine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms and the group --SO.sub.3 M,A.sub.1 signifies a C.sub.1 to C.sub.3 alkylene chain, unsubstituted or substituted by up to two alkyl groups of 1 to 4 carbon atoms,A.sub.2 signifies a C.sub.1 to C.sub.3 alkylene chain, unsubstituted or substituted by up to two alkyl groups of 1 to 4 carbon atoms; or a phenylene group, unsubstituted or substituted by up to 2 substituents selected from chlorine, fluorine, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms and the group --SO.sub.3 M,Y signifies --O-- or --NR.sub.6 --, in which R.sub.6 signifies a hydrogen atom or an alkyl radical of 1 to 4 carbon atoms, andThe Ms, which may be the same or different, each signifies a hydrogen atom, or a non-chromophoric cation;Their production and use as optical brightening agents particularly for textile substrates comprising polyamide fibers.
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公开(公告)号:US3940388A
公开(公告)日:1976-02-24
申请号:US421002
申请日:1973-12-03
申请人: Horst Aebli , Fritz Fleck , Horst Schmid
发明人: Horst Aebli , Fritz Fleck , Horst Schmid
IPC分类号: C07D249/06 , C07D249/20 , C08K5/3472
CPC分类号: C07D249/20 , C07D249/06 , C08K5/3472
摘要: The present invention provides novel compounds of the formula: ##SPC1##In whichR.sub.1 signifies hydrogen, fluorine or chlorine atom, a carboxylic or sulphonic acid group or an amide or ester thereof, a cyano group or an alkylsulphonyl or arylsulphonyl group,R.sub.2 signifies a hydrogen, fluorine or chlorine atom, a cyano group, a phenyl or alkyl radical which may be substituted, a carboxylic or sulphonic acid group or an amide or ester thereof, an alkylsulphonyl or arylsulphonyl group or a benzoxazole group which may be substituted,R.sub.3 and R.sub.4 independently signify a hydrogen, fluorine or chlorine atom, an alkyl radical of 1 to 6 carbon atoms which may be substituted, a cyano or carboxy group, a carboxylic acid amide or ester group, and R.sub.4 may also signify an aryl radical which may be substituted, andA signifies a hydrogen atom or an alkyl or aryl radical which may be substituted or a group of formula II,B--CH = CH-- II in which B signifies an aryl or heterocyclic radical which may be substituted,And their water soluble sulphonated derivatives.The compounds are useful as optical brighteners for various organic materials.
摘要翻译: 本发明提供下式的新型化合物:
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公开(公告)号:US3939154A
公开(公告)日:1976-02-17
申请号:US436129
申请日:1974-01-24
IPC分类号: C08K5/00 , C07D231/06 , C08K5/43 , C08L77/00 , C09B57/00
CPC分类号: C07D231/06
摘要: The invention relates to optical brightening agents.
摘要翻译: 本发明涉及荧光增白剂。
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公开(公告)号:US4182861A
公开(公告)日:1980-01-08
申请号:US755459
申请日:1976-12-30
申请人: Fritz Fleck , Hans Balzer , Horst Aebli
发明人: Fritz Fleck , Hans Balzer , Horst Aebli
IPC分类号: C07D311/00 , C07D405/04 , C07D405/10 , D06L3/12 , C09K1/02
CPC分类号: C07D405/04 , C07D311/00 , C07D405/10 , D06L3/12
摘要: Polyester, cotton, polyamide and polyacrylonitrile fabrics and foils of polyvinylchloride are optically brightened by the addition of a compound of the formula ##STR1## in which each of R.sub.1 and R.sub.2 represents a hydrogen atom or an aliphatic, alicyclic, araliphatic, halogen- or alkyl-substituted araliphatic, aromatic, or halogen- or alkyl-substituted aromatic radical,R.sub.3 represents a hydrogen or halogen atom or a low molecular weight alkyl or alkoxy radical.
摘要翻译: 聚酯,棉,聚酰胺和聚丙烯腈织物和聚氯乙烯箔通过加入其中R1和R2各自表示氢原子或脂族,脂环族,芳脂族,卤素或烷基的式“IMAGE”化合物进行光学增白 取代的芳脂族,芳族或卤素或烷基取代的芳族基团,R 3表示氢或卤素原子或低分子量烷基或烷氧基。
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公开(公告)号:US4108887A
公开(公告)日:1978-08-22
申请号:US653506
申请日:1976-01-29
申请人: Fritz Fleck , Juerg Heller
发明人: Fritz Fleck , Juerg Heller
IPC分类号: C08K5/00 , C07C15/52 , C07C49/223 , C07C51/00 , C07C51/347 , C07C57/42 , C07C57/60 , C07C69/618 , C07C69/76 , C07C233/02 , C07C233/09 , C07C235/00 , C07C255/34 , C07C309/15 , C07C309/32 , C07C309/51 , C07C317/08 , C07C317/10 , C07C317/14 , C07D303/16 , C08L1/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09B23/14 , C09B57/00 , C09K11/06 , D06L3/12 , C07C63/60 , C07C121/70 , C07C147/06
CPC分类号: D06L3/125 , C07C15/52 , C07C255/00 , C07C317/10 , C07C317/14 , C07C51/347 , C07C57/42 , C07C57/60 , C07D303/16 , C09B23/141 , C09K11/06 , D06L3/12
摘要: Disclosed are compounds of formula I ##STR1## in which R.sub.1 and R.sub.4, independently, are hydrogen, a non-chromophoric second order substituent, or alkyl or alkenyl unsubstituted or substituted by a non-chromophoric group,R.sub.2 and R.sub.5, independently, are hydrogen or alkyl or alkenyl, unsubstituted or substituted by a non-chromophoric group,R.sub.3 and R.sub.6, independently, are hydrogen, alkyl, carboxyl or a non-chromophoric esterified carboxyl group, orR.sub.2, together with R.sub.3, and/or R.sub.5 together with R.sub.6, signify an alkylene bridge,R.sub.7 and R.sub.8, independently, signify hydrogen or a non-chromophoric substituent, or, whenR.sub.7 is in the 3-position and/or R.sub.8 in the 3' position, R.sub.7 together with R.sub.2, and/or R.sub.8 together with R.sub.5 signify an alkylene bridge,With the proviso that no more than one of R.sub.1 and R.sub.2 and no more than one of R.sub.4 and R.sub.5 signify hydrogen, their production and use as optical brightening agents.
摘要翻译: 公开了式I的化合物,其中R 1和R 4独立地是氢,非发色二级取代基或未被取代或被非发色基团取代的烷基或烯基,R 2和R 5独立地是 氢或烷基或烯基,未被取代或被非发色基团取代,R 3和R 6独立地是氢,烷基,羧基或非发色团酯化的羧基,或R 2与R 3和/或R 5连同 R6表示亚烷基桥,R7和R8独立地表示氢或非发色团取代基,或者当R7位于3位和/或R8位于3'位时,R7与R2和/或 R8与R5一起表示一个亚烷基桥,只要不超过R1和R2的一个,并且R4和R5中不超过一个表示氢,它们的生产和用作荧光增白剂。
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