High-impact polyamide molding resin compositions
    2.
    发明授权
    High-impact polyamide molding resin compositions 失效
    高抗冲聚酰胺成型树脂组合物

    公开(公告)号:US4320213A

    公开(公告)日:1982-03-16

    申请号:US84441

    申请日:1979-10-24

    IPC分类号: C08L77/00

    CPC分类号: C08L77/00

    摘要: Polyamide molding resin compositions are prepared by melt-blending a polyamide resin, a hydroxyl-functional elastomer and a succinic-functional coupling agent. The invention includes a process fore preparing the molding resin and the molded resin product.

    摘要翻译: 通过熔融共混聚酰胺树脂,羟基官能弹性体和琥珀酸官能偶联剂制备聚酰胺模塑树脂组合物。 本发明包括一种制备模塑树脂和模制树脂产品的方法。

    Thermoplastic polyamide compositions
    4.
    发明授权
    Thermoplastic polyamide compositions 失效
    热塑性聚酰胺组合物

    公开(公告)号:US4501861A

    公开(公告)日:1985-02-26

    申请号:US462248

    申请日:1983-01-31

    申请人: James C. Woodbrey

    发明人: James C. Woodbrey

    IPC分类号: C08L77/02 C08L77/00

    CPC分类号: C08L77/02

    摘要: Polyamide compositions comprising:(a) poly(.epsilon.-caprolactam) resin of viscosity average molecular weight of at least about 15,000; and(b) at least one block polymer having(i) from about 25 to about 80 weight percent poly(.epsilon.-caprolactam) segments of the formula ##STR1## wherein x is an integer equal to 5 or more; and (ii) from about 75 to about 20 weight percent of segments having a number average molecular weight of at least 300 selected from the group consisting of segments of poly(propylene oxide), polycaprolactone, polytetrahydrofuran, polybutadiene, polyisoprene, polyisobutylene, poly(C.sub.1 -C.sub.8 alkylene acrylate), poly(C.sub.1 -C.sub.4 dialkylene siloxane), poly(ethylene-co-propylene), poly(ethylene-co-carbon monoxide), and combinations thereof; said (ii) segments being connected to an (i) polyamide segment through groups selected from amide, ester, urea, carbamate, and imide; provided that the composition contains from about 15 to about 85 weight percent of Component (a) and from about 85 to about 15 weight percent of Component (b).

    摘要翻译: 聚酰胺组合物包含:(a)粘均分子量至少约为15,000的聚(ε-己内酰胺)树脂; 和(b)至少一种嵌段聚合物,其具有(i)约25至约80重量%的式(IMAGE)的聚(ε-己内酰胺)部分,其中x是等于5或更大的整数; 和(ii)约75至约20重量%的数均分子量为至少300的链段,其选自聚环氧丙烷,聚己内酯,聚四氢呋喃,聚丁二烯,聚异戊二烯,聚异丁烯,聚( C1-C8亚烷基丙烯酸酯),聚(C1-C4二亚烷基硅氧烷),聚(乙烯 - 共 - 丙烯),聚(乙烯 - 共 - 一氧化碳)及其组合; (ii)段通过选自酰胺,酯,脲,氨基甲酸酯和酰亚胺的基团与(i)聚酰胺链段连接; 条件是组合物包含约15至约85重量%的组分(a)和约85至约15重量%的组分(b)。

    Thermoplastic polyamide compositions
    5.
    发明授权
    Thermoplastic polyamide compositions 失效
    热塑性聚酰胺组合物

    公开(公告)号:US4346200A

    公开(公告)日:1982-08-24

    申请号:US220939

    申请日:1980-12-29

    申请人: James C. Woodbrey

    发明人: James C. Woodbrey

    IPC分类号: C08G69/44 C08L77/00

    CPC分类号: C08G69/44 C08L77/00

    摘要: Polyamide compositions comprising:(a) at least one polyamide resin of number average molecular weight of at least 5000; and(b) at least one block polymer having(i) from about 30 to about 70 weight percent polyamide segments selected from ##STR1## wherein x is an integer equal to five or more and y is an integer equal to three or more;(ii) from about 70 to about 30 weight percent of segments having a molecular weight of at least 300 selected from the group consisting of segments of poly(ethylene oxide), poly(propylene oxide), polycaprolactone, polytetrahydrofuran, polybutadiene, polyisoprene, polyisobutylene, poly(C.sub.1 -C.sub.8 alkylene acrylate), poly(C.sub.1 -C.sub.4 dialkylene siloxane), poly(ethylene-co-propylene), poly(ethylene-co-carbon monoxide) and combinations thereof; said (ii) segments being connected to an (i) polyamide segment through groups selected from amide, ester, urea, carbamate and imide; and(iii) greater than 0.05 milliequivalents of ##STR2## groups per gram of (b); wherein Y and Z are alkylene having from about 3 to about 14 carbon atoms and X is arylene or alkylene having from about 3 to about 14 carbon atoms; provided that the composition contains from about 10 to about 90 weight percent of Component (a) and from about 90 to about 10 weight percent of Component (b).

    摘要翻译: 聚酰胺组合物,其包含:(a)至少一种数均分子量为至少5000的聚酰胺树脂; 和(b)至少一种嵌段聚合物,其具有(i)约30至约70重量%的选自“IMAGE”的聚酰胺片段,其中x为等于或大于5的整数,y为等于或大于3的整数; (ii)约70至约30重量%的分子量为至少300的链段,其选自聚环氧乙烷,聚(环氧丙烷),聚己内酯,聚四氢呋喃,聚丁二烯,聚异戊二烯,聚异丁烯 ,聚(C1-C8亚烷基丙烯酸酯),聚(C1-C4二亚烷基硅氧烷),聚(乙烯 - 共 - 丙烯),聚(乙烯 - 共 - 一氧化碳)及其组合; (ii)段通过选自酰胺,酯,脲,氨基甲酸酯和酰亚胺的基团与(i)聚酰胺链段连接; 和(iii)每克(b)大于0.05毫当量的组; 其中Y和Z是具有约3至约14个碳原子的亚烷基,X是亚芳基或具有约3至约14个碳原子的亚烷基; 条件是组合物含有约10至约90重量%的组分(a)和约90至约10重量%的组分(b)。

    Amino-functional photopolymer compositions and photo-oxidation imaging
processes employing same

    公开(公告)号:US4188223A

    公开(公告)日:1980-02-12

    申请号:US866133

    申请日:1977-12-30

    IPC分类号: G03F7/038 G03C1/68 G03C5/00

    CPC分类号: G03F7/0388 Y10S430/114

    摘要: The present invention relates to amino-functional photopolymer compositions and to photo-oxidation imaging processes utilizing such compositions. The amino-functional photopolymer compositions comprise amino-functional polymers and photosensitizing agents which, when exposed to electromagnetic radiation in the presence of ordinary molecular oxygen, are cured, thereby forming a less soluble polymer. Where the irradiation has been done selectively or in an imagewise fashion, the compositions allow for the development of an image by virtue of the solubility or redispersibility differential between the exposed and unexposed portions of the compositions. The amino-functional photopolymer may be any of a large variety of types, but generally will comprise a polymer with two or more amino-functional groups. The polymer may be a soluble polymer or a small-particle-size microgel cross-linked polymer. The photopolymer may also comprise mixtures of soluble polymer and small-particle-size microgel cross-linked polymer. The amino-functional photopolymer may be rubbery, leathery or glassy. The photosensitizer incorporated in the amino-functional photopolymer composition may be any of a large number of photosensitizers which stimulate the production of singlet molecular oxygen; for example, tetraphenyl porphorin (TPP) and its derivatives and salts, fluoranthene, dinaphthalene, thiophene, rose bengal, etc. By varying the photosensitizer used in the compositions, the amino-functional photopolymer composition in the presence of ordinary molecular oxygen may be made sensitive to photo-curing by ultraviolet or visible irradiation, including green light and red light. The compositions may contain other constituents in addition to the amino-functional polymer and photosensitizer. For example, other polymers or resins without amino-functionality may be incorporated to aid in adapting the compositions for use in particular applications as are discussed herein.

    Compositions of nylon and elastomers
    8.
    发明授权
    Compositions of nylon and elastomers 失效
    尼龙和弹性体的组成

    公开(公告)号:US4546147A

    公开(公告)日:1985-10-08

    申请号:US440772

    申请日:1982-11-10

    摘要: The present invention provides compositions which comprise a blend of: p0 (a) from about 10 to about 97 percent by weight of the composition of a polyamide resin having a minimum molecular weight of about 5,000; p0 (b) from about 3 to about 90 percent by weight of the composition of an elastomeric polymer which(1) is selected from a group consisting of poly(ethylene oxide), poly(propylene oxide), polycaprolactone, polytetrahydrofuran, polybutadiene, polyisoprene, polyisobutylene, poly(C.sub.1 -C.sub.8 alkylene acrylate), poly(C.sub.1 -C.sub.4 dialkylene siloxane), poly(ethylene-co-propylene), poly(ethylene-co-carbon monoxide), polyethylene-co-vinyl chloride, and poly(ethylene-co-vinyl acetate) polymers and copolymers and combinations thereof; and(2) contains a minimum of about 0.055 milliequivalents of acyllactam groups per gram of said elastomeric polymer.

    摘要翻译: 本发明提供了包含以下组合物的组合物:p0(a)约10至约97重量%的组合物,具有最小分子量约5,000的聚酰胺树脂; (1)选自聚环氧乙烷,聚(环氧丙烷),聚己酸内酯,聚四氢呋喃,聚丁二烯,聚异戊二烯的聚合物 ,聚异丁烯,聚(C1-C8亚烷基丙烯酸酯),聚(C1-C4二亚烷基硅氧烷),聚(乙烯 - 共 - 丙烯),聚(乙烯 - 共 - 一氧化碳),聚乙烯 - 共 - 氯乙烯和聚( 乙烯 - 共 - 乙酸乙烯酯)聚合物和共聚物及其组合; 和(2)每克所述弹性体聚合物含有至少约0.055毫当量的酰基内酰胺基团。

    Amino-functional photopolymer compositions and photo-oxidation imaging
processes employing same
    10.
    发明授权
    Amino-functional photopolymer compositions and photo-oxidation imaging processes employing same 失效
    氨基官能的光聚合物组合物和使用其的光氧化成像方法

    公开(公告)号:US4234674A

    公开(公告)日:1980-11-18

    申请号:US64978

    申请日:1979-08-08

    CPC分类号: G03F7/0388 Y10S430/114

    摘要: The present invention relates to amino-functional photopolymer compositions and to photo-oxidation imaging processes utilizing such compositions. The amino-functional photopolymer compositions comprise amino-functional polymers. For example, other polymers or resins without amino-functionality may be incorporated to aid in adapting the compositions for use in particular applications as are discussed herein.

    摘要翻译: 本发明涉及氨基官能的光聚合物组合物和利用这种组合物的光氧化成像方法。 氨基官能的光聚合物组合物包含氨基官能的聚合物。 例如,可以引入其它没有氨基官能团的聚合物或树脂以帮助适配用于特定应用的组合物,如本文所讨论的。