Electrolyte for lithium secondary battery comprising chelating agent and lithium secondary battery using the same
    3.
    发明授权
    Electrolyte for lithium secondary battery comprising chelating agent and lithium secondary battery using the same 有权
    包含螯合剂的锂二次电池用电解液和使用其的锂二次电池

    公开(公告)号:US07745056B2

    公开(公告)日:2010-06-29

    申请号:US12095845

    申请日:2006-12-01

    IPC分类号: H01M6/18

    摘要: Disclosed herein is an electrolyte for lithium secondary batteries comprising: a chelating agent, which forms complexes with transition metal ions in the battery, and at the same time does not react and coordinate with lithium ions; a non-aqueous solvent; and an electrolyte salt, as well as a lithium secondary battery comprising the electrolyte. The chelating agent, which is contained in the electrolyte for lithium secondary batteries, can suppress a side reaction in which transition metal ions are reduced and deposited as transition metals on the anode. Also, the chelating agent can suppress internal short-circuits in the battery and the resulting voltage drop of the battery and a reduction in the safety and performance of the battery, which can occur when transition metals are deposited on the anode.

    摘要翻译: 本发明公开了一种锂二次电池用电解液,其特征在于,包括螯合剂,其与电池中的过渡金属离子形成配合物,同时不与锂离子反应并配位; 非水溶剂; 和电解质盐,以及包含电解质的锂二次电池。 包含在用于锂二次电池的电解质中的螯合剂可以抑制过渡金属离子被还原并沉积在阳极上作为过渡金属的副反应。 此外,螯合剂可以抑制电池中的内部短路和电池的所得电压下降以及当在阳极上沉积过渡金属时可能发生的电池的安全性和性能的降低。

    LITHIUM IRON PHOSPHATE HAVING OLIVINE STRUCTURE AND METHOD FOR ANALYZING THE SAME
    5.
    发明申请
    LITHIUM IRON PHOSPHATE HAVING OLIVINE STRUCTURE AND METHOD FOR ANALYZING THE SAME 审中-公开
    具有OLIVINE结构的锂铁磷酸盐及其分析方法

    公开(公告)号:US20100261060A1

    公开(公告)日:2010-10-14

    申请号:US12709021

    申请日:2010-02-19

    摘要: Provided is an olivine-type lithium iron phosphate having a composition represented by Formula I, comprising 0.1 to 5% by weight of Li3PO4, and comprising no Li2CO3 or, if present, comprising Li2CO3 in an amount less than 0.25% by weight: Lii+aFe1−xMx(PO4−b)Xb (I) wherein M, X, a, x and b are as defined above.The lithium iron phosphate comprises no lithium carbonate (Li2CO3) or, if present, comprises the Li2CO3 in an extremely small amount, and comprises Li3PO4 having superior electrochemical stability, thermal stability and ionic conductivity, thus advantageously imparting high-temperature and storage stability as well as stability and rate properties to lithium secondary batteries, when used as a cathode active material for the lithium secondary batteries.

    摘要翻译: 本发明提供一种具有由式I表示的组成的橄榄石型磷酸铁锂,其包含0.1至5重量%的Li 3 PO 4,并且不包含Li 2 CO 3或如果存在,其包含少于0.25重量%的Li 2 CO 3:Li + aFe1-xMx(PO4-b)Xb(I)其中M,X,a,x和b如上所定义。 磷酸铁锂不包含碳酸锂(Li 2 CO 3),或者如果存在的话,极少量包含Li 2 CO 3,并且包含具有优异的电化学稳定性,热稳定性和离子导电性的Li 3 PO 4,因此有利地赋予高温和储存稳定性 作为锂二次电池的稳定性和速率特性,用作锂二次电池的正极活性物质。

    CATHODE MIX CONTAINING HAVING IMPROVED EFFICIENCY AND ENERGY DENSITY OF ELECTRODE
    6.
    发明申请
    CATHODE MIX CONTAINING HAVING IMPROVED EFFICIENCY AND ENERGY DENSITY OF ELECTRODE 有权
    含有改善效率和电极密度的阴极混合物

    公开(公告)号:US20100239909A1

    公开(公告)日:2010-09-23

    申请号:US12709011

    申请日:2010-02-19

    IPC分类号: H01M4/52

    摘要: Provided is a cathode mix for lithium secondary batteries, comprising a cathode active material having a composition represented by the following Formula I: LiFe(P1-XO4) (I) wherein a molar fraction (1-x) of phosphorus (P) is in the range of 0.910 to 0.999, to allow operational efficiency of the cathode active material to be leveled to a lower operational efficiency of an anode active material and improve energy density of the cathode active material.The cathode mix maximizes operational efficiency of batteries, minimizes electrode waste and thus reduces manufacturing costs of batteries. Furthermore, The cathode active material, wherein a molar fraction (1-x) of phosphorus (P) is lower than 1, according to the present invention contains both Fe2+ and Fe3+, thus advantageously causing no structural deformation, improving ionic conductivity, exhibiting superior rate properties, inhibiting IR drop upon charge/discharge, thereby imparting high energy density to batteries.

    摘要翻译: 提供一种用于锂二次电池的阴极混合物,其包含具有由下式I表示的组成的阴极活性材料:其中磷(P)的摩尔分数(1-x)在其中的LiFe(P1-XO4)(I) 范围为0.910至0.999,以使阴极活性材料的操作效率平衡至阳极活性材料的较低操作效率,并提高阴极活性材料的能量密度。 阴极混合物可最大限度地提高电池的运行效率,最大限度地减少电极浪费,从而降低电池的制造成本。 此外,根据本发明的磷(P)的摩尔分数(1-x)小于1的正极活性物质既含有Fe 2+和Fe 3+,因此有利地不引起结构变形,提高离子电导率,显示出优异的 速率特性,在充电/放电时抑制IR降低,从而赋予电池高的能量密度。

    Cathode active material for lithium secondary battery
    8.
    发明授权
    Cathode active material for lithium secondary battery 有权
    锂二次电池用阴极活性物质

    公开(公告)号:US08277980B2

    公开(公告)日:2012-10-02

    申请号:US12833518

    申请日:2010-07-09

    摘要: Provided is a cathode active material which is lithium transition metal oxide having an α-NaFeO2 layered crystal structure, wherein the transition metal is a blend of Ni and Mn, an average oxidation number of the transition metals except lithium is +3 or higher, and lithium transition metal oxide satisfies the Equation m(Ni)≧m(Mn) (in which m (Ni) and m (Mn) represent an molar number of manganese and nickel, respectively). The lithium transition metal oxide has a uniform and stable layered structure through control of oxidation number of transition metals to a level higher than +3, thus advantageously exerting improved overall electrochemical properties including electric capacity, in particular, superior high-rate charge/discharge characteristics.

    摘要翻译: 本发明提供一种正极活性物质,其为具有α-NaFeO 2层状结晶结构的锂过渡金属氧化物,其中,过渡金属为Ni和Mn的混合物,除锂以外的过渡金属的平均氧化数为+3以上, 锂过渡金属氧化物满足方程m(Ni)≥m(Mn)(其中m(Ni)和m(Mn)分别表示锰和镍的摩尔数)。 锂过渡金属氧化物通过将过渡金属的氧化数控制到高于+ 3的水平,具有均匀且稳定的层状结构,因此有利地实现包括电容在内的改进的整体电化学性质,特别是优异的高速率充电/放电特性 。

    CATHODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY
    9.
    发明申请
    CATHODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY 有权
    用于锂二次电池的阴极活性材料

    公开(公告)号:US20110140036A1

    公开(公告)日:2011-06-16

    申请号:US12833518

    申请日:2010-07-09

    IPC分类号: H01M4/86 C01G53/04

    摘要: Provided is a cathode active material which is lithium transition metal oxide having an α-NaFeO2 layered crystal structure, wherein the transition metal is a blend of Ni and Mn, an average oxidation number of the transition metals except lithium is +3 or higher, and lithium transition metal oxide satisfies the Equation m(Ni)≧m(Mn) (in which m (Ni) and m (Mn) represent an molar number of manganese and nickel, respectively). The lithium transition metal oxide has a uniform and stable layered structure through control of oxidation number of transition metals to a level higher than +3, thus advantageously exerting improved overall electrochemical properties including electric capacity, in particular, superior high-rate charge/discharge characteristics.

    摘要翻译: 本发明提供一种正极活性物质,其为具有α-NaFeO 2层状结晶结构的锂过渡金属氧化物,其中,过渡金属为Ni和Mn的混合物,除锂以外的过渡金属的平均氧化数为+3以上, 锂过渡金属氧化物满足方程m(Ni)≥m(Mn)(其中m(Ni)和m(Mn)分别表示锰和镍的摩尔数)。 锂过渡金属氧化物通过将过渡金属的氧化数控制到高于+ 3的水平,具有均匀且稳定的层状结构,因此有利地实现包括电容在内的改进的整体电化学性质,特别是优异的高速率充电/放电特性 。

    Cathode mix having improved efficiency and energy density of electrode
    10.
    发明授权
    Cathode mix having improved efficiency and energy density of electrode 有权
    具有提高电极效率和能量密度的阴极混合物

    公开(公告)号:US08962185B2

    公开(公告)日:2015-02-24

    申请号:US12709011

    申请日:2010-02-19

    摘要: Provided is a cathode mix for lithium secondary batteries, comprising a cathode active material having a composition represented by the following Formula I: LiFe(P1-XO4) (I) wherein a molar fraction (1−x) of phosphorus (P) is in the range of 0.910 to 0.999, to allow operational efficiency of the cathode active material to be leveled to a lower operational efficiency of an anode active material and improve energy density of the cathode active material.The cathode mix maximizes operational efficiency of batteries, minimizes electrode waste and thus reduces manufacturing costs of batteries. Furthermore, The cathode active material, wherein a molar fraction (1−x) of phosphorus (P) is lower than 1, according to the present invention contains both Fe2+ and Fe3+, thus advantageously causing no structural deformation, improving ionic conductivity, exhibiting superior rate properties, inhibiting IR drop upon charge/discharge, thereby imparting high energy density to batteries.

    摘要翻译: 提供一种用于锂二次电池的阴极混合物,其包含具有由下式I表示的组成的阴极活性材料:其中磷(P)的摩尔分数(1-x)在其中的LiFe(P1-XO4)(I) 范围为0.910至0.999,以使阴极活性材料的操作效率平衡至阳极活性材料的较低操作效率,并提高阴极活性材料的能量密度。 阴极混合物可最大限度地提高电池的运行效率,最大限度地减少电极浪费,从而降低电池的制造成本。 此外,根据本发明的磷(P)的摩尔分数(1-x)小于1的正极活性物质既含有Fe 2+和Fe 3+,因此有利地不引起结构变形,提高离子电导率,显示出优异的 速率特性,在充电/放电时抑制IR降低,从而赋予电池高的能量密度。