公开(公告)号：US20100190635A1

公开(公告)日：2010-07-29

申请号：US12751321

申请日：2010-03-31

申请人： Kevin P. Kelly ,  James R. Butler

发明人： Kevin P. Kelly ,  James R. Butler

IPC分类号： B01J29/06

CPC分类号： C07C2/66 ,  B01J29/061 ,  B01J29/7057 ,  B01J37/0009 ,  B01J2229/42 ,  C07C15/073

摘要： A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethylbenzene.

摘要翻译： 提供了包含金属/沸石的金属改性烷基化催化剂，其中金属是选自钇和除了铈之外的镧系稀土稀土的一种或两种。 在使用两种金属的情况下，可以使用Ce或La，金属促进的沸石可用作通过苯在液相或临界相中乙基化生产乙苯的分子筛芳烃烷基化催化剂。 生产含有乙苯作为主要产物的烷基化产物，伴随着生产不超过乙苯的10-60重量％的较重的烷基化副产物。

公开(公告)号：US06972047B2

公开(公告)日：2005-12-06

申请号：US10750438

申请日：2003-12-31

申请人： James R. Butler ,  Kevin P. Kelly ,  Paul J. Buras ,  Bill Lee

发明人： James R. Butler ,  Kevin P. Kelly ,  Paul J. Buras ,  Bill Lee

IPC分类号： C08L95/00 ,  C10C3/00 ,  C09D195/00

CPC分类号： C08L95/00

摘要： It has been discovered that a synthetic flux oil can contain and deliver asphaltites, such as gilsonite, more easily and readily to an asphalt to improve its properties. The synthetic flux oil includes the asphaltite and a carrier oil. Depending on the nature of the carrier oil, the synthetic flux oil may or may not need to be heated during mixing and incorporation into the asphalt.

公开(公告)号：US06767939B2

公开(公告)日：2004-07-27

申请号：US10140317

申请日：2002-05-07

申请人： James R. Butler ,  Kevin P. Kelly ,  Paul Buras

发明人： James R. Butler ,  Kevin P. Kelly ,  Paul Buras

IPC分类号： C08L9500

CPC分类号： C08L95/00 ,  C08L2666/02 ,  C08L25/00 ,  C08L33/00 ,  C08L2666/04 ,  C08L53/00 ,  C08L2666/08

摘要： The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt. Crosslinking agents include compositions of mercaptobenzothiazole, zinc oxide and elemental sulfur; compositions of mercaptobenzothiazole, zinc oxide, and mixed polythiomorpholine; and compositions of zinc 2-mercaptobenzothiazole and dithiodimorpholine.

摘要翻译： 本发明提供一种制备沥青和热塑性弹性体组合物的方法。 该方法包括将在搅拌槽中切割的沥青加热到足以允许在罐中搅拌沥青的温度。 在沥青中继续搅拌沥青时，加入热塑性弹性体或橡胶。 将混合物以足以增加弹性体分配到沥青中的速度搅拌一段时间。 搅拌速度降低，温度升高，向罐中加入交联剂。 搅拌持续一段时间，足以改善沥青中交联剂分散体的分布。 交联剂包括巯基苯并噻唑，氧化锌和元素硫的组合物; 巯基苯并噻唑，氧化锌和混合多硫代吗啉的组成; 和2-巯基苯并噻唑锌和二硫代二吗啉的组合物。

公开(公告)号：US06180697B2

公开(公告)日：2001-01-30

申请号：US09389785

申请日：1999-09-04

申请人： Kevin P. Kelly ,  James R. Butler

发明人： Kevin P. Kelly ,  James R. Butler

IPC分类号： C08L9500

CPC分类号： C08L95/00 ,  C08L2666/04 ,  C08L53/00

摘要： The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.

摘要翻译： 本发明提供一种制备沥青和热塑性弹性体组合物的方法。 该方法包括将在搅拌槽中切割的沥青加热到足以允许在罐中搅拌沥青的温度。 在沥青中继续搅拌沥青时，加入热塑性弹性体或橡胶。 将混合物以足以增加弹性体分配到沥青中的速度搅拌一段时间。 搅拌速度降低，温度升高，向罐中加入交联剂的油分散体。 搅拌持续一段时间，足以改善沥青中交联剂分散体的分布。

公开(公告)号：US5308481A

公开(公告)日：1994-05-03

申请号：US892307

申请日：1992-06-02

申请人： David L. Stalling ,  Congyuan Guo ,  Kenneth C. Kuo ,  Kevin P. Kelly ,  Said Saim

发明人： David L. Stalling ,  Congyuan Guo ,  Kenneth C. Kuo ,  Kevin P. Kelly ,  Said Saim

IPC分类号： B01D15/08 ,  B01J20/32 ,  G01N30/52

CPC分类号： B01D15/08 ,  B01J20/3204 ,  B01J20/3212 ,  B01J20/3219 ,  B01J20/324 ,  G01N2030/484 ,  G01N2030/528 ,  Y10S977/735 ,  Y10S977/753 ,  Y10S977/835

摘要： The present invention relates to buckminsterfullerenes or related condensed carbon molecules covalently bonded to a polymer particle or a siliceous support particle and their use for packing media for column chromatography.

摘要翻译： 本发明涉及共价键合到聚合物颗粒或硅质载体颗粒上的巴克明斯特富勒烯或相关的冷凝碳分子及其用于柱层析的培养基的用途。

公开(公告)号：US07419929B2

公开(公告)日：2008-09-02

申请号：US11195003

申请日：2005-08-02

申请人： Kevin P Kelly ,  James R. Butler

发明人： Kevin P Kelly ,  James R. Butler

IPC分类号： B01J20/34

CPC分类号： B01J29/90 ,  B01J29/7057 ,  B01J38/14 ,  C07C2/66 ,  C07C6/126 ,  C07C2529/08 ,  C07C2529/70 ,  Y02P20/584 ,  C07C15/073

摘要： A process for the production of ethylbenzene by the ethylation of benzene in the critical phase over a molecular sieve aromatic alkylation catalyst comprising cerium-promoted zeolite beta. An aromatic feedstock having a benzene content of at least 90 wt. % is supplied into a reaction zone and into contact with the cerium-promoted zeolite beta having a silica/alumina mole ratio within the range of 50-150 and a cerium-aluminum ratio of 0.5-1.5. Ethylene is supplied to the alkylation reaction zone in an amount to provide a benzene/ethylene mole ratio of 1-15. The reaction zone is operated at temperature and pressure conditions in which benzene is in the super critical phase to cause ethylation of the benzene in the presence of the cerium zeolite beta alkylation catalyst. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 60 wt. % of the ethylbenzene. The critical phase alkylation reaction may be followed by the transalkylation of a polyalkylated aromatic component.

摘要翻译： 通过苯在临界相中的乙基化生成乙苯的方法，该分子筛芳族烷基化催化剂包含铈促进沸石β。 苯含量至少为90wt。％的芳族原料。 将％供给到反应区并与二氧化硅/氧化铝摩尔比在50-150范围内并且铈 - 铝比为0.5-1.5的铈促进沸石β接触。 将乙烯以提供苯/乙烯摩尔比为1-15的量供入烷基化反应区。 反应区在苯处于超临界阶段的温度和压力条件下运行，以在铈沸石β烷基化催化剂存在下引起苯的乙基化。 制备含有乙苯作为主要产物的烷基化产物，伴随产生不超过60重量％的较重烷基化副产物。 ％的乙苯。 临界相烷基化反应之后可以是多烷基化芳族组分的烷基转移。

公开(公告)号：US07371911B2

公开(公告)日：2008-05-13

申请号：US11066951

申请日：2005-02-25

申请人： James R. Butler ,  Kevin P. Kelly

发明人： James R. Butler ,  Kevin P. Kelly

IPC分类号： C07C2/66

CPC分类号： C07C2/66 ,  C07C6/126 ,  Y02P20/544 ,  C07C15/073

摘要： A process for the production of ethylbenzene by the ethylation of benzene in the critical phase in a reaction zone containing a molecular sieve aromatic alkylation catalyst comprising cerium-promoted zeolite beta. A polyethylbenzene is supplied into the reaction zone and into contact with the cerium-promoted zeolite beta having a silica/alumina mole ratio within the range of 20-500. The reaction zone is operated at temperature and pressure conditions in which benzene is in the supercritical phase to cause ethylation of the benzene and the transalkylation of polyethylbenzene and benzene in the presence of the zeolite beta catalyst. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated byproducts of no more than 60 wt. % of the ethylbenzene. The alkylation reaction zone is operated under conditions providing a composite byproduct yield of propyl benzene and butyl benzene relative to ethylbenzene, which is no more than one half of the corresponding yield byproduct for zeolite beta promoted with lanthanum. The production of ethylbenzene in the critical phase alkylation reaction zone is attended by recycle of a polyalkylated aromatic component of the reaction product back to the reaction zone.

摘要翻译： 在包含铈促进沸石β的分子筛芳族烷基化催化剂的反应区中通过苯在临界阶段乙苯化生产乙苯的方法。 将聚乙苯供入反应区并与二氧化硅/氧化铝摩尔比在20-500范围内的铈促进沸石β接触。 反应区在苯处于超临界阶段的温度和压力条件下进行，以在沸石β催化剂存在下引起苯的乙基化和多乙基苯和苯的烷基转移。 生产含有乙苯作为主要产物的烷基化产物，伴随产生不超过60重量％的较重烷基化副产物。 ％的乙苯。 烷基化反应区在相对于乙苯提供丙基苯和丁基苯的复合副产物产率的条件下操作，其不超过用镧促进的沸石β的相应产率副产物的一半。 通过将反应产物的多烷基化芳族组分再循环回到反应区，可以在临界相烷基化反应区中生产乙苯。

公开(公告)号：US06407152B1

公开(公告)日：2002-06-18

申请号：US09723951

申请日：2000-11-28

申请人： James R. Butler ,  Kevin P. Kelly

发明人： James R. Butler ,  Kevin P. Kelly

IPC分类号： C08L9500

CPC分类号： C08K5/37 ,  C08J3/243 ,  C08L95/00 ,  C08L2666/08

摘要： A process for the preparation of an asphalt and polymer composition in which a minor amount of polymer component is subjected to a crosslinking. An asphalt base material is heated in a mixing chamber at a temperature sufficient to melt the asphalt and allow stirring of the asphalt within the chamber. A thermoplastic elastomer is added to the chamber in an amount not greater than 12 wt. %. While the asphalt elastomer formulation is stirred, a crosslinking agent is added in an amount effective to crosslink the thermoplastic elastomer. The crosslinking agent formulation comprises at least two components. One component is a thiopolymer incorporating organic sulfur prepared by the reaction of 6-tertiary butyl cresol and sulfur dichloride which reacts to produce a reaction product comprising 4,4-thiobis(6-tertiary butyl-m-cresol) and the thiopolymer, followed by subsequent separation of the 4,4-thiobis(6-tertiary-butyl-m-cresol) from the thiopolymer product. The second crosslinking component comprises a source of sulfur to crosslink the thermoplastic elastomer. The second crosslinking component may be selected from the group consisting of elemental sulfur, polythiomorpholine, specifically dithiodimorpholine, zinc-2-mercaptothiazole and mixtures thereof

摘要翻译： 一种沥青和聚合物组合物的制备方法，其中少量的聚合物组分进行交联。 沥青基材料在混合室中以足以熔化沥青的温度加热并允许在室内搅拌沥青。 将热塑性弹性体以不大于12重量％的量添加到室中。 ％。 在搅拌沥青弹性体配方的同时，加入有效交联热塑性弹性体的量的交联剂。 交联剂制剂包含至少两种组分。 一种组分是含有通过6-叔丁基甲酚和二氯化硫反应制备的有机硫的硫代聚合物，其反应生成包含4,4-二硫代（6-叔丁基间甲酚）和硫代聚合物的反应产物， 随后从硫代聚合物产物中分离出4,4-二硫代双（6-叔丁基间甲酚）。 第二交联组分包含硫源以交联热塑性弹性体。 第二交联组分可以选自元素硫，多硫代吗啉，特别是二硫代二吗啉，锌-2-巯基噻唑及其混合物

公开(公告)号：US06310122B1

公开(公告)日：2001-10-30

申请号：US09389960

申请日：1999-09-03

申请人： James R. Butler ,  Kevin P. Kelly

发明人： James R. Butler ,  Kevin P. Kelly

IPC分类号： C08L9500

CPC分类号： C08L95/00 ,  C08L2666/04 ,  C08L53/00

摘要： The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion or aqueous emulsion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.

摘要翻译： 本发明提供一种制备沥青和热塑性弹性体组合物的方法。 该方法包括将在搅拌槽中切割的沥青加热到足以允许在罐中搅拌沥青的温度。 在沥青中继续搅拌沥青时，加入热塑性弹性体或橡胶。 将混合物以足以增加弹性体分配到沥青中的速度搅拌一段时间。 搅拌速度降低，温度升高，向罐中加入交联剂的油分散体或水性乳液。 搅拌持续一段时间，足以改善沥青中交联剂分散体的分布。

公开(公告)号：US10105890B2

公开(公告)日：2018-10-23

申请号：US14737439

申请日：2015-06-11

申请人： Kevin P. Kelly

发明人： Kevin P. Kelly

IPC分类号： B29C51/16 ,  E04C1/39 ,  E04C2/52 ,  E04B2/02 ,  E04B2/72 ,  B41M5/00 ,  E04H17/14 ,  E04H17/16 ,  B44C5/04 ,  B29L31/10 ,  B29K55/02

摘要： A modular exterior and interior panel, wall and divider system is provided. The modular wall system includes a support base, a plurality of horizontal two-sided panels, each having opposite vertical edges, and a plurality of vertical members secured to the support base. Each of the vertical members has at least one groove for receiving the opposite vertical edges of the horizontal panels. A decorative layer is applied on at least the exterior surfaces of the horizontal panels and the vertical members.