Process for the preparation of a 2-pyrrolidone
    1.
    发明授权
    Process for the preparation of a 2-pyrrolidone 失效
    制备2-吡咯烷酮的方法

    公开(公告)号:US4325872A

    公开(公告)日:1982-04-20

    申请号:US218465

    申请日:1980-12-22

    CPC分类号: C07D201/08 Y02P20/584

    摘要: An improved method for hydrogenating succinonitrile, optionally carrying substituents, to form 2-pyrrolidones, in the liquid phase in the presence of ammonia, using a fixed-bed catalyst wherein the catalyst may be regenerated by successively passing liquid ammonia at 75.degree.-130.degree. C., then hydrogen at 130.degree.-350.degree. C., and then liquid ammonia again at 75.degree.-130.degree. C. over the catalyst.

    摘要翻译: 使用固定床催化剂,在氨水存在下,在液相中氢化丁腈橡胶(任选携带取代基)形成2-吡咯烷酮的改进方法,其中催化剂可以通过在75°-130℃依次通过液氨而再生 然后在130-350℃下加入氢气,然后在75°-130℃再次加入氨水,过催化剂。

    Process for preparing 2-pyrrolidone
    2.
    发明授权
    Process for preparing 2-pyrrolidone 失效
    制备2-吡咯烷酮的方法

    公开(公告)号:US4193925A

    公开(公告)日:1980-03-18

    申请号:US4474

    申请日:1979-01-18

    CPC分类号: C07D207/267 C07D201/08

    摘要: An improved process for the preparation of 2-pyrrolidone by the liquid phase hydrogenation of succinonitrile in the presence of a hydrogenation catalyst and ammonia, whereafter the resulting hydrogenation product is hydrolyzed with water. A hydrogenation catalyst in the form of a fixed bed is used, and a liquid phase of succinonitrile and liquid ammonia is passed over the catalyst at a temperature of between 50.degree. and 130.degree. C.

    摘要翻译: 通过在加氢催化剂和氨的存在下丁二腈的液相氢化制备2-吡咯烷酮的改进方法,之后所得的氢化产物用水水解。 使用固定床形式的氢化催化剂,在50-130℃的温度下使琥珀腈和液氨的液相通过催化剂。

    Process for preparing 2-pyrrolidones
    4.
    发明授权
    Process for preparing 2-pyrrolidones 失效
    制备2-吡咯烷酮的方法

    公开(公告)号:US4279820A

    公开(公告)日:1981-07-21

    申请号:US136115

    申请日:1980-03-27

    CPC分类号: C07D201/08

    摘要: 2-pyrrolidones are prepared by hydrogenating a succinonitrile in the liquid phase in the presence of ammonia by passing an ammoniacal solution of a succinonitrile over a fixed bed catalyst, particularly of the trickle-phase type, in which the catalyst is nickel on an alkaline support such as calcium hydroxide or calcium carbonate. Attractive yields are achieved without the expense of filtering off and separating used catalyst as in prior procedures.

    摘要翻译: 通过使琥珀腈的氨溶液通过固定床催化剂,特别是涓流相类型的催化剂为镍的碱性载体上的氨水溶液,在氨的存在下,通过在液相中氢化丁二腈而制备2-吡咯烷酮 例如氢氧化钙或碳酸钙。 无需像过去的程序那样过滤和分离使用过的催化剂,就可以实现有吸引力的产率。