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    Method of manufacturing a composite material
    1.
    发明授权
    Method of manufacturing a composite material 失效
    制造复合材料的方法

    公开(公告)号：US6110329A

    公开(公告)日：2000-08-29

    申请号：US215392

    申请日：1998-12-18

    Applicant: Helmut Holleck ,  Michael Stuber

    Inventor： Helmut Holleck ,  Michael Stuber

    IPC: C23C14/02 ,  C23C14/06 ,  C23C14/35

    CPC classification number: C23C14/0605 ,  C23C14/027

    Abstract: In a method of manufacturing a composite material structure consisting of a substrate with a layer of essentially pure sp.sup.2 - and sp.sup.3 -hybridized carbon with a sp.sup.3 -hybridized carbon proportion which increases toward the surface of the carbon layer, the carbon layer is deposited on the substrate by a PVD process using a magnetron sputtering apparatus in a process chamber in which an argon partial pressure of 0.6 to 1.0 pa is maintained and, during the carbon deposition, a bias voltage is maintained which is increased with increasing thickness of the layer from 0 to 300 volts.

    Abstract translation: 在制备复合材料结构的方法中，所述复合材料结构由具有基本上纯的sp2-和sp3杂化的碳的基底组成，其中sp3-杂化的碳比例朝向碳层的表面增加，碳层沉积在 通过使用磁控溅射装置的PVD工艺在基板中保持0.6至1.0Pa的氩分压，并且在碳沉积期间保持偏压，该偏置电压随着层的厚度从0增加而增加 至300伏。

    Protective coating for metallic substrates
    2.
    发明授权
    Protective coating for metallic substrates 失效
    金属基材的保护涂层

    公开(公告)号：US4835062A

    公开(公告)日：1989-05-30

    申请号：US836628

    申请日：1986-03-05

    Applicant: Helmut Holleck

    Inventor： Helmut Holleck

    IPC: C23C14/06 ,  C23C28/04

    CPC classification number: C23C28/044

    Abstract: A protective coating for metallic substrates consists of a plurality of layers having a total thickness ranging from 0.1 to 10.mu., an individual thickness for each layer ranging from 0.5 to 40 nm, and a total number of layers which does not exceed 20,000, each layer being comprised of one kind of at least two kinds of crystalline hard substances and being arranged in a sequentially alternating order with respect to the others, the crystalline hard substances having phase interfaces with respect to one another which are at least crystallographically partially coherent. In an alternate embodiment, the protective coating is a single layer which is a superfinely dispersed mixture of the crystalline hard substances. The multi-layered embodiment is provided by a method which includes positioning the metallic substrate in a physical vapor deposition apparatus; providing at least two cathodes in the apparatus, each cathode being comprised of a different kind of crystalline hard substance; continuously moving the metallic substrate sequentially past each cathode; and causing the vapor deposition of the crystalline hard substances on the metallic substrate as a protective coating having a plurality of layers. The single-layered embodiment is provided by an alternate method in which one cathode is provided and is comprised of at least two kinds of crystalline hard substances. These protective coatings have a resistance to wear which exceeds that for a coating comprised of any one of the crystalline hard substances alone.

    Abstract translation: 用于金属基底的保护涂层由总厚度为0.1-10μm的多个层组成，每一层的单独厚度为0.5〜40nm，层数总和不超过20,000层 由一种至少两种结晶硬质物质组成，并以相对于其它物质顺序交替排列的方式，所述结晶硬物质相互之间具有至少在晶体学部分相干的相界面。 在替代实施例中，保护涂层是单层，其是结晶硬物质的超细分散混合物。 多层实施例通过包括将金属基板定位在物理气相沉积设备中的方法来提供; 在设备中提供至少两个阴极，每个阴极由不同种类的结晶硬物质组成; 连续地将金属基板顺序地移动通过每个阴极; 并且使金属基体上的结晶硬物质气相沉积为具有多个层的保护涂层。 单层实施例由提供一种阴极并由至少两种结晶硬物质构成的替代方法提供。 这些保护涂层具有耐磨性，其超过单独使用任何一种结晶硬质物质的涂层。

    Hard alloy comprising one or more hard phases and a binary or multicomponent binder metal alloy
    3.
    发明授权
    Hard alloy comprising one or more hard phases and a binary or multicomponent binder metal alloy 失效
    包含一种或多种硬相和二元或多组分粘合剂金属合金的硬质合金

    公开(公告)号：US4432794A

    公开(公告)日：1984-02-21

    申请号：US286376

    申请日：1981-07-17

    Applicant: Helmut Holleck

    Inventor： Helmut Holleck

    IPC: C22C29/06 ,  C22C29/08 ,  C22C29/10 ,  C22C32/00 ,  B22F3/16 ,  C22C14/00 ,  C22C27/00 ,  C22C28/00

    CPC classification number: C22C32/0052 ,  C22C29/06 ,  C22C29/067

    Abstract: A hard alloy including at least one hard phase and a binary or multicomponent binder metal alloy, in which the hard substance comprises a finely dispersed, homogeneous distribution in the binder metal. The hard phase comprises a carbide of a Group IVb, Vb or VIb transition metal, and the binder metal alloy comprises a solid alloy of a Group IVb, Vb or VIb transition metal, with Re, Ru, Rh, Pd, Os, Ir, or Pt.

    Abstract translation: 包括至少一种硬相和二元或多组分粘合剂金属合金的硬质合金，其中所述硬质物质包含在所述粘合剂金属中的细分散均匀分布。 硬质相包括IVb族，Vb族或VIb族过渡金属的碳化物，并且该粘合剂金属合金包含IVb族，Vb族或VIb族过渡金属与Re，Ru，Rh，Pd，Os，Ir， 或Pt。

    Wear protection layer
    5.
    发明授权
    Wear protection layer 失效
    磨损保护层

    公开(公告)号：US06245446B1

    公开(公告)日：2001-06-12

    申请号：US08903682

    申请日：1997-07-31

    Applicant: Veit Schier ,  Helmut Holleck

    Inventor： Veit Schier ,  Helmut Holleck

    IPC: B32B1504

    CPC classification number: C23C28/044 ,  B32B18/00 ,  C04B2237/36 ,  C04B2237/361 ,  C04B2237/363 ,  C04B2237/366 ,  C04B2237/368 ,  C04B2237/704 ,  C23C28/42 ,  Y10T428/12576

    Abstract: In a wear protection layer comprising, disposed on a substrate, a plurality of individual layers including a first individual layer of a metallic hard material disposed directly on the substrate, periodically repeated composite arrangements of three individual layers comprising two individual layers of different metallic hard materials and one individual layer consisting of a covalent hard material are disposed on the first individual layer of a metallic hard material whereby the mechanical, physical and chemical properties of the metallic hard materials are combined with the properties of the covalent hard materials.

    Abstract translation: 在包括设置在基底上的磨损保护层中，包括直接设置在基底上的金属硬质材料的第一单独层的多个单独层，周期性地重复复合布置的三个单独的层，包括两层不同的金属硬质材料 并且由金属硬质材料的第一单层设置由共价硬质材料构成的一个单独的层，由此金属硬质材料的机械，物理和化学性质与共价硬质材料的性质相结合。

    Protective layer of hard material with homogeneous distribution of elements
    8.
    发明授权
    Protective layer of hard material with homogeneous distribution of elements 失效
    具有均质分布元素的硬质材料保护层

    公开(公告)号：US5182238A

    公开(公告)日：1993-01-26

    申请号：US335601

    申请日：1989-04-10

    Applicant: Helmut Holleck

    Inventor： Helmut Holleck

    IPC: C23C14/06 ,  C23C14/35

    CPC classification number: C23C14/0641 ,  C23C14/0635 ,  Y10T428/31678 ,  Y10T428/31815

    Abstract: A primarily crystalline, titanium-containing protective layer of hard material with homogeneous distribution of elements on the surfaces of a substrate material. The protective layer comprises a stabilized mixed phase having a crystal structure made of a metallic hard material which is at least one material selected from TiN and TiC and a covalent hard material which is at least one material selected from SiC and Si.sub.3 N.sub.4.

    Abstract translation: 一种主要结晶的含钛保护层的硬质材料，在基材表面上均匀分布元素。 保护层包括具有由金属硬质材料制成的晶体结构的稳定混合相，其为选自TiN和TiC中的至少一种材料，以及选自SiC和Si 3 N 4中的至少一种材料的共价硬质材料。

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