摘要:
The present invention relates to evenly substituted polysaccharide derivatives having the general structure: polysaccharide—O—R wherein polysaccharide—O represents a substituted or unsubstituted polysaccharide unit and R is a substituent of a polysaccharide-OH group having either the structure R=—A—B— or the structure R=—B—, wherein A is a linear polyether chain having the following structure: A=(—D—O—)n wherein D denotes a linear aliphatic branched or unbranched chain having 2 to 12 C atoms, O represents an oxygen atom and n is a number equal to or greater than 1, and B represents a substituted carbamic acid having the structure wherein E denotes a linear or branched aliphatic chain having 1 to 18 C atoms.
摘要:
In a process for purifying crude pyrrolidine to give a pyrrolidine composition comprising more than 99% (m/m) of pyrrolidine and less than 0.3% (m/m) of water, crude pyrrolidine comprising from 40 to 98% (m/m) of pyrrolidine and having a water content of more than 2% (m/m) is subjected to continuous distillation at a pressure at the top of less than 950 hPa in a column having a stripping section and a rectifying section.
摘要:
The invention concerns novel plant-treatment agents comprising: at least one thermoplastically processable biodegradable polyester amide, optionally in a mixture with one or a plurality of further thermoplastically processable, biodegradable polymer components; at least one agrochemical substance; and optionally additives. The invention further concerns a process for preparing these agents, and their use in the application of agrochemical substances.
摘要:
A process for preparing pyrroles of the formula I: ##STR1## where R.sub.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and are hydrogen atoms, alkyl groups having from 1 to 12 carbon atoms or cycloalkyl groups having from 3 to 12 carbon atoms, by dehydrogenation of pyrrolidines of the formula II: ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are as defined above, in the presence of a supported noble metal catalyst is described. In this process, the dehydrogenation is carried out at from 150 to 300.degree. C. and pressures of from 0.01 to 50 bar and the noble metal catalyst comprises from 30 to 100% by weight of:a) palladium on an oxide of a rare earth or an oxide of an element of the 4.sup.th group (transition group IV) of the Periodic Table, orb) a platinum/palladium mixture on aluminum oxide, an oxide of a rare earth or an oxide of an element of the 4.sup.th groupand from 0 to 70% by weight of alkali metal oxide or alkaline earth metal oxide.
摘要:
Optically active amines are racemized by reaction of the optically active amine in the gas phase at elevated temperature in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst.
摘要:
In a process for racemizing optically active amines by reacting the optically active amine in the presence of hydrogen and a hydrogenation or dehydrogenation catalyst at elevated temperature, the reaction is carried out in liquid phase and the catalyst comprises the catalytically active constituents copper, silver, iron, cobalt, nickel, ruthenium, rhodium, palladium, osmium, iridium and/or platinum and a support material selected from the group consisting of aluminum oxide, zirconium dioxide, titanium dioxide, carbon and/or oxygen compounds of silicon.
摘要:
A process for the preparation of racemic amines of the formula I ##STR1## where R.sup.1 and R.sup.2 are different and R.sup.1, R.sup.2, R.sup.3 are alkyl, cycloalkyl, arylalkyl, aryl, heteroaryl and heterocyclic radicals and R.sup.3 can also be hydrogen, where the radicals can bear substituents selected from the group consisting of alkyl, cycloalkyl, alkoxy, aryloxy, amino, alkylamino and dialkylamino, which comprises simultaneously reacting in situ the corresponding optically active amine I and the secondary alcohol of the formula II and/or the unsymmetrical ketone of the formula III ##STR2## and the amine of the formula R.sup.3 NH.sub.2 in the presence of hydrogen and a hydrogenation catalyst or dehydrogenation catalyst at elevated temperature.
摘要:
An apparatus for developing photographic material having a delivery device and a removal device for developing fluid as well as an inlet and an outlet for the material to be developed with a narrow conduit that extends from the inlet to the outlet. A transport mechanism for transporting the photographic material to be developed from the inlet through the conduit to the outlet wherein the material to be developed comes into contact with the developing fluid as it is transported through the conduit and is developed. Two half shells are connectable to one another, with each half shell having two plates joined to make the half shell. The apparatus also has a central positive displacement element, which together with the inner wall of the half shells, defines the conduit in which the photographic material is developed. The conduit extends between the positive displacement element and the respective inner wall of the half shell. The inner wall of the positive displacement element is embodied substantially as a flat face, while the outer wall reinforces the inner wall in order to prevent deformation of the inner wall by the high pressure of the developing fluid.
摘要:
The present invention relates to a process for preparing ethylene urea in solid form, in which a water-comprising product melt of ethylene urea is cooled on a breaking-up apparatus and the water content of the solid obtained is from 5 to 15% by weight. Furthermore, the invention relates to ethylene urea as solid prepared by a process according to the invention, wherein the water content of the solid is from 5 to 15% by weight and the solid displays lasting powder flow.
摘要:
The present invention relates to a process for preparing ethylene urea in solid form, in which a water-comprising product melt of ethylene urea is cooled on a breaking-up apparatus and the water content of the solid obtained is from 5 to 15% by weight. Furthermore, the invention relates to ethylene urea as solid prepared by a process according to the invention, wherein the water content of the solid is from 5 to 15% by weight and the solid displays lasting powder flow.