摘要:
The invention relates to a direct synthesis method for producing etherified melamine resin condensates having average molar masses of 500 to 50,000. The method is characterized by the fact that a) an etherified melamine resin precondensate is produced in an alcoholic solution in a first reaction step; b) the etherified melamine resin precondensate is concentrated in an alcoholic solution in at least one condensation step, C4 to C18 alcohols, diols of type HO—R—OH, and/or tetravalent alcohols that are based on erythritol being added to the melamine resin precondensate during and/or following the concentration process; c) the concentrated melamine resin precondensate is reacted by means of a mixer, especially a kneader, in a second reaction step.
摘要:
The invention relates to products, especially moulding materials of polymers containing triazine segments and consisting of mixtures of meltable 4-18 ring oligotriazine ethers which are soluble in highly polar solvents, and in which the triazine rings are predominantly linked by alkylene diamiino groups. Said moulding materials can contain up to 50 mass % of other reactive polymers such as ethylene copolymers, maleic acid anhydride copolymers, modified maleic acid anhydride copolymers, poly(meth)acrylates, polyamides, polyester and/or polyurethanes, up to 75 mass % of filling materials and/or reinforcing fibres, and up to 2 mass % of stabilisers, UV absorbers and/or auxiliary agents. The moulding materials of polymers containing triazine segments can be processed by means of conventional fusion methods and can be used as hot-melt adhesives and for producing plates, tubes, profiles, injection moulded parts, fibres, coatings and foamed material.
摘要:
The invention relates to composite material containing a proportion of wood and a proportion of crosslinked melamine resins, which is characterized in that the crosslinked melamine resins are formed from melamine resins that are, in essence, linearly synthesized and have a shear-dependent viscosity. The invention also relates to a method for producing the composite materials and to the use thereof.
摘要:
The invention relates to plastic products with high strength and flexibility, having 10 to 50 mass % of at least one crosslinked thermoplast and 90 to 50 mass % of at least one crosslinked melamine resin ether. The invention further relates to a method for production of such a plastic product. The aim of the invention is the production of plastic objects in thermoplastics and duroplastics which can be produced by thermoplastic methodology and which have improved material properties.
摘要:
A method for curing aminoplasts, during which layers having layer thicknesses of up to 300 um or filaments and fiber fibrids having a diameter of up to 300 um, which consist of: i) 95 to 99.95% by mass of solvent-free meltable aminoplast polycondensates with molar masses ranging from 1000 to 300000; j) 5 to 0.05% by mass of curing agents, which can be activated by actinic light and which are comprised of acidifiers of the blocked sulfonic acid and/or halogen-substituted triazine derivative and/or onium salt type, and optionally; k) 1 to 20% by mass, with regard to the meltable aminoplast polycondensates, of unmodified and/or modified maleic anhydride copolymers, and/or; i) 0.1 to 5% by mass, with regard to the meltable aminoplast polycondensates, of nanoparticles. The aminoplasts are cured by irradiating them with actinic light at a temperature between the melting point of the aminoplast polycondensate and the thermoinduced decomposition temperature of the light-activatable curing agents. This method enables the production of, preferably, textile fabrics or coatings.
摘要:
The invention relates to composite materials, comprising plastics and wood, with 55 to 90 mass % of wood in the form of sawdust, wood fibres, and/or wood chippings and 45 to 10 mass % of partly crosslinked melamine resin ethers or mixtures of partly crosslinked thermoplastics and crosslinked melamine resin ethers, whereby the plastics in the composite materials can be in the form of a foam. Said materials can be produced by homogenization of the components in the extruder, pre-impregnation of wood with melamine resins in the screw mixer and subsequent homogenization of the components in the extruder, or by a sinter method, each followed by a subsequent moulding to give the composite material. The composite materials are suitable for application in building and in sport and leisure applications.
摘要:
The invention relates to synthetic material dispersions consisting of (a) an aqueous phase of solutions of hydrophilic melamine resin precondensates and a latent hardening catalyst in water or in mixtures of water and alcohols C1-C6, (b) an organic nanophase in the form of nanometric droplets and/or nanoparticles derived from 70-99% of the melamine resin precondensates which are insoluble in water and etherifieds and contain hardening acid catalysts and acid impermeability agents, (c) dispersion agents at a concentration of 1-10 mass % in relation to the total mass of the melamine resin precondensates. The synthetic material dispersions are used for producing flat coated products which are externally used in the form of laminates, of coated flat carrying materials or moulded coated bodies for construction or for sports and recreation.
摘要:
Elastomeric polypropylenes modified by grafting and blends thereof with isotactic polypropylenes modified by grafting, and the use thereof as compatibilizers or adhesion promoters for blends and metal composites.
摘要:
The invention relates to new aromatic/aliphatic and/or alicyclic copolyester amides with high molecular weights, without crosslinking. A subsequent solid phase condensation is avoided or is greatly limited in time. The occurrence of thermal decomposition reactions, dark discolorations of the polymers as well as the formation of block structures are avoided.
摘要:
The invention relates to a method for synthesizing a liquid melamine resin, wherein: a) melamine, at least one aldehyde and at least one alcohol are fed to at least one first reactor operated continuously, in particular at least one agitated tank operated continuously and are reacted together, b) the reaction product that is obtained is fed to a solid-liquid phase separation device, c) a solids-rich phase that has been produced in the solid-liquid phase separation is fed back to at least one first reactor, and d) a phase devoid of solids that has been produced in the solid-liquid phase separation is subjected to additional processing steps. The invention thus provides an efficient continuous direct synthesis method for a liquid melamine resin.