公开(公告)号：US5439874A

公开(公告)日：1995-08-08

申请号：US95078

申请日：1993-07-21

Applicant: Mark W. Drewes ,  Rolf Kirsten ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

Inventor： Mark W. Drewes ,  Rolf Kirsten ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

IPC: A01N43/54 ,  A01N43/66 ,  C07C62/06 ,  C07C62/24 ,  C07C69/757 ,  C07D239/34 ,  C07D239/46 ,  C07D239/60 ,  C07D251/14 ,  C07D401/12 ,  C07D239/38 ,  C07D239/42 ,  C07D413/12

CPC classification number: C07D401/12 ,  A01N43/54 ,  A01N43/66 ,  C07C62/06 ,  C07C62/24 ,  C07C69/757 ,  C07D239/60

Abstract: The invention relates to novel substituted bicyclo[3.1.0]hexanes of the formula ##STR1## in which R.sup.1 represents, e. g., hydroxyl or alkoxy,R.sup.2 to R.sup.8 represent, e. g., hydrogen or alkyl,R.sup.9 and R.sup.10 represent, e.g., methyl or methoxy,X represents, e.g., oxygen,Y represents, e.g., oxygen or sulphur andZ represents, e.g., CH or N,as well as salts of the free acid (R.sup.1 =OH) and their further functional derivatives, and furthermore to processes and novel intermediates for their preparation, and to their use as herbicides.In addition, a novel process is described for preparing certain 2-keto-bicyclo[3.1.0]hexanes, which are required as intermediates, starting from correspondingly substituted .alpha.,.beta.-unsaturated carbonyl compounds (of the methacrolein type) and .beta.-keto acid esters (of the acetoacetic acid ester type).

Abstract translation: 本发明涉及式（I）的新的取代的双环[3.1.0]己烷，其中R1表示， 例如羟基或烷氧基，R 2至R 8表示， 例如，氢或烷基，R 9和R 10表示例如甲基或甲氧基，X表示例如氧，Y表示例如氧或硫，Z表示例如CH或N， 酸（R1 = OH）及其进一步的功能性衍生物，以及其制备方法和新型中间体，以及它们作为除草剂的用途。 另外，描述了一种新方法，用于制备作为中间体所需的某些2-酮 - 双环[3.1.0]己烷，起始于相应取代的α，β-不饱和羰基化合物（甲基丙烯醛型）和β-酮 （乙酰乙酸酯型）的酸酯。

公开(公告)号：US5371062A

公开(公告)日：1994-12-06

申请号：US41650

申请日：1993-04-01

Applicant: Roland Andreee ,  Mark W. Drewes ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

Inventor： Roland Andreee ,  Mark W. Drewes ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

IPC: A01N43/54 ,  A01N43/66 ,  C07D239/28 ,  C07D239/60 ,  C07D251/12 ,  C07D251/30 ,  C07D401/12 ,  C07D409/12

CPC classification number: C07D401/12 ,  A01N43/54 ,  A01N43/66 ,  C07D239/60 ,  C07D251/30 ,  C07D409/12

Abstract: The present invention relates to new substituted azines, of the general formula (I) ##STR1## in which n, Q.sup.1, Q.sup.2, Q.sup.3, R.sup.1, R.sup.2, R.sup.3, X, Y and Z have the meanings given in the description, to a plurality of processes for their preparation, and to their use as herbicides.

Abstract translation: 本发明涉及通式（I）的新的取代的吖嗪，其中n，Q1，Q2，Q3，R1，R2，R3，X，Y和Z具有说明书中给出的含义 ，多种制备方法及其作为除草剂的用途。

公开(公告)号：US5215569A

公开(公告)日：1993-06-01

申请号：US738702

申请日：1991-07-31

Applicant: Mark W. Drewes ,  Peter Muller ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

Inventor： Mark W. Drewes ,  Peter Muller ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

IPC: A01N43/54 ,  A01N43/66 ,  C07D401/12 ,  C07D401/14 ,  C07D405/14 ,  C07D409/14 ,  C07F9/6512 ,  C07F9/6521

CPC classification number: C07D401/12 ,  A01N43/54 ,  A01N43/66

Abstract: Substituted pyridines of the formula ##STR1## in which A represents nitrogen or a C-X group where X represents hydrogen or halogen,Q represents oxygen or sulphur,R.sup.1 and R.sup.2 are identical or different and represent hydrogen, halogen, alkyl, halogenoalkyl, alkoxyalkyl, alkoxy, halogenoalkoxy, alkylthio, alkylamino or dialkylamino,R.sup.3 represents hydrogen, amino, nitro, hydroxyl, halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkylamino, dialkylamino, alkylcarbonylamino, alkoxycarbonylamino or alkysulphonylamino,R.sup.4 represents hydrogen or alkyl andZ represents oxygen or one of the groups below: ##STR2## where R.sup.5, R.sup.6 and R.sup.7 are defined herein and their use in herbicide compositions.

Abstract translation: 其中A表示氮或X基团的式（I）的取代吡啶，其中X表示氢或卤素，Q表示氧或硫，R1和R2相同或不同，表示氢，卤素，烷基，卤代烷基， 烷氧基，烷氧基，卤代烷氧基，烷硫基，烷基氨基或二烷基氨基，R 3表示氢，氨基，硝基，羟基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷基氨基，二烷基氨基，烷基羰基氨基，烷氧基羰基氨基或烷磺酰基氨基， 氧气或以下组中的一种：其中R 5，R 6和R 7在本文中定义，以及它们在除草剂组合物中的用途。

公开(公告)号：US5186734A

公开(公告)日：1993-02-16

申请号：US757860

申请日：1991-09-11

Applicant: Roland Andree ,  Mark W. Drewes ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

Inventor： Roland Andree ,  Mark W. Drewes ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

IPC: A01N43/54 ,  A01N43/66 ,  C07D239/28 ,  C07D239/34 ,  C07D239/38 ,  C07D239/42 ,  C07D239/46 ,  C07D239/48 ,  C07D239/52 ,  C07D239/58 ,  C07D239/60 ,  C07D251/14 ,  C07D251/26 ,  C07D251/34 ,  C07D403/12

CPC classification number: C07D251/34 ,  A01N43/54 ,  A01N43/66 ,  C07D239/60

Abstract: Herbicidal bisazinyl compounds of the formula ##STR1## in which A.sup.1 and A.sup.2 are identical or different and represent nitrogen or a C--X group, X representing hydrogen, halogen, alkyl or alkoxy, andQ.sup.1 and Q.sup.2 are identical or different and represent oxygen, sulphur, NH or N-alkyl,(the substituents R, X.sup.1, X.sup.2, Y.sup.1, Y.sup.2 and Z representing a variety of organic radicals).The compounds of the formulas ##STR2## are also new.

Abstract translation: 其中A1和A2相同或不同并且表示氮或CX基团的式（I）的除草双嗪嗪基化合物，X代表氢，卤素，烷基或烷氧基，以及Q 1和Q 2相同或不同，代表氧 ，硫，NH或N-烷基（取代基R，X1，X2，Y1，Y2和Z代表各种有机基团）。 式（II）＆lt; IMAGE＆gt;（IIIa）和＆lt; IMAGE＆gt;（VIII）的化合物也是新的。

公开(公告)号：US5185026A

公开(公告)日：1993-02-09

申请号：US680495

申请日：1991-04-04

Applicant: Mark W. Drewes ,  Michael Haug ,  Klaus Lurssen ,  Hans-Joachim Santel ,  Robert R. Schmidt

Inventor： Mark W. Drewes ,  Michael Haug ,  Klaus Lurssen ,  Hans-Joachim Santel ,  Robert R. Schmidt

IPC: A01N43/54 ,  A01N51/00 ,  C07D239/34 ,  C07D239/42 ,  C07D239/60 ,  C07D401/12 ,  C07D405/12

CPC classification number: A01N51/00 ,  A01N43/54 ,  C07D239/60 ,  C07D401/12 ,  C07D405/12

Abstract: Herbicidal naphthalene derivatives of the formula ##STR1## in which Q represents oxygen, sulphur or the group NR, where R represents hydrogen or alkyl,R.sup.1 represents hydrogen or alkylR.sup.2, R.sup.3 and R.sup.4 are identical or different and in each case represent hydrogen or another radical,R.sup.5 represents hydrogen or halogen, or represents in each case optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino,R.sup.6 represents hydrogen or halogen, or represents in each case optionally substituted alkyl or alkoxy, andR.sup.7 represents hydrogen or halogen, or represents in each case optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino, andZ represents N--R.sup.8 or ##STR2##

Abstract translation: 其中Q表示氧，硫或NR基团，其中R表示氢或烷基，R1表示氢或烷基R2，R3和R4的除草性萘衍生物，其中Q表示氧，硫或基团NR，R 3和R 4相同或不同，并且在每种情况下表示氢或另一个 基团，R 5表示氢或卤素，或在每种情况下表示任选取代的烷基，烷氧基，烷硫基，烷基氨基或二烷基氨基，R 6表示氢或卤素，或在各种情况下表示任选取代的烷基或烷氧基，并且R 7表示氢或卤素，或 在每种情况下表示任选取代的烷基，烷氧基，烷硫基，烷基氨基或二烷基氨基，Z表示N-R8或<

公开(公告)号：US5167693A

公开(公告)日：1992-12-01

申请号：US704545

申请日：1991-05-23

Applicant: Mark W. Drewes ,  Rolf Kirsten ,  Wolfgang Kramer ,  Bernd W. Kruger ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

Inventor： Mark W. Drewes ,  Rolf Kirsten ,  Wolfgang Kramer ,  Bernd W. Kruger ,  Hans-Joachim Santel ,  Klaus Lurssen ,  Robert R. Schmidt

IPC: A01N43/54 ,  A01N43/66 ,  A01N57/16 ,  A01N57/20 ,  C07D239/34 ,  C07D239/38 ,  C07D239/47 ,  C07D239/52 ,  C07D239/54 ,  C07D239/56 ,  C07D239/58 ,  C07D239/60 ,  C07D251/16 ,  C07D251/22 ,  C07D251/26 ,  C07D251/30 ,  C07D251/34 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07F9/6509 ,  C07F9/6521

CPC classification number: C07D403/12 ,  A01N43/54 ,  A01N43/66 ,  C07D239/60 ,  C07D251/30 ,  C07D405/12 ,  C07D409/12

Abstract: Herbicidal substituted azines of the formula ##STR1## in which m represents the numbers 0, 1, 2 or 3,A represents nitrogen or a C-X group where X represents hydrogen or halogen,Q represents oxygen or sulphur,R.sup.1 and R.sup.2 are identical or different and represent hydrogen, halogen, alkyl, halogenoalkyl, alkoxy-alkyl, alkoxy, halogenoalkoxy, alkylthio, alkylamino or dialkylamino,R.sup.3 represents amino, hydroxyl, halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, alkylamino, dialkylamino, alkylcarbonylamino, alkoxycarbonyl-amino or alkylsulphonylamino,R.sup.4 represents hydrogen or alkyl andZ represents N--R.sup.5 or ##STR2##

Abstract translation: 其中m代表数字0,1,2或3的式（Ⅰ）的除草取代的吖嗪，A代表氮或一个X基团，其中X代表氢或卤素，Q代表氧或硫，R1和R2是 烷氧基，卤代烷氧基，烷硫基，烷基氨基或二烷基氨基，R 3表示氨基，羟基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷基氨基，二烷基氨基，烷基羰基氨基， 氨基或烷基磺酰基氨基，R 4表示氢或烷基，Z表示N-R 5或

公开(公告)号：US4990669A

公开(公告)日：1991-02-05

申请号：US172046

申请日：1988-03-23

Applicant: Manfred T. Reetz ,  Mark W. Drewes

Inventor： Manfred T. Reetz ,  Mark W. Drewes

IPC: C07D207/16 ,  C07B31/00 ,  C07B53/00 ,  C07C67/00 ,  C07C211/27 ,  C07C213/00 ,  C07C215/04 ,  C07C215/08 ,  C07C215/24 ,  C07C215/28 ,  C07C215/30 ,  C07C221/00 ,  C07C223/00 ,  C07C223/02 ,  C07C229/40 ,  C07C237/10 ,  C07C255/32 ,  C07C255/58 ,  C07D207/08 ,  C07D209/44 ,  C07D227/04 ,  C07D403/06

CPC classification number: C07C255/00

Abstract: The invention relates to new optically active .alpha.-amino aldehydes of the formulae ##STR1## in which R.sub.1 represents an optionally substituted alkyl, alkenyl, aralkyl or aryl radical, andR.sub.2 and R.sub.3, independently of one another, denote an optionally substituted alkyl, alkenyl, cycloalkyl or aralkyl group, together form an optionally substituted phenylene-(1,2)-bis-methylene radical, or R.sub.2 is an optionally substituted, alkyl, cycloalkyl or aralkyl radical, and R.sub.3 forms together with R.sub.1 a 1,3-propylene radical.a process for the preparation thereof, and the use thereof for the stereoselective preparation of optically active .beta.-amino alcohols.

Abstract translation: 本发明涉及式IMA的新的光学活性α-氨基醛，其中R 1表示任选取代的烷基，烯基，芳烷基或芳基，R 2和R 3彼此独立地表示任选取代的烷基， 烯基，环烷基或芳烷基一起形成任选取代的亚苯基 - （1,2） - 双 - 亚甲基，或R2是任选取代的烷基，环烷基或芳烷基，R3与R1一起形成1,3-二 丙烯基。 其制备方法及其用于立体选择性制备光学活性β-氨基醇的用途。