Adhesives comprising epoxy-acid crosslinked groups and methods
    8.
    发明授权
    Adhesives comprising epoxy-acid crosslinked groups and methods 有权
    包含环氧 - 酸交联基团的粘合剂和方法

    公开(公告)号:US09434866B2

    公开(公告)日:2016-09-06

    申请号:US14194840

    申请日:2014-03-03

    摘要: Adhesives compositions and methods of preparing adhesive compositions are described. The methods generally comprise a) providing a syrup composition comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic copolymer; and b) radiation curing the syrup composition in the absence of an ionic photoacid generator. In one embodiment, the solute (meth)acrylic copolymer as provided or during curing comprises repeat units derived from at least one alkyl(meth)acrylate monomer, at least one ethylenically unsaturated monomer comprising an acid-functional group; and at least one (meth)acryloyl monomer comprising an epoxy-functional group; and the acid-functional groups crosslink with the epoxy-functional groups. In another embodiment, the solute (meth)acrylic copolymer comprising repeat units derived from at least one alkyl(meth)acrylate monomer and at least one ethylenically unsaturated monomer comprising an acid-functional group; and an epoxy resin, having on average greater than one polymerizable epoxy group per molecule, crosslinks the acid-functional groups.

    摘要翻译: 描述了制备粘合剂组合物的粘合剂组合物和方法。 方法通常包括:a)提供糖浆组合物,其包含i)可自由基聚合的溶剂单体; 和ii)溶质(甲基)丙烯酸共聚物; 和b)在不存在离子型光酸产生剂的情况下辐射固化糖浆组合物。 在一个实施方案中,所提供的或在固化期间的溶质(甲基)丙烯酸共聚物包含衍生自至少一种(甲基)丙烯酸烷基酯单体的重复单元,至少一种包含酸官能团的烯属不饱和单体; 和至少一种包含环氧官能团的(甲基)丙烯酰基单体; 酸官能团与环氧官能团交联。 在另一个实施方案中,包含衍生自至少一种(甲基)丙烯酸烷基酯单体和至少一种包含酸官能团的烯属不饱和单体的重复单元的溶质(甲基)丙烯酸共聚物; 和每分子平均具有大于一个可聚合环氧基团的环氧树脂交联酸官能团。

    PRESSURE-SENSITIVE ADHESIVE COMPOSITION, CONDUCTIVE ADHESIVE COMPOSITION AND ADHESIVE TAPE MADE THEREFROM
    10.
    发明申请
    PRESSURE-SENSITIVE ADHESIVE COMPOSITION, CONDUCTIVE ADHESIVE COMPOSITION AND ADHESIVE TAPE MADE THEREFROM 有权
    压敏粘合剂组合物,导电粘合剂组合物及粘合胶带

    公开(公告)号:US20160230052A1

    公开(公告)日:2016-08-11

    申请号:US15022003

    申请日:2014-09-23

    摘要: The present invention provides a thermally curable pressure-sensitive adhesive composition, which, based on the total weight of the composition, comprises the following components: a) 35-99% by weight of a reactive polymethacrylate component having a glass transition temperature Tg of −35° C. to 32° C., and having a reactive functional group which can react with benzoxazine to form an interpenetrating polymer network; and b) 1-65% by weight of a benzoxazine component of the following formula: wherein: X is selected from the group consisting of a covalent bond, C1-C6 alkylene, C3-C10 cycloalkylene group, C═O, S, S═O or O═S═O R1 and R2 are the same or different and independently of each other selected from the group consisting of hydrogen, C1-C6 alkyl, or C5-C14 aryl, and R4 is selected from the group consisting of hydrogen, halogen or C1-C6 alkyl. The present invention also provides an electrically conductive adhesive composition and an adhesive tape comprising the above-described composition, and provides for the use of the composition for preparing membranes used for electronic and electrical products, automobile products and new energy equipment.

    摘要翻译: 本发明提供一种热固化型压敏粘合剂组合物,其基于组合物的总重量包含以下组分:a)35-99重量%的玻璃化转变温度Tg为 - 35℃至32℃,并具有可与苯并恶嗪反应形成互穿聚合物网络的反应性官能团; 和b)1-65重量%的下式的苯并恶嗪组分:其中:X选自共价键,C 1 -C 6亚烷基,C 3 -C 10亚环烷基,C = O,S,S = O或O = S = O R 1和R 2相同或不同且彼此独立地选自氢,C 1 -C 6烷基或C 5 -C 14芳基,R 4选自氢 ,卤素或C 1 -C 6烷基。 本发明还提供了一种导电粘合剂组合物和包含上述组合物的粘合带,并且提供了用于制备用于电子和电气产品,汽车产品和新能源设备的膜的组合物的用途。