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公开(公告)号：US4048427A
公开(公告)日：1977-09-13
申请号：US680247
申请日：1976-04-26
摘要： This invention relates to the preparation of solution polymers and rubbers from vinyl monomers using a new catalyst complex of a barium di-tert-alkoxide-hydroxide salt and an organic lithium compound. In particular, homopolymers and copolymers of butadiene with styrene and/or isoprene, prepared with this catalyst, are uniquely characterized by the butadiene units having a low vinyl content (not over about 12%) and a trans-1,4 structure of from about 70 to 81%. Also, the copolymer has a random comonomer sequence distribution. This molecular structure permits elastomers containing little or no styrene to have sufficient stereoregularity to crystallize. Furthermore, the butadiene homopolymer and copolymer with styrene and/or isoprene exhibit a broad molecular weight distribution as well as tack and green-strength which are valuable properties for a rubber to possess when building tires.
摘要翻译： 本发明涉及使用新的二 - 叔 - 醇盐 - 氢氧化钡和有机锂化合物的催化剂络合物从乙烯基单体制备溶液聚合物和橡胶。 特别地，用该催化剂制备的丁二烯与苯乙烯和/或异戊二烯的均聚物和共聚物的独特特征在于具有低乙烯基含量（不超过约12％）的丁二烯单元和约 70〜81％。 此外，共聚物具有无规共聚单体序列分布。 该分子结构允许含有很少或不含苯乙烯的弹性体具有足够的立构规整性以结晶。 此外，丁二烯均聚物和与苯乙烯和/或异戊二烯的共聚物表现出宽的分子量分布以及粘性和生坯强度，这对于橡胶在制造轮胎时具有有价值的性质。
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公开(公告)号：US3992561A
公开(公告)日：1976-11-16
申请号：US593579
申请日：1975-07-07
IPC分类号： C08F4/00 , C07C27/00 , C07C31/30 , C07C67/00 , C07F3/00 , C08F2/00 , C08F2/04 , C08F2/06 , C08F4/06 , C08F4/10 , C08F4/42 , C08F4/46 , C08F4/50 , C08F12/06 , C08F36/00 , C08F36/04 , C08F36/06 , C08F36/08 , C08F4/72 , C08F12/08
摘要： This invention relates to the preparation of solution polymers and rubbers from vinyl monomers using a new catalyst complex of a barium di-tert-alkoxide-hydroxide salt and an organic lithium compound. In particular, homopolymers and copolymers of butadiene with styrene and/or isoprene, prepared with this catalyst, are uniquely characterized by the butadiene units having a low vinyl content (not over about 12%) and a trans-1,4 structure of from about 70 to 81%. Also, the copolymer has a random comonomer sequence distribution. This molecular structure permits elastomers containing little or no styrene to have sufficient stereoregularity to crystallize. Furthermore, the butadiene homopolymer and copolymer with styrene and/or isoprene exhibit a broad molecular weight distribution as well as tack and green-strength which are valuable properties for a rubber to possess when building tires.
摘要翻译： 本发明涉及使用新的二 - 叔 - 醇盐 - 氢氧化钡和有机锂化合物的催化剂络合物从乙烯基单体制备溶液聚合物和橡胶。 特别地，用该催化剂制备的丁二烯与苯乙烯和/或异戊二烯的均聚物和共聚物的独特特征在于具有低乙烯基含量（不超过约12％）的丁二烯单元和约 70〜81％。 此外，共聚物具有无规共聚单体序列分布。 该分子结构允许含有很少或不含苯乙烯的弹性体具有足够的立构规整性以结晶。 此外，丁二烯均聚物和与苯乙烯和/或异戊二烯的共聚物表现出宽的分子量分布以及粘性和生坯强度，这对于橡胶在制造轮胎时具有有价值的性质。
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公开(公告)号：US4020115A
公开(公告)日：1977-04-26
申请号：US679542
申请日：1976-04-23
摘要： This invention relates to the preparation of solution polymers and rubbers from vinyl monomers using a new catalyst complex of a barium di-tert-alkoxide-hydroxide salt and an organic lithium compound. In particular, homopolymers and copolymers of butadiene with styrene and/or isoprene, prepared with this catalyst, are uniquely characterized by the butadiene units having a low vinyl content (not over about 12%) and a trans-1,4 structure of from about 70 to 81%. Also, the copolymer has a random comonomer sequence distribution. This molecular structure permits elastomers containing little or no styrene to have sufficient stereoregularity to crystallize. Furthermore, the butadiene homopolymer and copolymer with styrene and/or isoprene exhibit a broad molecular weight distribution as well as tack and green-strength which are valuable properties for a rubber to possess when building tires.
摘要翻译： 本发明涉及使用新的二 - 叔 - 醇盐 - 氢氧化钡和有机锂化合物的催化剂络合物从乙烯基单体制备溶液聚合物和橡胶。 特别地，用该催化剂制备的丁二烯与苯乙烯和/或异戊二烯的均聚物和共聚物的独特特征在于具有低乙烯基含量（不超过约12％）的丁二烯单元和约 70〜81％。 此外，共聚物具有无规共聚单体序列分布。 该分子结构允许含有很少或不含苯乙烯的弹性体具有足够的立构规整性以结晶。 此外，丁二烯均聚物和与苯乙烯和/或异戊二烯的共聚物表现出宽的分子量分布以及粘性和生坯强度，这对于橡胶在制造轮胎时具有有价值的性质。
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4.发明授权
公开(公告)号：US3965080A
公开(公告)日：1976-06-22
申请号：US553716
申请日：1975-02-27
摘要： Organometallic compounds of high carbanion yield are prepared by metallation with barium, strontium or calcium or mixture of the same of certain acidic organic compounds having a pKa value of between about 15 and 35 on the MSAD scale in the presence of aprotic polar solvents, e.g., barium reacted with xanthene in 1,2-dimethoxyethane to yield dixanthenyl barium. Such organometallic compounds formed by metal-hydrogen exchange reaction are useful in initiating anionic growth-type polymerization of monomers, e.g., alkylene oxides and vinyl compounds, to form homopolymers and copolymers. The persistence of polymer carbanions created by such catalysts makes possible the controlled preparation of a variety of polymers, including block copolymers.
摘要翻译： 高碳负离子产率的有机金属化合物是通过在非质子极性溶剂的存在下，在MSAD标度上用钡，锶或钙或相同的具有约15至35的pKa值的某些酸性有机化合物的混合物进行金属化制备的， 钡与1,2-二甲氧基乙烷中的呫吨反应产生二苯基钡。 通过金属 - 氢交换反应形成的这种有机金属化合物可用于引发单体例如环氧烷和乙烯基化合物的阴离子生长型聚合以形成均聚物和共聚物。 由这种催化剂产生的聚合物碳阴离子的持久性使得可以控制制备各种聚合物，包括嵌段共聚物。
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公开(公告)号：US4033900A
公开(公告)日：1977-07-05
申请号：US679634
申请日：1976-04-23
摘要： This invention relates to the preparation of solution polymers and rubbers from vinyl monomers using a new catalyst complex of a barium di-tert-alkoxide-hydroxide salt and ann organic lithium compound. In particular, homopolymers and copolymers of butadiene with styrene and/or isoprene, prepared with this catalyst, are uniquely characterized by the butadiene units having a low vinyl content (not over about 12%) and a trans-1,4 structure of from about 70 to 81%. Also, the copolymer has a random comonomer sequence distribution. This molecular structure permits elastomers containing little or no styrene to have sufficient stereoregularity to crystallize. Furthermore, the butadiene homopolymer and copolymer with styrene and/or isoprene exhibit a broad molecular weight distribution as well as tack and green-strength which are valuable properties for a rubber to possess when building tires.
摘要翻译： 本发明涉及使用新的二 - 叔 - 醇盐 - 氢氧化钡和有机锂化合物的催化剂络合物从乙烯基单体制备溶液聚合物和橡胶。 特别地，用该催化剂制备的丁二烯与苯乙烯和/或异戊二烯的均聚物和共聚物的独特特征在于具有低乙烯基含量（不超过约12％）的丁二烯单元和约 70〜81％。 此外，共聚物具有无规共聚单体序列分布。 该分子结构允许含有很少或不含苯乙烯的弹性体具有足够的立构规整性以结晶。 此外，丁二烯均聚物和与苯乙烯和/或异戊二烯的共聚物表现出宽的分子量分布以及粘性和生坯强度，这对于橡胶在制造轮胎时具有有价值的性质。
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6.发明授权Alkaline earth metal organometallic compounds, their preparation by metallation and catalysts comprising same 失效碱土金属有机金属化合物，它们通过金属化制备和包含其的催化剂
公开(公告)号：US3966638A
公开(公告)日：1976-06-29
申请号：US524336
申请日：1974-11-15
IPC分类号： C07F3/00 , C08F4/00 , C08G65/12 , B01J31/12 , C07D311/82
摘要： Organometallic compounds of high carbanion yield are prepared by metallation with barium, strontium or calcium or mixture of the same of certain acidic organic compounds having a pKa value of between about 15 and 35 on the MSAD scale in the presence of aprotic polar solvents, e.g., barium reacted with xanthene in 1,2-dimethoxyethane to yield dixanthenyl barium. Such organometallic compounds formed by metal-hydrogen exchange reaction are useful in initiating anionic growth-type polymerization of monomers, e.g., alkylene oxides and vinyl compounds, to form homopolymers and copolymers. The persistence of polymer carbanions created by such catalysts makes possible the controlled preparation of a variety of polymers, including block copolymers.
摘要翻译： 高碳负离子产率的有机金属化合物是通过在非质子极性溶剂的存在下，在MSAD标度上用钡，锶或钙或相同的具有约15至35的pKa值的某些酸性有机化合物的混合物进行金属化制备的， 钡与1,2-二甲氧基乙烷中的呫吨反应产生二苯基钡。 通过金属 - 氢交换反应形成的这种有机金属化合物可用于引发单体例如环氧烷和乙烯基化合物的阴离子生长型聚合以形成均聚物和共聚物。 由这种催化剂产生的聚合物碳阴离子的持久性使得可以控制制备各种聚合物，包括嵌段共聚物。
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7.发明授权Alkaline earth metal organometallic compounds, their preparation by metallation and catalysts comprising same 失效碱土金属有机金属化合物，它们通过金属化制备和包含其的催化剂
公开(公告)号：US4012336A
公开(公告)日：1977-03-15
申请号：US681499
申请日：1976-04-29
CPC分类号： C08G65/12 , B01J31/122 , C07F3/00 , C08F4/00
摘要： Organometallic compounds of high carbanion yield are prepared by metallation with barium, strontium or calcium or mixture of the same of certain acidic organic compounds having a pKa value of between about 15 and 35 on the MSAD scale in the presence of aprotic polar solvents, e.g., barium reacted with xanthene in 1,2-dimethoxyethane to yield dixanthenyl barium. Such organometallic compounds formed by metal-hydrogen exchange reaction are useful in initiating anionic growth-type polymerization of monomers, e.g., alkylene oxides and vinyl compounds, to form homopolymers and copolymers. The persistence of polymer carbanions created by such catalysts makes possible the controlled preparation of a variety of polymers, including block copolymers.
摘要翻译： 高碳负离子产率的有机金属化合物是通过在非质子极性溶剂的存在下，在MSAD标度上用钡，锶或钙或相同的具有约15至35的pKa值的某些酸性有机化合物的混合物进行金属化制备的， 钡与1,2-二甲氧基乙烷中的呫吨反应产生二苯基钡。 通过金属 - 氢交换反应形成的这种有机金属化合物可用于引发单体例如环氧烷和乙烯基化合物的阴离子生长型聚合以形成均聚物和共聚物。 由这种催化剂产生的聚合物碳阴离子的持久性使得可以控制制备各种聚合物，包括嵌段共聚物。
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8.发明授权Rubber composition containing a thermoplastic polymer and tire sidewall component or tire support ring comprised of such rubber composition 失效含有热塑性聚合物和由这种橡胶组合物构成的轮胎侧壁部件或轮胎支承环的橡胶组合物公开(公告)号：US06646066B2
公开(公告)日：2003-11-11
申请号：US10098080
申请日：2002-03-14
IPC分类号： C08F28308
CPC分类号： B60C17/06 , B60C1/0025 , B60C15/06 , B60C17/0009 , C08L21/00 , C08L25/06 , C08L71/12 , C08L81/02 , C08L2666/02
摘要： This invention relates to rubber composition which contains a thermoplastic polymer and use thereof as a tire sidewall component and/or tread supporting ring for use in a tire/rim assembly. Such tire sidewall component may be a sidewall insert and/or apex of a rubber composition which contains a thermoplastic polymer.
摘要翻译： 本发明涉及含有热塑性聚合物的橡胶组合物及其用作轮胎/轮辋组件中使用的轮胎侧壁部件和/或胎面支撑环的用途。 这种轮胎侧壁部件可以是包含热塑性聚合物的橡胶组合物的侧壁插入件和/或顶点。
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