公开(公告)号：US5777034A

公开(公告)日：1998-07-07

申请号：US745393

申请日：1996-11-08

申请人： Nilesh Shah ,  Manhua Lin

发明人： Nilesh Shah ,  Manhua Lin

IPC分类号： C08L33/04 ,  C08L33/12 ,  C08L33/08 ,  C08L33/10 ,  C08L33/20

CPC分类号： C08L33/12 ,  C08L2205/02 ,  C08L2205/14 ,  C08L2205/18

摘要： The invention encompasses a new methacrylate resin blend composition, and a method of making the blend composition, having improved solvent craze resistance. The new blend composition contains a methacrylate matrix resin, particles of a single layer polymer, and, optionally, an acrylic multi-layer polymer. Particles of the single layer polymer derived from 50% or more methyl methacrylate, and having weight average molecular weight (Mw) at least 120% of the Mw of the methacrylate matrix resin component of the blend, the particles having a diameter of from 50 to 500 nanometers, have been discovered to confer a solvent craze resistance value to the methacrylate resin blend which is at least twice the solvent craze resistance value of the methacrylate resin absent particles of the single layer polymer. Solvent craze resistance of the blend may be improved by as much as 10-fold or more over the solvent craze resistance of the methacrylate matrix resin alone.

摘要翻译： 本发明包括新的甲基丙烯酸酯树脂共混物组合物，以及制备该共混组合物的方法，具有改进的耐溶剂耐热性。 新的共混组合物包含甲基丙烯酸酯基质树脂，单层聚合物的颗粒和任选的丙烯酸多层聚合物。 衍生自50％或更多甲基丙烯酸甲酯的单层聚合物的颗粒，其重均分子量（Mw）为共混物的甲基丙烯酸酯基树脂组分的Mw的至少120％，颗粒的直径为50至 已经发现500纳米的甲基丙烯酸酯树脂共混物的溶剂耐热性值是甲基丙烯酸酯树脂不含单层聚合物颗粒的溶剂耐热性的至少两倍。 混合物的溶剂耐热性可以比单独的甲基丙烯酸酯基体树脂的溶剂耐热性提高多达10倍或更多。

公开(公告)号：US07049466B2

公开(公告)日：2006-05-23

申请号：US09962998

申请日：2001-09-25

申请人： Leonard Edward Bogan, Jr. ,  Daniel A. Bors ,  Fernando Antonio Pessoa Cavalcanti ,  Scott Han ,  Bradley Anson Jacobs ,  Frederick William Kaiser ,  Peter David Klugherz ,  Manhua Lin ,  Donald Lee Zolotorofe

发明人： Leonard Edward Bogan, Jr. ,  Daniel A. Bors ,  Fernando Antonio Pessoa Cavalcanti ,  Scott Han ,  Bradley Anson Jacobs ,  Frederick William Kaiser ,  Peter David Klugherz ,  Manhua Lin ,  Donald Lee Zolotorofe

IPC分类号： C07C51/16

CPC分类号： C07C253/24 ,  B01J2523/00 ,  C07C51/215 ,  C07C51/252 ,  C07C2523/28 ,  Y02P20/52 ,  C07C57/04 ,  C07C255/08 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： A method for producing an unsaturated carboxylic acid comprises: (a) contacting, in a reaction zone, an alkane with a catalyst containing a mixed metal oxide, under conditions which produce a product gas comprising the unsaturated carboxylic acid, unreacted alkane and a product alkene; (b) recovering unreacted alkane and product alkene from the product gas; and (c) recycling the recovered unreacted alkane and product alkene to the reaction zone; wherein the mixed metal oxide consists of a material having the formula AaMmNnXxOo wherein A is at least one element selected from the group consisting of molybdenum and tungsten, wherein M is at least one element selected from the group consisting of vanadium, cerium and chromium, wherein N is at least one element selected from the group consisting of tellurium, bismuth and selenium, wherein X is at least one element selected from the group consisting of niobium, tantalum, titanium, aluminum, zirconium, chromium, manganese, iron, ruthenium, cobalt, rhodium, nickel, platinum, bismuth, boron, indium, arsenic, germanium, tin, lithium, sodium, potassium, rubidium, cesium, francium, beryllium, magnesium, calcium, strontium, barium, hafnium, lead, phosphorus, promethium, europium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, gold, silver, palladium, gallium, zinc, praseodymium, rhenium, iridium, neodymium, yttrium, samarium and terbium, wherein 0.25

公开(公告)号：US06180825B2

公开(公告)日：2001-01-30

申请号：US09316007

申请日：1999-05-21

申请人： Manhua Lin ,  Michael William Linsen

发明人： Manhua Lin ,  Michael William Linsen

IPC分类号： C07C5116

CPC分类号： C07C51/215 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J37/0236 ,  B01J2523/00 ,  C07C45/33 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： A process for preparing a catalyst comprises: admixing metal compounds, at least one of which is an oxygen containing compound, and at least one solvent to form a solution; removing the solvent from the solution to obtain a catalyst precursor; and calcining the catalyst precursor under an inert atmosphere to form a catalyst having the formula AaMmNnXxOo wherein a, m, n, x and o are the molar proportions of A, M, N, X and O, respectively, and o is dependent on the oxidation state of the elements A, M, N and X, wherein A is Mo, W, Fe, Nb, Ta, Zr, Ru or mixtures thereof, M is V, Ce, Cr or mixtures thereof, N is Te, Bi, Sb, Se or mixtures thereof, and X is Nb, Ta, W, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pd, Pt, Sb, Bi, B, In, Ce or mixtures thereof. The catalyst is useful for the gas phase oxidation of alkanes to unsaturated aldehydes or carboxylic acids.

摘要翻译： 制备催化剂的方法包括：将至少一种是含氧化合物的金属化合物和至少一种溶剂混合以形成溶液; 从溶液中除去溶剂，得到催化剂前体; 并在惰性气氛下煅烧催化剂前体以形成具有甲醛的催化剂，m，n，x和o分别是A，M，N，X和O的摩尔比，o取决于氧化态 的元素A，M，N和X，其中A是Mo，W，Fe，Nb，Ta，Zr，Ru或其混合物，M是V，Ce，Cr或其混合物，N是Te，Bi，Sb， Se或其混合物，X为Nb，Ta，W，Ti，Al，Zr，Cr，Mn，Fe，Ru，Co，Rh，Ni，Pd，Pt，Sb，Bi，B，In，Ce或其混合物 。 该催化剂可用于将烷烃气相氧化成不饱和醛或羧酸。

公开(公告)号：US06989460B2

公开(公告)日：2006-01-24

申请号：US10722281

申请日：2003-11-25

申请人： Leonard Edward Bogan, Jr. ,  Scott Han ,  Bradley Anson Jacobs ,  Frederick William Kaiser ,  Peter David Klugherz ,  Manhua Lin ,  Richard David Link, III ,  Michael William Linsen

发明人： Leonard Edward Bogan, Jr. ,  Scott Han ,  Bradley Anson Jacobs ,  Frederick William Kaiser ,  Peter David Klugherz ,  Manhua Lin ,  Richard David Link, III ,  Michael William Linsen

IPC分类号： C07C253/24

CPC分类号： C07C253/24 ,  B01J2523/00 ,  C07C51/215 ,  C07C51/252 ,  Y02P20/52 ,  Y02P20/582 ,  C07C57/04 ,  C07C255/08 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： Unsaturated carboxylic acids are produced by the vapor phase catalytic oxidation of mixtures of alkenes and alkanes in the presence of a catalyst containing a mixed metal oxide. Similarly, unsaturated nitriles are produced by the vapor phase catalytic oxidation of alkenes or mixtures of alkenes and alkanes and ammonia in the presence of a catalyst containing a mixed metal oxide.

摘要翻译： 在含有混合金属氧化物的催化剂存在下，通过气相催化氧化烯烃和烷烃的混合物来生产不饱和羧酸。 类似地，在含有混合金属氧化物的催化剂的存在下，通过烯烃或烯烃和烷烃和氨的混合物的气相催化氧化制备不饱和腈。

公开(公告)号：US06653253B1

公开(公告)日：2003-11-25

申请号：US09677389

申请日：2000-10-02

申请人： Manhua Lin

发明人： Manhua Lin

IPC分类号： B01J3100

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J27/0576 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0236 ,  B01J2523/00 ,  C07C45/33 ,  C07C45/35 ,  C07C45/39 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C47/21 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： A catalyst useful for oxidation reactions is disclosed. The catalyst is useful for the gas phase oxidation of alkanes, propylene, acrolein, or isopropanol to unsaturated aldehydes or carboxylic acids.

摘要翻译： 公开了一种可用于氧化反应的催化剂。 该催化剂可用于将烷烃，丙烯，丙烯醛或异丙醇气相氧化成不饱和醛或羧酸。

公开(公告)号：US06514903B2

公开(公告)日：2003-02-04

申请号：US09425671

申请日：1999-10-22

申请人： Manhua Lin ,  Michael William Linsen

发明人： Manhua Lin ,  Michael William Linsen

IPC分类号： B01J2310

CPC分类号： C07C51/215 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J37/0236 ,  B01J2523/00 ,  C07C45/33 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： An improved catalyst including a compound of the formula (I) AaMmNnXxOo  (I) wherein 0.25

摘要翻译： 包含其中0.25

公开(公告)号：US06514901B1

公开(公告)日：2003-02-04

申请号：US09425670

申请日：1999-10-22

申请人： Manhua Lin ,  Michael William Linsen

发明人： Manhua Lin ,  Michael William Linsen

IPC分类号： B01J2310

CPC分类号： C07C51/215 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J37/0236 ,  B01J2523/00 ,  C07C45/33 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： A process for preparing a catalyst is disclosed. The catalyst is useful for the gas phase oxidation of alkanes to unsaturated aldehydes or carboxylic acids.

摘要翻译： 公开了制备催化剂的方法。 该催化剂可用于将烷烃气相氧化成不饱和醛或羧酸。

公开(公告)号：US20240351009A1

公开(公告)日：2024-10-24

申请号：US17948387

申请日：2022-09-20

申请人： Manhua Lin ,  Waisi Eng

发明人： Manhua Lin ,  Waisi Eng

IPC分类号： B01J23/888 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/68 ,  B01J35/40 ,  B01J37/00 ,  B01J37/08 ,  C07C1/24 ,  C07C45/38 ,  C07C51/235 ,  C07C67/40

CPC分类号： B01J23/8885 ,  B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J23/687 ,  B01J23/888 ,  B01J35/40 ,  B01J37/0036 ,  B01J37/08 ,  C07C1/24 ,  C07C45/38 ,  C07C51/235 ,  C07C67/40 ,  B01J2523/00 ,  C07C2523/10 ,  C07C2523/18 ,  C07C2523/22 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/745 ,  C07C2523/888 ,  Y02P20/52

摘要： Disclosed is a catalyst system, and its methods of preparation for producing, among others, alkenes and/or saturated or unsaturated oxygenates and, which include at least one of an aldehyde and an acid (such as propyl aldehyde, acrolein, acrylic acid, isobutyl aldehyde, methacrolein, methacrylic acid), comprising subjecting the corresponding C3 to C4 aliphatic alcohols that are derivable from biomass, such as, propanols, propanediols, and isobutanol, to a vapor phase process over the catalytic system described herein in the presence of a gas mixture of oxygen, air or nitrogen and/or other suitable diluting gas. In the case where a C3 aliphatic alcohol is subjected to a vapor phase catalytic process over the said catalytic system in the presence of air or oxygen, and a co-fed gas, such as nitrogen or other diluting gas, the product is at least one of propylene, propyl aldehyde, acrolein and acrylic acid. In the case where isobutanol is subjected to such a process, the product is at least one of isobutylene, isobutyl aldehyde, methacrolein and methacrylic acid. The catalyst system comprises a single catalytic zone or multi-catalytic zones, in each of which the composition of the co-feed and other reaction parameter can be independently controlled.

公开(公告)号：US06812366B2

公开(公告)日：2004-11-02

申请号：US10653634

申请日：2003-09-02

申请人： Manhua Lin

发明人： Manhua Lin

IPC分类号： C07C4534

CPC分类号： C07C51/252 ,  B01J23/002 ,  B01J23/20 ,  B01J23/28 ,  B01J27/0576 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0236 ,  B01J2523/00 ,  C07C45/33 ,  C07C45/35 ,  C07C45/39 ,  C07C51/215 ,  C07C51/235 ,  C07C51/25 ,  C07C47/21 ,  C07C47/22 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： A catalyst useful for oxidation reactions is disclosed. The catalyst is useful for the gas phase oxidation of alkanes, propylene, acrolein, or isopropanol to unsaturated aldehydes or carboxylic acids.

摘要翻译： 公开了一种可用于氧化反应的催化剂。 该催化剂可用于将烷烃，丙烯，丙烯醛或异丙醇气相氧化成不饱和醛或羧酸。

公开(公告)号：US06710207B2

公开(公告)日：2004-03-23

申请号：US09962487

申请日：2001-09-25

申请人： Leonard Edward Bogan, Jr. ,  Scott Han ,  Bradley Anson Jacobs ,  Frederick William Kaiser ,  Peter David Klugherz ,  Manhua Lin ,  Richard David Link, III. ,  Michael William Linsen

发明人： Leonard Edward Bogan, Jr. ,  Scott Han ,  Bradley Anson Jacobs ,  Frederick William Kaiser ,  Peter David Klugherz ,  Manhua Lin ,  Richard David Link, III. ,  Michael William Linsen

IPC分类号： C07C5116

CPC分类号： C07C253/24 ,  B01J2523/00 ,  C07C51/215 ,  C07C51/252 ,  Y02P20/52 ,  Y02P20/582 ,  C07C57/04 ,  C07C255/08 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68

摘要： Unsaturated carboxylic acids are produced by the vapor phase catalytic oxidation of mixtures of alkenes and alkanes in the presence of a catalyst containing a mixed metal oxide. Similarly, unsaturated nitrites are produced by the vapor phase catalytic oxidation of alkenes or mixtures of alkenes and alkanes and ammonia in the presence of a catalyst containing a mixed metal oxide.

摘要翻译： 在含有混合金属氧化物的催化剂存在下，通过气相催化氧化烯烃和烷烃的混合物来生产不饱和羧酸。 类似地，在含有混合金属氧化物的催化剂的存在下，通过烯烃或烯烃和烷烃和氨的混合物的气相催化氧化产生不饱和亚硝酸盐。