Preparation of block copolyether-ester-amides
    1.
    发明授权
    Preparation of block copolyether-ester-amides 失效
    嵌段共聚醚 - 酯 - 酰胺的制备

    公开(公告)号:US5280087A

    公开(公告)日:1994-01-18

    申请号:US7822

    申请日:1993-01-22

    CPC classification number: C08G69/44 C08G65/33317

    Abstract: Disclosed is a novel two-step reaction method for preparing block copolyether-ester-amides. In the first step, caprolactam or other lactam is reacted with a polyether polyol in the presence of a catalyst to form an amino-terminated prepolymer with both a polyamide hard segment and a polyether soft segment. In the second step, the prepolymer is reacted with a dicarboxylic acid as a chain extender to form high molecular weight block copolyether-ester-amides.The block copolyether-ester-amides prepared by this method are transparent, easily moldable by conventional processing methods such as extrusion and injection molding, and exhibit excellent mechanical properties.

    Abstract translation: 公开了一种制备嵌段共聚醚 - 酯 - 酰胺的新型两步反应方法。 在第一步中,己内酰胺或其它内酰胺与聚醚多元醇在催化剂存在下反应,形成具有聚酰胺硬链段和聚醚软链段的氨基封端的预聚物。 在第二步中,预聚物与作为扩链剂的二羧酸反应形成高分子量嵌段共聚醚 - 酯 - 酰胺。 通过该方法制备的嵌段共醚 - 酯 - 酰胺是透明的,通过常规加工方法如挤出和注射成型容易模塑,并且显示出优异的机械性能。

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