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14 条记录 (耗时 0.019 秒)

    Triazolylstyryl triazoles
    1.
    发明授权
    Triazolylstyryl triazoles 失效
    三唑基苯乙烯基三唑

    公开(公告)号：US3940388A

    公开(公告)日：1976-02-24

    申请号：US421002

    申请日：1973-12-03

    申请人： Horst Aebli ,  Fritz Fleck ,  Horst Schmid

    发明人： Horst Aebli ,  Fritz Fleck ,  Horst Schmid

    IPC分类号： C07D249/06 ,  C07D249/20 ,  C08K5/3472

    CPC分类号： C07D249/20 ,  C07D249/06 ,  C08K5/3472

    摘要： The present invention provides novel compounds of the formula: ##SPC1##In whichR.sub.1 signifies hydrogen, fluorine or chlorine atom, a carboxylic or sulphonic acid group or an amide or ester thereof, a cyano group or an alkylsulphonyl or arylsulphonyl group,R.sub.2 signifies a hydrogen, fluorine or chlorine atom, a cyano group, a phenyl or alkyl radical which may be substituted, a carboxylic or sulphonic acid group or an amide or ester thereof, an alkylsulphonyl or arylsulphonyl group or a benzoxazole group which may be substituted,R.sub.3 and R.sub.4 independently signify a hydrogen, fluorine or chlorine atom, an alkyl radical of 1 to 6 carbon atoms which may be substituted, a cyano or carboxy group, a carboxylic acid amide or ester group, and R.sub.4 may also signify an aryl radical which may be substituted, andA signifies a hydrogen atom or an alkyl or aryl radical which may be substituted or a group of formula II,B--CH = CH-- II in which B signifies an aryl or heterocyclic radical which may be substituted,And their water soluble sulphonated derivatives.The compounds are useful as optical brighteners for various organic materials.

    摘要翻译： 本发明提供下式的新型化合物：

    Improved optical brightening of polyamides
    2.
    发明授权
    Improved optical brightening of polyamides 失效
    改进聚酰胺的光学增白

    公开(公告)号：US4169702A

    公开(公告)日：1979-10-02

    申请号：US766410

    申请日：1977-02-07

    申请人： Fritz Fleck ,  Emmanuel Hervot ,  Peter Merk ,  Horst Schmid ,  Achim Wiedemann

    发明人： Fritz Fleck ,  Emmanuel Hervot ,  Peter Merk ,  Horst Schmid ,  Achim Wiedemann

    IPC分类号： D06L3/12 ,  D06P1/00 ,  D06P1/64 ,  D06P1/651 ,  D06P3/54 ,  D06P1/645

    CPC分类号： D06L3/1264 ,  D06L3/1271

    摘要： Disclosed is an optical brightening process for substrates comprising or consisting of synthetic polyamide in which the optical brightener is applied to the substrate by impregnation followed by heat treatment and wherein the brightener is applied in the presence of a compound or mixture of compounds of formula I,rnh.sub.2 iwherein R is --OH, --NR.sub.1 R.sub.2 or ##STR1## X being O, S or NH, and R.sub.1 and R.sub.2 being, independently, hydrogen, C.sub.1-6 alkyl or C.sub.2-4 hydroxyalkyl,Which compounds are in free base or acid addition salt form or, when R is OH, in O-sulphonic acid form, and preparations for use in such process.

    摘要翻译： 公开了一种用于包含合成聚酰胺或由合成聚酰胺组成的基材的光学增亮方法，其中将荧光增白剂通过浸渍施加到基材上进行热处理，并且其中增亮剂在式I化合物或其混合物存在下使用， RNH2 I，其中R是-OH，-NR1R2或X是O，S或NH，R1和R2独立地是氢，C1-6烷基或C2-4羟烷基，哪种化合物是在无机碱或酸添加盐 形式，或当R为OH时，为O-磺酸形式，以及用于该方法的制剂。

    Triazolylstyrene compounds
    3.
    发明授权
    Triazolylstyrene compounds 失效
    三唑基苯乙烯化合物

    公开(公告)号：US4167629A

    公开(公告)日：1979-09-11

    申请号：US521642

    申请日：1974-11-07

    申请人： Fritz Fleck ,  Horst Schmid

    发明人： Fritz Fleck ,  Horst Schmid

    IPC分类号： C07D249/24 ,  C07D403/10 ,  C09B23/14

    CPC分类号： C07D249/24

    摘要： This invention relates to new di-triazolylstyrene derivatives, useful as optical brighteners for organic polymeric materials, especially when applied to or incorporated in synthetic fibres.

    摘要翻译： 本发明涉及新的二 - 三唑基苯乙烯衍生物，其可用作有机聚合物材料的荧光增白剂，特别是当应用于或掺入合成纤维中时。

    Sulfo group-free disazo and polyazo compounds containing at least two basic or cationic group and which are in metal-free or 2:1 metal complex form
    4.
    发明授权
    Sulfo group-free disazo and polyazo compounds containing at least two basic or cationic group and which are in metal-free or 2:1 metal complex form 失效

    公开(公告)号：US4468347A

    公开(公告)日：1984-08-28

    申请号：US361183

    申请日：1982-03-24

    申请人： Paul Doswald ,  Emil Moriconi ,  Helmut Moser ,  Horst Schmid

    发明人： Paul Doswald ,  Emil Moriconi ,  Helmut Moser ,  Horst Schmid

    IPC分类号： C09B44/06 ,  C09B62/08 ,  C09B62/09 ,  C09B44/04 ,  C09B44/08 ,  C09B45/24 ,  C09B45/28

    CPC分类号： C09B44/06 ,  C09B62/08 ,  C09B62/09

    摘要： Disazo and polyazo compounds of the formula ##STR1## wherein each A is independently ##STR2## andeach R.sub.1 and the ##STR3## radical to which it is attached, taken together, independently, are ##STR4## wherein ring B may be substituted by one substituent selected from halogen, C.sub.1-4 alkyl and C.sub.1-4 alkoxy, and each R.sub.3 is independently C.sub.1-4 alkyl, orwherein the ** denotes the carbon atom attached to X, or each A, R.sub.3 and the ##STR5## radical to which they are attached, taken together, independently, are each R.sub.1 and the ##STR6## radical to which it is attached, taken together, independently, are the radical of an aromatic carbocyclic or heterocyclic coupling component, ##STR7## wherein each R.sub.21 is independently halo, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,p is 0, 1 or 2,the * denotes the carbon atom attached to the --N.dbd.N-- radical, andthe ** denotes the carbon atom attached to X,eachA.sub.1 and A.sub.2 taken together are --O--Me--O--, wherein Me is copper, cobalt, iron, nickel, manganese or zinc, oreachA.sub.1 is hydroxy, andeachA.sub.2 is independently hydrogen, hydroxy or C.sub.1-4 alkoxy,X is a direct bond or a bridging radical,eachY is independently a direct bond, C.sub.1-4 alkylene, --CO--NH--(CH.sub.2).sub.m -***, --NH--CO--(CH.sub.2).sub.m *** or --SO.sub.2 --NR.sub.4 --(CH.sub.2).sub.m -***, wherein R.sub.4 is hydrogen or C.sub.1-4 alkyl,m is 1, 2, 3 or 4, and the *** denotes the carbon atom attached to the Z group, each Z is independently ##STR8## wherein A.sup..crclbar. is a non-chromophoric anion,m is 1, 2, 3 or 4, andp is 0, 1 or 2, andn is at least 2,with the provisos that (i) the compound is free of sulfo groups, and (ii) when the compound is in metal-free form, each A, R.sub.3 and the ##STR9## radical to which they are attached form a group of formula (b) and each R.sub.1 and the ##STR10## radical to which it is attached together form a 1-phenylpyrazole group the phenyl ring of which is substituted by one --Y--Z group, which compounds are useful for dyeing and printing paper, leather, textile materials comprising natural or regenerated cellulose (for example, cotton, mercerized cotton, alkali treated cotton, hemp, sisal, jute and flax) and fibers, yarns and textile materials comprising polyamide or polyester modified to contain acid groups.

    Thyristor having controllable emitter-base shorts
    5.
    发明授权
    Thyristor having controllable emitter-base shorts 失效
    晶闸管具有可控制的发射极 - 基极短路

    公开(公告)号：US4760432A

    公开(公告)日：1988-07-26

    申请号：US923867

    申请日：1986-10-28

    申请人： Michael Stoisiek ,  Horst Schmid ,  Helmut Strack

    发明人： Michael Stoisiek ,  Horst Schmid ,  Helmut Strack

    IPC分类号： H01L29/74 ,  H01L29/745 ,  H01L29/749

    CPC分类号： H01L29/7408 ,  H01L29/7455

    摘要： A thyristor having a pnpn semiconductor body comprising MISFET structures 9 and 12 through 16 which serve as controllable emitter base shorts formed at the edge side relative to one of the emitter layers and each of the structures is composed of a semiconductor region 9 inserted into the emitter layer which is contacted by an electrode 6 for the emitter layer 1 and also includes a subregion 12 of the adjacent base layer 2 and of an intervening channel region 13 which is formed of an edge zone of the emitter layer 1 and is also composed of a gate covering the channel region in an insulated manner. The gate also convers the subregion 12 of the base layer 2 and forms a MIS capacitor C1. A voltage generator 23 drives the gate 15 with a voltage which alternates between first and second values. At the change from the first voltage value which lies below the threshold value of the channel region 13 to the second voltage level which is close to the threshold voltage of the subregion 12 of the base layer, the thyristor ignites due to the shift in current of the MIS capacitor C1 which serves as the ignition current and, thus, when the change from the second to the first voltage occurs, the thyristor is quenched.

    摘要翻译： 具有pnpn半导体本体的晶闸管包括MISFET结构9和12至16，其用作可控发射极基极短路，其形成在相对于一个发射极层的边缘侧，并且每个结构由插入发射极的半导体区域9 层，其由发射极层1的电极6接触，并且还包括相邻基极层2的子区域12和由发射极层1的边缘区域形成的中间沟道区域13，并且还由 栅极以绝缘方式覆盖沟道区域。 门也对基层2的子区域12进行通信，形成MIS电容器C1。 电压发生器23以在第一和第二值之间交替的电压驱动门15。 在从低于通道区域13的阈值的第一电压值变化到接近于基极层子区域12的阈值电压的第二电压电平的情况下，晶闸管由于电流的偏移而点燃 用作点火电流的MIS电容器C1，因此当从第二电压到第一电压的变化发生时，晶闸管被淬火。

    Pyrazoline compounds useful as optical brighteners
    6.
    发明授权
    Pyrazoline compounds useful as optical brighteners 失效
    吡唑啉化合物可用作荧光增白剂

    公开(公告)号：US3988346A

    公开(公告)日：1976-10-26

    申请号：US586350

    申请日：1975-06-12

    申请人： Horst Schmid

    发明人： Horst Schmid

    IPC分类号： C09B57/00 ,  C07D231/06 ,  D06L3/12

    CPC分类号： C07D231/06

    摘要： Disclosed are optical brightening agents of formula I, ##SPC1##whereinR.sub.1 is hydrogen or chlorine,R.sub. 2 is hydrogen or methyl,R.sub.3 is hydrogen or C.sub.1.sub.-6 alkyl, andM is hydrogen or a non-chromophoric cation.

    摘要翻译： 公开了式I的荧光增白剂，其中R 1是氢或氯，R 2是氢或甲基，R 3是氢或C 1-6烷基，M是氢或非发色阳离子。

    Sulfo group-free disazo and polyazo compounds containing two 1-phenylpyrazol-5-one coupling component radicals and at least two basic or cationic groups
    8.
    发明授权
    Sulfo group-free disazo and polyazo compounds containing two 1-phenylpyrazol-5-one coupling component radicals and at least two basic or cationic groups 失效

    公开(公告)号：US4483796A

    公开(公告)日：1984-11-20

    申请号：US409164

    申请日：1982-08-18

    申请人： Paul Doswald ,  Emil Moriconi ,  Helmut Moser ,  Horst Schmid

    发明人： Paul Doswald ,  Emil Moriconi ,  Helmut Moser ,  Horst Schmid

    IPC分类号： C09B44/06 ,  C09B62/08 ,  C09B62/09 ,  C09B35/18 ,  C09B35/22 ,  C09B35/227 ,  C09B35/26

    CPC分类号： C09B44/06 ,  C09B62/08 ,  C09B62/09

    摘要： Disazo and polyazo compounds of the formula ##STR1## wherein each A is independently ##STR2## and each R.sub.3 is independently C.sub.1-4 alkyl, oreach A, R.sub.3 and the ##STR3## radical to which they are attached, taken together, independently, are ##STR4## wherein each R.sub.21 is independently halo, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,p is 0, 1 or 2,the * denotes the carbon atom attached to the --N.dbd.N-- radical, andthe ** denotes the carbon atom attached to X,each R.sub.1 and the ##STR5## radical to which it is attached taken together, independently, are the radical of an aromatic or heterocyclic coupling component,each A.sub.1 and A.sub.2 taken together are --O--Me--O--, wherein Me is copper, cobalt, iron, nickel, manganese or zinc, oreach A.sub.1 is hydroxy, andeach A.sub.2 is independently hydrogen, hydroxy or C.sub.1-4 alkoxy,X is a direct bond or a bridging radical,each Y is independently a direct bond, C.sub.1-4 alkylene, --CO--NH--(CH.sub.2).sub.m --, --NH--CO--(CH.sub.2).sub.m -- or --SO.sub.2 --NR.sub.4 --(CH.sub.2).sub.m --,whereinR.sub.4 is hydrogen or C.sub.1-4 alkyl,m is 1, 2, 3 or 4, andthe *** denotes the carbon atom attached to the Z group,each Z is independently ##STR6## wherein A.sup..crclbar. is a non-chromophoric anion,m is 1, 2, 3 or 4, andp is 0, 1, or 2, andn is at least 2,with the provisos that (i) the compound is free of sulfo groups, and (ii) when the compound is in metal-free form, each A, R.sub.3 and the ##STR7## radical to which they are attached form a group of formula (b) and each R.sub.1 and the ##STR8## radical to which it is attached together form a 1-phenylpyrazole group the phenyl ring of which is substituted by one --Y--Z group, which compounds are useful for dyeing and printing paper, leather, textile materials comprising natural or regenerated cellulose (for example, cotton, mercerized cotton, alkali treated cotton, hemp, sisal, jute and flax) and fibers, yarns and textile materials comprising polyamide or polyester modified to contain acid groups.