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公开(公告)号:US5236624A
公开(公告)日:1993-08-17
申请号:US547534
申请日:1990-06-29
Applicant: Andre Lepert , Jacques Mourand , Alain J. M. Rauline , Thierry Lapie , Jean L. Marchal , Graham Yeadon
Inventor: Andre Lepert , Jacques Mourand , Alain J. M. Rauline , Thierry Lapie , Jean L. Marchal , Graham Yeadon
IPC: C08J3/03
CPC classification number: C08J3/03 , C08J2395/00 , Y10S516/928
Abstract: Dispersions of hydrophobic substance e.s. resin emulsions, usually having a relatively low average particle size can be continuously and speedily prepared by feed a hydrophobic substance in the liquid state into at least two static mixers, arranged in a series. The resin is introduced at a temperature above 50 degrees C. but below its degradation temperature of hydrophobic substance and water under pressure is introduced into the first mixer. The mixture of resin and water is passed to another mixer maintained at a temperature lower than that prevailing in the first mixer and below the boiling point of water. Optionally aqueous solution of surfactant under pressure instead of water is introduced into the first mixer and optionally aqueous surfactant is introduced into the second mixer.
Abstract translation: 疏水物质的分散体e.s. 通常具有相对低的平均粒度的树脂乳液可以通过将液态的疏水性物质进料至至少两个串联的静态混合器中而连续且快速地制备。 树脂在高于50℃的温度下引入,但低于其在疏水物质的降解温度和压力下的水被引入到第一混合器中。 将树脂和水的混合物通入保持在低于第一混合器中并低于水沸点的温度的另一混合器。 任选将表面活性剂在压力下代替水的水溶液引入第一混合器中,并且任选地将水性表面活性剂引入第二混合器中。
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公开(公告)号:US09321938B2
公开(公告)日:2016-04-26
申请号:US13394883
申请日:2010-09-13
Applicant: Chan U. Ko , Dominique Wouters , Graham Yeadon , Prakash Mallya , Roger Maerki
Inventor: Chan U. Ko , Dominique Wouters , Graham Yeadon , Prakash Mallya , Roger Maerki
IPC: C09J133/02 , C09J7/02 , C08K5/3412 , C09J133/06
CPC classification number: C09J7/0217 , C08K5/3412 , C09J7/385 , C09J133/02 , C09J133/068 , C09J2205/102 , Y10T428/287 , C08L33/08
Abstract: Tackfied PSAs and tapes comprising a copolymer based on an acrylic backbone, with a glycidyl monomer, unsaturated carboxylic acid monomer and a tackifier, said adhesives being dual curable and having combination of outstanding peel adhesion on the LSE substrates, high temperature shear performance, excellent stress relieving properties and excellent converting properties.
Abstract translation: 包含基于丙烯酸骨架的共聚物与缩水甘油单体,不饱和羧酸单体和增粘剂的粘合的PSA和胶带,所述粘合剂是双重可固化的,并且具有LSE基材上出色的剥离粘合力,高温剪切性能,优异的应力 减轻性能和优异的转换性能。
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公开(公告)号:US06586510B1
公开(公告)日:2003-07-01
申请号:US09464055
申请日:1999-12-15
Applicant: Ian Brown , Graham Yeadon
Inventor: Ian Brown , Graham Yeadon
IPC: C08K510
CPC classification number: C09J133/08 , C08L91/06 , C08L2666/02 , C08L2666/28 , C09J7/38 , C09J7/385 , C09J133/06 , C09J2201/606 , C09J2203/334 , C09J2433/00 , Y10T428/2848 , Y10T428/2861 , Y10T428/2883 , Y10T428/2891 , Y10T428/31895 , Y10T428/31909
Abstract: Improved, removable PSA compositions and constructions contain an emulsion acrylic PSA copolymer of a plurality of acrylic monomers and at least one multifunctional crosslinking monomer, compounded with a wax and a plasticizer. Peel forces required to remove the constructions from a variety of substrates are notably smaller than those required to remove comparable compositions containing no crosslinking monomer.
Abstract translation: 改进的可拆卸PSA组合物和结构含有多种丙烯酸单体和至少一种与蜡和增塑剂混合的多官能交联单体的乳液丙烯酸PSA共聚物。 从各种底物去除结构所需的剥离力明显小于除去不含交联单体的可比组合所需的剥离力。
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公开(公告)号:US06569949B1
公开(公告)日:2003-05-27
申请号:US09586122
申请日:2000-06-02
Applicant: Ivan S. P Lee , Graham Yeadon , Paul Keller
Inventor: Ivan S. P Lee , Graham Yeadon , Paul Keller
IPC: C09J15104
CPC classification number: C09J133/08 , C09J2201/606
Abstract: Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges. The compositions may also contain one or more internal or external crosslinkers.
Abstract translation: 本发明提供了用于标记膜应用的压敏粘合剂组合物。 组合物包含通过至少一种单体混合物的乳液聚合制备的聚合物颗粒。 单体混合物包含至少一种丙烯酸烷基酯,其烷基具有约4至12个碳原子,优选约73%至90%重量的至少一种不饱和羧酸,其含有约3至 5个碳原子,优选约2重量%至12重量%的量,和至少一种硬单体,优选以约5重量%至15重量%的量存在。 如通过激光散射确定的,颗粒具有约300nm或更小的平均直径。 优选地,硬单体包括苯乙烯单体,更优选苯乙烯单体和甲基丙烯酸烷基酯。 在一些实施方案中,通过第一和第二单体电荷的顺序聚合制备组合物。 组合物还可以含有一种或多种内部或外部交联剂。
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公开(公告)号:US09914858B2
公开(公告)日:2018-03-13
申请号:US11437253
申请日:2006-05-19
Applicant: Eric L. Bartholomew , Christopher L. Lester , Roger Maerki , Alfredo Mueller , Graham Yeadon
Inventor: Eric L. Bartholomew , Christopher L. Lester , Roger Maerki , Alfredo Mueller , Graham Yeadon
IPC: C09J133/06 , C08F220/18 , C09J7/02
CPC classification number: C09J133/06 , C08F220/18 , C09J7/385 , C09J2203/334 , Y10T428/2891 , Y10T428/31935
Abstract: Water resistant, acrylic emulsion pressure sensitive adhesive polymers containing particles having a mean “volume-average” particle diameter of greater than about 210 nm for use in label and tape application are provided. The emulsion polymers exhibit an increase in opacity of less than about 10%.
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公开(公告)号:US09422465B2
公开(公告)日:2016-08-23
申请号:US12447478
申请日:2007-11-01
Applicant: Alfredo Mueller , Jos Van Noort , Graham Yeadon
Inventor: Alfredo Mueller , Jos Van Noort , Graham Yeadon
IPC: B32B27/30 , C08K5/17 , C08L33/02 , C09J133/08
CPC classification number: C09J133/08 , B32B7/12 , B32B27/06 , B32B38/10 , B32B43/006 , B32B2519/00 , C09J7/29 , C09J2201/122 , C09J2201/162 , C09J2201/606 , C09J2201/622 , C09J2203/334 , C09J2433/00 , Y10T156/1111 , Y10T156/1142 , Y10T156/1153 , Y10T428/24942 , Y10T428/2891
Abstract: This invention relates to removable pressure sensitive adhesive compositions and constructions that contain an emulsion acrylic pressure sensitive adhesive copolymer of a plurality of acrylic monomers and at least one polymerizable acid. The invention further relates to labels, particularly removable polymeric labels for use on reusable containers.
Abstract translation: 本发明涉及可移除的压敏粘合剂组合物和包含多种丙烯酸单体和至少一种可聚合酸的乳液丙烯酸压敏粘合剂共聚物的结构。 本发明还涉及用于可重复使用的容器的标签,特别是可拆卸的聚合物标签。
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公开(公告)号:US20100051200A1
公开(公告)日:2010-03-04
申请号:US12447478
申请日:2007-11-01
Applicant: Alfredo Mueller , Jos Van Noort , Graham Yeadon
Inventor: Alfredo Mueller , Jos Van Noort , Graham Yeadon
CPC classification number: C09J133/08 , B32B7/12 , B32B27/06 , B32B38/10 , B32B43/006 , B32B2519/00 , C09J7/29 , C09J2201/122 , C09J2201/162 , C09J2201/606 , C09J2201/622 , C09J2203/334 , C09J2433/00 , Y10T156/1111 , Y10T156/1142 , Y10T156/1153 , Y10T428/24942 , Y10T428/2891
Abstract: This invention relates to removable pressure sensitive adhesive compositions and constructions that contain an emulsion acrylic pressure sensitive adhesive copolymer of a plurality of acrylic monomers and at least one polymerizable acid. The invention further relates to labels, particularly removable polymeric labels for use on reusable containers.
Abstract translation: 本发明涉及可移除的压敏粘合剂组合物和包含多种丙烯酸单体和至少一种可聚合酸的乳液丙烯酸压敏粘合剂共聚物的结构。 本发明还涉及用于可重复使用的容器的标签,特别是可拆卸的聚合物标签。
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公开(公告)号:US20060263600A1
公开(公告)日:2006-11-23
申请号:US11437253
申请日:2006-05-19
Applicant: Eric Bartholomew , Christopher Lester , Roger Maerki , Alfredo Mueller , Graham Yeadon
Inventor: Eric Bartholomew , Christopher Lester , Roger Maerki , Alfredo Mueller , Graham Yeadon
IPC: C08F2/00 , C08F4/30 , C08F118/02 , B32B27/30
CPC classification number: C09J133/06 , C08F220/18 , C09J7/385 , C09J2203/334 , Y10T428/2891 , Y10T428/31935
Abstract: Water resistant, acrylic emulsion pressure sensitive adhesive polymers containing particles having a mean “volume-average” particle diameter of greater than about 210 nm for use in label and tape application are provided. The emulsion polymers exhibit an increase in opacity of less than about 10%.
Abstract translation: 提供了含有用于标签和胶带应用的具有大于约210nm的平均“体积平均”粒径的颗粒的耐水丙烯酸乳液压敏粘合剂聚合物。 乳液聚合物的不透明度增加小于约10%。
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公开(公告)号:US6147165A
公开(公告)日:2000-11-14
申请号:US37589
申请日:1998-03-09
Applicant: Ivan S. P. Lee , Graham Yeadon , Paul Keller
Inventor: Ivan S. P. Lee , Graham Yeadon , Paul Keller
IPC: C09J133/08 , C09J133/02
CPC classification number: C09J133/08 , C09J2201/606
Abstract: Inherently tacky, pressure-sensitive adhesive compositions useful in marking film applications are provided. The compositions comprise polymer particles prepared by emulsion polymerization of at least one monomer mixture. The monomer mixture comprises at least one alkyl acrylate, the alkyl group of which has from about 4 to 12 carbon atoms, preferably in an amount of from about 73% to 90% by weight, at least one unsaturated carboxylic acid containing from about 3 to 5 carbon atoms, preferably in an amount of from about 2% to 12% by weight, and at least one hard monomer, preferably present in an amount of from about 5% to 15% by weight. The particles have a mean diameter of about 300 nm or less, as determined by laser light scattering. Preferably the hard monomer comprises a styrenic monomer, more preferably both a styrenic monomer and an alkyl methacrylate. In some embodiments, the compositions are prepared by sequential polymerization of the first and second monomer charges. The compositions may also contain one or more internal or external crosslinkers.
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公开(公告)号:US20140124399A1
公开(公告)日:2014-05-08
申请号:US14131023
申请日:2012-07-05
Applicant: Graham Yeadon , Huig Van Der Bent , Jos Van Noort , Harald Becker , Edwin Van Delft
Inventor: Graham Yeadon , Huig Van Der Bent , Jos Van Noort , Harald Becker , Edwin Van Delft
IPC: C09J133/08 , C09J7/02 , B65D25/20
CPC classification number: C09J133/08 , B65D23/085 , B65D25/205 , C09J7/22 , C09J7/38 , C09J7/385 , C09J133/04 , C09J2201/622 , C09J2203/334 , C09J2423/106 , C09J2433/00 , Y10T428/2891
Abstract: Various adhesives are described that are resistant to relatively hot aqueous washing solutions and particularly to hot caustic solutions used in bottle washing applications. The adhesives are used to adhere polymeric labels to containers such as beverage bottles and thereby enable the labeled bottles to be subjected to multiple washing operations without label removal or debonding.
Abstract translation: 描述了耐受相对热水洗涤溶液,特别是用于瓶洗应用中的热苛性碱溶液的各种粘合剂。 粘合剂用于将聚合物标签粘附到诸如饮料瓶的容器上,从而使标记的瓶子经受多次洗涤操作,而无需标签去除或脱粘。
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