摘要:
Provided are an electrode active material having a plurality of pores and a secondary battery including the same, and more particularly, a porous electrode active material including silicon-based oxide expressed by SiOx (0.5≦x≦1.2) and having a Brunauer, Emmett, and Teller (BET) specific surface area ranging from 2 m2/g to 100 m2/g, and a secondary battery including a cathode including a cathode active material, a separator, an anode including an anode active material, and an electrolyte, in which the anode active material includes a porous electrode active material including silicon-based oxide expressed by SiOx (0.5≦x≦1.2) and having a BET specific surface area ranging from 2 m2/g to 100 m2/g.
摘要:
An anode active material for a lithium secondary battery and a lithium secondary battery having the same are disclosed. The anode active material for a lithium secondary battery includes a silicon alloy consisting of silicon and at least two kinds of metals other than silicon, each having the heat of mixing with the silicon of −23 kJ/mol or less. The anode active material for a lithium secondary battery has a high capacity, and thus, is useful in fabricating a high-capacity lithium secondary battery. Also, the anode active material for a lithium secondary battery has a small crystal size of a silicon phase and consequently a small change in volume during charging/discharging, and thus, ensures excellent cycle life characteristics in applications to batteries.
摘要:
Disclosed herein is a cathode active material for a lithium secondary battery, including lithium transition metal oxide, where the lithium transition metal oxide is coated with carbon particles and a polymer resin at a surface thereof, and the polymer resin is a substance inactivated by an electrolyte for a lithium secondary battery and an organic solvent and has a melting point of at least 80° C. A lithium secondary battery having the disclosed cathode active material has advantages of improving rate properties and high temperature stability, so as to provide excellent cell characteristics.
摘要:
The present invention provides a method of preparing a negative active material for a rechargeable lithium battery, comprising the steps of: mixing a silicon precursor, a surfactant comprising an ammonium halide salt having a organic group, an initiator, and a solvent; heat-treating the mixture; cooling the heat-treated mixture to room temperature; washing the cooled, heat treated mixture; and calcining the washed product.
摘要:
A cable-type secondary battery includes an electrode assembly, which has a first polarity current collector having a long and thin shape, at least two first polarity electrode active material layers formed on the first polarity current collector to be spaced apart in the longitudinal direction, an electrolyte layer filled to surround at least two first polarity electrode active material layers, at least two second polarity electrode active material layers formed on the electrolyte layer to be spaced apart at positions corresponding to the first polarity electrode active material layers, the electrode assembly being continuously bent into a serpentine configuration by a space between the first polarity electrode active material layers; a second polarity current collector configured to surround at least one side of the electrode assembly bent into a serpentine configuration; and a cover member configured to surround the second polarity current collector and the electrode assembly.
摘要:
Disclosed herein is an integrated electrode assembly including a cathode, an anode, and a separation layer disposed between the cathode and the anode. The cathode, the anode, and the separation layer are integrated with each other. The separation layer includes 3 phases including a liquid-phase component containing an ionic salt, a solid-phase component supporting the separation layer between the cathode and the anode, and a polymer matrix in which linear polymers and cross-linked polymers form a viscoelastic structure with the liquid-phase component and the solid-phase component being incorporated in the polymer matrix. The polymer matrix is coupled to each of the cathode and the anode. The liquid-phase component of the separation layer flows into the electrodes (i.e., the cathode and anode) during preparation of the integrated electrode assembly to greatly improve wetting properties of the electrodes and to increase ionic conductivity of the electrodes.
摘要:
Disclosed herein is an electrode active material for a secondary battery, and more particularly to an electrode active material comprising a porous silicon oxide-based composite and the method for preparing a porous silicon oxide-based composite.
摘要:
Provided is a cable-type secondary battery including an electrode assembly having a horizontal cross section of a predetermined shape and extending longitudinally, and a wire-type outer current collector wound on the outer surface of the electrode assembly, the electrode assembly including an inner current collector, an anode active material layer, and an electrolyte layer, and a cathode active material layer; the wire-type outer current collector has excellent flexibility and a predetermined level of elasticity, and thus, improves the flexibility of the entire cable-type secondary battery and prevents a short circuit from occurring and the active material from falling off from the active material layer, due to the deformation of the cable-type secondary battery.