摘要:
Electrode assemblies for use in electrochemical cells are provided. The negative electrode assembly comprises negative electrode active material and an electrolyte chosen specifically for its useful properties in the negative electrode. These properties include reductive stability and ability to accommodate expansion and contraction of the negative electrode active material. Similarly, the positive electrode assembly comprises positive electrode active material and an electrolyte chosen specifically for its useful properties in the positive electrode. These properties include oxidative stability and the ability to prevent dissolution of transition metals used in the positive electrode active material. A third electrolyte can be used as separator between the negative electrode and the positive electrode.
摘要:
The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that is ionically conductive, mechanically robust, and can be formed into desirable shapes using conventional polymer processing methods. An exemplary polymer electrolyte material has an elastic modulus in excess of 1×106 Pa at 90 degrees C. and is characterized by an ionic conductivity of at least 1×10−5 Scm-1 at 90 degrees C. An exemplary material can be characterized by a two domain or three domain material system. An exemplary material can include material components made of diblock polymers or triblock polymers. Many uses are contemplated for the solid polymer electrolyte materials. For example, the present invention can be applied to improve Li-based batteries by means of enabling higher energy density, better thermal and environmental stability, lower rates of self-discharge, enhanced safety, lower manufacturing costs, and novel form factors.
摘要:
Electrode assemblies for use in electrochemical cells are provided. The negative electrode assembly comprises negative electrode active material and an electrolyte chosen specifically for its useful properties in the negative electrode. These properties include reductive stability and ability to accommodate expansion and contraction of the negative electrode active material. Similarly, the positive electrode assembly comprises positive electrode active material and an electrolyte chosen specifically for its useful properties in the positive electrode. These properties include oxidative stability and the ability to prevent dissolution of transition metals used in the positive electrode active material. A third electrolyte can be used as separator between the negative electrode and the positive electrode.
摘要:
Nanostructured gel polymer electrolytes that have both high ionic conductivity and high mechanical strength are disclosed. The electrolytes have at least two domains—one domain contains an ionically-conductive gel polymer and the other domain contains a rigid polymer that provides structure for the electrolyte. The domains are formed by block copolymers. The first block provides a polymer matrix that may or may not be conductive on by itself, but that can soak up a liquid electrolyte, thereby making a gel. An exemplary nanostructured gel polymer electrolyte has an ionic conductivity of at least 1×10−4 S cm−1 at 25° C.
摘要翻译:公开了具有高离子导电性和高机械强度的纳米结构凝胶聚合物电解质。 电解质具有至少两个结构域 - 一个结构域含有离子导电的凝胶聚合物,另一个结构域含有提供电解质结构的刚性聚合物。 这些结构域由嵌段共聚物形成。 第一个嵌段提供了一种聚合物基质,其本身可以是或可以不是导电的,但是可以吸收液体电解质,从而形成凝胶。 示例性的纳米结构凝胶聚合物电解质在25℃具有至少1×10 -4 S cm -1的离子电导率
摘要:
Nanostructured gel polymer electrolytes that have both high ionic conductivity and high mechanical strength are disclosed. The electrolytes have at least two domains—one domain contains an ionically-conductive gel polymer and the other domain contains a rigid polymer that provides structure for the electrolyte. The domains are formed by block copolymers. The first block provides a polymer matrix that may or may not be conductive on by itself, but that can soak up a liquid electrolyte, thereby making a gel. An exemplary nanostructured gel polymer electrolyte has an ionic conductivity of at least 1×10−4 S cm−1 at 25° C.
摘要翻译:公开了具有高离子导电性和高机械强度的纳米结构凝胶聚合物电解质。 电解质具有至少两个结构域 - 一个结构域含有离子导电的凝胶聚合物,另一个结构域含有提供电解质结构的刚性聚合物。 这些结构域由嵌段共聚物形成。 第一个嵌段提供了一种聚合物基质,其本身可以是或可以不是导电的,但是可以吸收液体电解质,从而形成凝胶。 示例性的纳米结构凝胶聚合物电解质在25℃具有至少1×10 -4 S cm -1的离子电导率
摘要:
An electrode assembly that includes an electrode film and a current collector is provided. The electrode film includes electrode active material, electronically conductive particles, and a solid polymer electrolyte. In some embodiments, no additional binder is used as the solid polymer electrolyte also acts as a binder to hold together the active material and electronically conductive particles, thus creating a freestanding electrode film. Such a freestanding film makes it possible to deposit a very thin current collector layer, thus increasing specific energy and specific power for electrochemical cells in which these electrode assemblies are used.
摘要:
One photovoltaic module includes a plurality of photovoltaic cells and at least one device selected from a sensor, a data storage device and an indicator. Another photovoltaic module includes a plurality of photovoltaic cells and a flexible circuit configured to act as an antenna for electromagnetic radiation. Methods of using such photovoltaic modules are also disclosed.
摘要:
A photovoltaic device having a first electrode layer, a high resistivity transparent film disposed on the first electrode, a second electrode layer, and an inorganic photoactive layer disposed between the first and second electrode layers, wherein the inorganic photoactive layer is disposed in at least partial electrical contact with the high resistivity transparent film, and in at least partial electrical contact with the second electrode. The photoactive layer has a first inorganic material and a second inorganic material different from the first inorganic material, wherein the first and second inorganic materials exhibit a type II band offset energy profile, and wherein the photoactive layer has a first population of nanostructures of a first inorganic material and a second population of nanostructures of a second inorganic material.
摘要:
One photovoltaic module includes a plurality of photovoltaic cells and at least one device selected from a sensor, a data storage device and an indicator. Another photovoltaic module includes a plurality of photovoltaic cells and a flexible circuit configured to act as an antenna for electromagnetic radiation. Methods of using such photovoltaic modules are also disclosed.
摘要:
An optimal architecture for a polymer electrolyte battery, wherein one or more layers of electrolyte (e.g., solid block-copolymer) are situated between two electrodes, is disclosed. An anolyte layer, adjacent the anode, is chosen to be chemically and electrochemically stable against the anode active material. A catholyte layer, adjacent the cathode, is chosen to be chemically and electrochemically stable against the cathode active material.