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1.发明授权Method for in situ immobilization of water-soluble nanodispersed metal oxide colloids 失效水溶性纳米分散金属氧化物胶体原位固定方法公开(公告)号：US07244688B2
公开(公告)日：2007-07-17
申请号：US10507764
申请日：2003-02-25
申请人： Manfred T. Reetz , Marco Lopez
发明人： Manfred T. Reetz , Marco Lopez
CPC分类号： H01M4/921 , B01J21/18 , B01J23/40 , B01J23/626 , B01J23/6525 , B01J35/0013 , B01J37/0211 , H01M4/8605
摘要： The invention relates to heterogeneous catalysts which are particularly easy to produce. Said heterogeneous catalysts are generated by immobilizing preformed monometallic or multimetallic metal oxide particles in situ on an oxidic or non-oxidic carrier, wherefore metal oxide colloids which are stabilized by hydroxide ions and immobilized on carriers contained in the suspension are generated from conventional, water-soluble metal salts by means of hydrolysis and condensation. The inventive method makes it possible to produce fuel cell catalysts, for example.
摘要翻译： 本发明涉及特别容易生产的多相催化剂。 所述非均相催化剂通过将预制的单金属或多金属氧化物颗粒原位固定在氧化或非氧化载体上而产生，因此由常规的水溶性聚合物产生由氢氧根离子稳定并固定在悬浮液中的载体上的金属氧化物胶体， 通过水解和缩合可溶性金属盐。 本发明的方法使得可以制备例如燃料电池催化剂。
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公开(公告)号：US4626579A
公开(公告)日：1986-12-02
申请号：US825822
申请日：1986-02-04
IPC分类号： C08F4/00 , C08F4/08 , C08F4/42 , C08F4/58 , C08F4/72 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/44 , C08F2/00
摘要： The invention relates to a process for the quasi-ionic polymerization of acrylic acid derivatives, in which the polymerization is initiated by using special mercaptosilanes as initiators in the presence of nucleophilic or electrophilic catalysts.
摘要翻译： 本发明涉及丙烯酸衍生物的准离子聚合方法，其中通过在亲核或亲电催化剂存在下使用特殊的巯基硅烷作为引发剂引发聚合反应。
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3.发明授权Electrochemical reduction of metal salts as a method of preparing highly dispersed metal colloids and substrate fixed clusters by electrochemical reduction of metal salts 失效作为通过电化学还原金属盐制备高度分散的金属胶体和底物固定簇的方法的金属盐的电化学还原
公开(公告)号：US5925463A
公开(公告)日：1999-07-20
申请号：US768513
申请日：1996-12-18
IPC分类号： B01J13/00 , B01J23/44 , B01J23/46 , B01J35/00 , B01J37/16 , B22F9/00 , B22F9/24 , C25B1/00 , C25C5/02 , B32B5/16 , B22F1/00
CPC分类号： B01J37/16 , B01J23/44 , B01J23/462 , B01J35/0013 , C25C5/02 , Y10T428/256 , Y10T428/259 , Y10T428/2982 , Y10T428/2991
摘要： The object of the invention is a method for the electrochemical preparation of metal colloids with particle sizes of less than 30 nm, characterized in that one or more metals of groups Ib, IIb, III, IV, V, VI, VIIb, VIII, lanthanoides, and/or actinoides of the periodic table are cathodically reduced in the presence of a stabilizer, optionally with a supporting electrolyte being added, in organic solvents or in solvent mixtures of organic solvents and/or water within a temperature range of between -78.degree. C. and +120.degree. C. to form metal colloidal solutions or redispersible metal colloid powders, optionally in the presence of inert substrates and/or soluble metal salts of the respective metals.The invention further relates to soluble or redispersible colloids as well as application on substrates and immobilization thereof, in particular for the preparation of catalysts.
摘要翻译： 本发明的目的是一种用于电化学制备粒径小于30nm的金属胶体的方法，其特征在于，一种或多种Ib，IIb，III，IV，V，VI，VIIb，VIII族，镧系金属 ，和/或周期表的锕系元素在有机溶剂或有机溶剂和/或水的溶剂混合物中在稳定剂存在下阴极还原，在稳定剂存在下，在-78℃的温度范围内 C和+120℃，任选地在惰性底物和/或各种金属的可溶性金属盐的存在下形成金属胶体溶液或可再分散的金属胶体粉末。 本发明还涉及可溶性或可再分散的胶体以及在底物上的应用和其固定，特别是用于制备催化剂。
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4.发明授权Method for anionic polymerization of acrylic and methacrylic acid derivatives and acrylonitrile methacrylonitrile using resonance stabilized anions 失效使用共振稳定阴离子进行丙烯酸和甲基丙烯酸衍生物和丙烯腈甲基丙烯腈的阴离子聚合的方法
公开(公告)号：US5494983A
公开(公告)日：1996-02-27
申请号：US737307
申请日：1991-07-31
申请人： Manfred T. Reetz , Thomas Knauf
发明人： Manfred T. Reetz , Thomas Knauf
摘要： A process for anionic polymerization of acrylic and/or methacrylic acid derivatives or their ammonium salts with easily produced initiators. Specifically, the initiators are ammonium salts of resonance-stabilized nitrogen anions. The introduction of such initiators provides a maximum amount of structural variation, while inducing the controlled anionic polymerization of monomers at room temperature. The anionic polymerization is also applicable to acrylonitrile or methacrylonitrile or their derivatives. The polymerization process of the present invention provides polymers with definite molecular weight and limited molecular weight distribution.
摘要翻译： 丙烯酸和/或甲基丙烯酸衍生物或其铵盐与容易生产的引发剂进行阴离子聚合的方法。 具体地，引发剂是共振稳定的氮阴离子的铵盐。 这种引发剂的引入提供最大量的结构变化，同时在室温下诱导单体的受控阴离子聚合。 阴离子聚合也适用于丙烯腈或甲基丙烯腈或其衍生物。 本发明的聚合方法提供具有确定分子量和有限分子量分布的聚合物。
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5.发明授权
公开(公告)号：US4990669A
公开(公告)日：1991-02-05
申请号：US172046
申请日：1988-03-23
申请人： Manfred T. Reetz , Mark W. Drewes
发明人： Manfred T. Reetz , Mark W. Drewes
IPC分类号： C07D207/16 , C07B31/00 , C07B53/00 , C07C67/00 , C07C211/27 , C07C213/00 , C07C215/04 , C07C215/08 , C07C215/24 , C07C215/28 , C07C215/30 , C07C221/00 , C07C223/00 , C07C223/02 , C07C229/40 , C07C237/10 , C07C255/32 , C07C255/58 , C07D207/08 , C07D209/44 , C07D227/04 , C07D403/06
CPC分类号： C07C255/00
摘要： The invention relates to new optically active .alpha.-amino aldehydes of the formulae ##STR1## in which R.sub.1 represents an optionally substituted alkyl, alkenyl, aralkyl or aryl radical, andR.sub.2 and R.sub.3, independently of one another, denote an optionally substituted alkyl, alkenyl, cycloalkyl or aralkyl group, together form an optionally substituted phenylene-(1,2)-bis-methylene radical, or R.sub.2 is an optionally substituted, alkyl, cycloalkyl or aralkyl radical, and R.sub.3 forms together with R.sub.1 a 1,3-propylene radical.a process for the preparation thereof, and the use thereof for the stereoselective preparation of optically active .beta.-amino alcohols.
摘要翻译： 本发明涉及式IMA的新的光学活性α-氨基醛，其中R 1表示任选取代的烷基，烯基，芳烷基或芳基，R 2和R 3彼此独立地表示任选取代的烷基， 烯基，环烷基或芳烷基一起形成任选取代的亚苯基 - （1,2） - 双 - 亚甲基，或R2是任选取代的烷基，环烷基或芳烷基，R3与R1一起形成1,3-二 丙烯基。 其制备方法及其用于立体选择性制备光学活性β-氨基醇的用途。
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公开(公告)号：US09428771B2
公开(公告)日：2016-08-30
申请号：US13824056
申请日：2011-09-06
CPC分类号： C12P7/16 , C12N9/0071 , C12P7/02 , Y02P20/52
摘要： A method is described for the oxidation of organic compounds in which the organic compound that is to be oxidized is brought to reaction in an aqueous solution in the presence of cytochrome P 450, and wherein perfluorinated organic compound is added to the aqueous reaction mixture as activator.
摘要翻译： 描述了一种有机化合物的氧化方法，其中在细胞色素P 450存在下将待氧化的有机化合物在水溶液中进行反应，并且其中将全氟化有机化合物作为活化剂加入到水性反应混合物中 。
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公开(公告)号：US20130236940A1
公开(公告)日：2013-09-12
申请号：US13824056
申请日：2011-09-06
CPC分类号： C12P7/16 , C12N9/0071 , C12P7/02 , Y02P20/52
摘要： A method is described for the oxidation of organic compounds in which the organic compound that is to be oxidized is brought to reaction in an aqueous solution in the presence of cytochrome P 450, and wherein perfluorinated organic compound is added to the aqueous reaction mixture as activator.
摘要翻译： 描述了一种有机化合物的氧化方法，其中在细胞色素P 450存在下将待氧化的有机化合物在水溶液中进行反应，并且其中将全氟化有机化合物作为活化剂加入到水性反应混合物中 。
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公开(公告)号：US07265237B2
公开(公告)日：2007-09-04
申请号：US10297315
申请日：2001-06-05
IPC分类号： C07C253/00
CPC分类号： C07F9/65744 , C07B53/00 , C07B2200/07 , C07C67/303 , C07F9/657127 , C07C69/34
摘要： Certain chiral monophosphites and their monothio derivatives are suitable as ligands in the asymmetrical transition-metal-catalyzed hydrogenation, hydroborination and hydrocyanation of prochiral olefins, ketones and imines.
摘要翻译： 某些手性单亚磷酸酯及其单硫代衍生物适用于非手性过渡金属催化的氢化，加氢硼氢化和前体手性烯烃，酮和亚胺的氢化氰化物中的配体。
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公开(公告)号：US06824982B1
公开(公告)日：2004-11-30
申请号：US09937512
申请日：2001-09-25
IPC分类号： C12Q168
CPC分类号： C12Q1/00
摘要： The present invention relates to a method for determining the enantioselectivity of kinetic resolution processes and of asymmetrically proceeding reactions of prochiral compounds bearing enantiotopic groups by using isotope-labeled substrates so that the reaction products can be quantitatively determined with an isotope-specific detection system, e.g., an ESI mass spectrometer. In connection with automated sample charging, the method can be employed for high throughput screening. The relevant enantioselective conversions can be induced by chiral homogeneous or heterogeneous catalysts, biocatalysts or stoichiometric amounts of optically active agents.
摘要翻译： 本发明涉及通过使用同位素标记的底物来确定动力学拆分方法和带有对映异构基团的前手性化合物的不对称进行反应的对映体选择性的方法，以便可以用同位素特异性检测系统定量测定反应产物，例如 ，ESI质谱仪。 关于自动样品充电，该方法可用于高通量筛选。 相关的对映选择性转化可以由手性均相或非均相催化剂，生物催化剂或化学计量的光学活性剂诱导。
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公开(公告)号：US06392111B1
公开(公告)日：2002-05-21
申请号：US09787786
申请日：2001-03-21
IPC分类号： C07C127
CPC分类号： C07C253/30 , C07B37/04 , C07C2/861 , C07C17/266 , C07C41/30 , C07C45/68 , C07C67/343 , C07C201/12 , C07C209/68 , C07C2531/22 , C07C22/08 , C07C49/796 , C07C69/618 , C07C69/734 , C07C211/45 , C07C255/50 , C07C205/06 , C07C43/215
摘要： Olefins containing aromatic substituents are synthesized without the addition of phosphonium salts or phosphanes with the aid of a PdII compound as a catalyst in the presence of nitrogen-containing additives such as N,N-dimethylglycine and a base.
摘要翻译： 在含氮添加剂如N，N-二甲基甘氨酸和碱的存在下，合成含有芳族取代基的烯烃，不用PdII化合物作为催化剂加入鏻盐或膦。
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