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公开(公告)号：US20190093210A1
公开(公告)日：2019-03-28
申请号：US16198388
申请日：2018-11-21
申请人： Eric Silberberg , Luc VanHee , Bruno Schmitz , Maxime Monnoyer
发明人： Eric Silberberg , Luc VanHee , Bruno Schmitz , Maxime Monnoyer
摘要： The present invention relates to a vacuum deposition facility for depositing a metal alloy coating on a substrate (7), said facility being equipped with a vapour generator/mixer comprising a vacuum chamber (6) in the form of an enclosure provided with means for creating a vacuum state therein relative to the external environment and provided with means for the entry and exit of the substrate (7), while still being essentially sealed from the external environment, said enclosure including a vapour deposition head, called the injector (3), configured so as to create a jet of metal alloy vapour of sonic velocity towards the surface of the substrate (7) and perpendicular thereto, said ejector (3) being in sealed communication with a separate mixer device (14), which is itself connected upstream to at least two crucibles (11, 12) respectively, these containing different metals M1 and M2 in liquid form, each crucible (11, 12) being connected to the mixer (14) by its own pipe (4, 4′).
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公开(公告)号：US10711339B2
公开(公告)日：2020-07-14
申请号：US16198388
申请日：2018-11-21
申请人： Eric Silberberg , Luc VanHee , Bruno Schmitz , Maxime Monnoyer
发明人： Eric Silberberg , Luc VanHee , Bruno Schmitz , Maxime Monnoyer
摘要： A method deposits a metal alloy coating on a substrate using a vacuum deposition facility. The facility is equipped with a vapour generator/mixer comprising a vacuum chamber enclosure provided with an inlet and an outlet for the substrate. The enclosure includes a vapour deposition head and an ejector is provided to create a jet of metal alloy vapour of sonic velocity towards the surface of the substrate and perpendicular thereto. The ejector is in sealed communication with a separate mixer device, which is itself connected upstream to at least two crucibles respectively, these containing different metals in liquid form, each crucible being connected to the mixer by its own pipe. The method uses a series of partitions to create alternating layers of metal vapours. The metal vapours enter the mixer inlet of the mixer at a velocity from 5 to 50 m/s to provide better homogeneity.
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公开(公告)号：US20150013409A1
公开(公告)日：2015-01-15
申请号：US13995107
申请日：2010-12-17
CPC分类号： C23C14/16 , B21C9/005 , B21C43/02 , C22C18/00 , C22C18/04 , C23C2/06 , C23C2/26 , C23C2/40 , C23C14/081 , C23C14/083 , C23C14/584 , C23C28/00 , C23C28/023 , C23C28/025 , C23C28/3225 , C23C28/34 , Y10T428/12611 , Y10T428/12736 , Y10T428/12799
摘要： A steel sheet is provided. The steel sheet includes a multilayer coating including at least one zinc-based layer being 0.1% to 20% magnesium by weight which is covered by a fine temporary protective layer of 5 to 100 nm. The fine temporary protective layer is composed of metal or metal oxide selected from the group consisting of aluminum, chromium, aluminum oxides AlOx, with x being strictly between 0.01 and 1.5 and chromium oxides CrOy, with y being strictly between 0.01 and 1.5. The at least one zinc-based layer is not alloyed with the temporary protective layer. Manufacturing methods for a sheet and part are also provided.
摘要翻译： 提供钢板。 该钢板包括多层涂层，其包含至少一种锌基层，其重量为0.1〜20％，被5〜100nm的细小临时保护层覆盖。 精细的临时保护层由选自铝，铬，氧化铝AlO x，x严格在0.01和1.5之间的金属或金属氧化物组成，铬氧化物CrOy，y严格在0.01和1.5之间。 至少一个锌基层不与临时保护层合金化。 还提供了片材和部件的制造方法。
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公开(公告)号：US09670576B2
公开(公告)日：2017-06-06
申请号：US13995107
申请日：2010-12-17
IPC分类号： C23C14/16 , C23C14/08 , C23C14/58 , C23C28/02 , B21C9/00 , C22C18/00 , C22C18/04 , C23C2/06 , C23C2/26 , C23C2/40 , C23C28/00 , B21C43/02
CPC分类号： C23C14/16 , B21C9/005 , B21C43/02 , C22C18/00 , C22C18/04 , C23C2/06 , C23C2/26 , C23C2/40 , C23C14/081 , C23C14/083 , C23C14/584 , C23C28/00 , C23C28/023 , C23C28/025 , C23C28/3225 , C23C28/34 , Y10T428/12611 , Y10T428/12736 , Y10T428/12799
摘要： A steel sheet is provided. The steel sheet includes a multilayer coating including at least one zinc-based layer being 0.1% to 20% magnesium by weight which is covered by a fine temporary protective layer of 5 to 100 nm. The fine temporary protective layer is composed of metal or metal oxide selected from the group consisting of aluminum, chromium, aluminum oxides AlOx, with x being strictly between 0.01 and 1.5 and chromium oxides CrOy, with y being strictly between 0.01 and 1.5. The at least one zinc-based layer is not alloyed with the temporary protective layer. Manufacturing methods for a sheet and part are also provided.
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公开(公告)号：US10704157B2
公开(公告)日：2020-07-07
申请号：US14371642
申请日：2012-01-10
摘要： The present invention provides an aqueous treatment solution containing sulfate ions SO42− in a concentration greater than or equal to 0.01 mol/l, to treat sheet metal including a steel substrate coated on at least one face with a coating including at least zinc and magnesium to reduce blackening or tarnishing of the sheet metal during storage. The present invention also provides a sheet metal treated with a solution of this type.
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6.发明申请METHOD FOR COATING A METAL STRIP AND EQUIPMENT FOR IMPLEMENTING SAID METHOD 审中-公开用于涂覆金属条和用于实施方法的设备的方法公开(公告)号：US20130061986A1
公开(公告)日：2013-03-14
申请号：US12919304
申请日：2009-02-18
申请人： Luc Vanhee , Maxime Monnoyer , Bruno Schmitz , Eric Silberberg , Qi He
发明人： Luc Vanhee , Maxime Monnoyer , Bruno Schmitz , Benoit Deweer , Eric Silberberg
CPC分类号： C23C14/025 , C23C2/06 , C23C2/26 , C23C2/28 , C23C14/16 , C23C14/5806 , C23C28/021 , C23C28/025 , Y02T50/67
摘要： The invention relates to a process for coating a metal strip, in which a layer of an oxidizable metal or an oxidizable metal alloy or a metal oxide is vacuum-deposited on a metal strip precoated with zinc or with a zinc alloy, the coated metal strip is then coiled, and the wound coil undergoes a static diffusion treatment so as to obtain a strip having a coating that comprises, in the upper portion, a layer of an alloy formed by diffusion of the oxidizable metal or the oxidizable metal alloy in all or part of the zinc or zinc alloy layer, and also to equipment for implementing the process.
摘要翻译： 本发明涉及一种用于涂覆金属条的方法，其中将可氧化金属或可氧化金属合金或金属氧化物层真空沉积在预涂有锌或锌合金的金属条上，所述金属带 然后卷绕，并且卷绕的线圈进行静态扩散处理，以获得具有涂层的条带，该涂层在上部包括通过可氧化金属或可氧化金属合金的全部扩散形成的合金层 部分锌或锌合金层，也用于实施该工艺的设备。
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7.发明申请Industrial Vapour Generator For Depositing An Alloy Coating On A Metal Strip 审中-公开用于在金属带上沉积合金涂层的工业蒸气发生器公开(公告)号：US20110281031A1
公开(公告)日：2011-11-17
申请号：US13140061
申请日：2009-12-17
申请人： Eric Silberberg , Luc Vanhee , Bruno Schmitz , Maxime Monnoyer
发明人： Eric Silberberg , Luc Vanhee , Bruno Schmitz , Maxime Monnoyer
IPC分类号： C23C16/06 , C23C16/455 , C23C16/448
CPC分类号： C23C14/243 , C23C14/16 , C23C14/24 , C23C14/548 , C23C14/562 , Y02T50/67 , Y02T50/6765
摘要： The present invention relates to a vacuum deposition facility for depositing a metal alloy coating on a substrate (7), said facility being equipped with a vapour generator/mixer comprising a vacuum chamber (6) in the form of an enclosure provided with means for creating a vacuum state therein relative to the external environment and provided with means for the entry and exit of the substrate (7), while still being essentially sealed from the external environment, said enclosure including a vapour deposition head, called the injector (3), configured so as to create a jet of metal alloy vapour of sonic velocity towards the surface of the substrate (7) and perpendicular thereto, said ejector (3) being in sealed communication with a separate mixer device (14), which is itself connected upstream to at least two crucibles (11, 12) respectively, these containing different metals M1 and M2 in liquid form, each crucible (11, 12) being connected to the mixer (14) by its own pipe (4, 4′).
摘要翻译： 本发明涉及一种用于在基板（7）上沉积金属合金涂层的真空沉积设备，所述设备装备有蒸气发生器/混合器，该蒸气发生器/混合器包括一个外壳形式的真空室（6），该真空室设置有用于产生 其中相对于外部环境的真空状态并且设置有用于进入和离开基板（7）的装置，同时仍然基本上与外部环境密封，所述外壳包括称为喷射器（3）的气相沉积头， 被配置为产生对基板（7）的表面并垂直于其的声速的金属合金蒸汽射流，所述喷射器（3）与独立的混合装置（14）密封连通，所述混合装置本身连接到上游 分别为至少两个坩埚（11,12），这些坩埚含有液体形式的不同金属M1和M2，每个坩埚（11,12）通过其自己的管道（4,4'）连接到混合器（14）。
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公开(公告)号：US10072327B2
公开(公告)日：2018-09-11
申请号：US12919304
申请日：2009-02-18
申请人： Luc Vanhee , Maxime Monnoyer , Bruno Schmitz , Benoit Deweer , Eric Silberberg , Qi He
发明人： Luc Vanhee , Maxime Monnoyer , Bruno Schmitz , Benoit Deweer , Eric Silberberg
IPC分类号： C23C8/10 , C23C2/26 , C23C14/24 , C23C14/02 , C23C2/06 , C23C2/28 , C23C14/16 , C23C14/58 , C23C28/02 , C23C28/00
CPC分类号： C23C14/025 , C23C2/06 , C23C2/26 , C23C2/28 , C23C14/16 , C23C14/5806 , C23C28/021 , C23C28/025 , Y02T50/67 , Y02T50/6765
摘要： The invention relates to a process for coating a metal strip, in which a layer of an oxidizable metal or an oxidizable metal alloy or a metal oxide is vacuum-deposited on a metal strip precoated with zinc or with a zinc alloy, the coated metal strip is then coiled, and the wound coil undergoes a static diffusion treatment so as to obtain a strip having a coating that comprises, in the upper portion, a layer of an alloy formed by diffusion of the oxidizable metal or the oxidizable metal alloy in all or part of the zinc or zinc alloy layer, and also to equipment for implementing the process.
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