摘要:
The invention relates to organosilicon compounds with at least three silicon atoms, consisting of units of the formula (I) RaSi(NR1C═ONR22)k(NR3C═ONR4)t/2YmOn/2[(CR52)s]r/2, where Y represents units of the formula (II) —SiR63-p-q(NR1C═ONR22)p(NR3C═ONR4)q/2, where R, R1, R2, R3, R4, R5 and R6 independently of each other can be either identical or different and represent a hydrogen atom or possibly substituted monovalent hydrocarbon radicals with between 1 and 20 carbon atoms; and where a, k, t, n, m, r, s, p and q have the meaning assigned to them in claim 1, under the provision that the sum of p+q is ≦3, the sum of a+k+l+m+n+r equals 4, the sum of m+r equals 0 or 1, and the organosilicon compound of the invention contains at least one unit of formula (I) where t is not equal to 0.
摘要翻译:本发明涉及具有至少三个硅原子的有机硅化合物,由式(I)RaSi(NR1C = ONR22)k(NR3C = ONR4)t / 2YmOn / 2 [(CR52)s] r / 2的单元组成,其中 Y表示式(II)-SiR 63-pq(NR 1 C = ONR 22)p(NR 3 C = ONR 4)q / 2的单元,其中R,R 1,R 2,R 3,R 4,R 5和R 6彼此独立地可以相同 或不同的,表示氢原子或可能具有1至20个碳原子的取代的一价烃基; 并且其中a,k,t,n,m,r,s,p和q具有在权利要求1中分配给它们的含义,在p + q的和为<= 3的条件下,a + k的和 + 1 + m + n + r等于4,m + r的和等于0或1,本发明的有机硅化合物含有至少一个式(I)单元,其中t不等于0。
摘要:
The present invention pertains to the preparation of organopolysiloxanes containing organyloxy groups by reacting organopolysiloxane(s) bearing terminal hydroxyl groups with an alkoxysilane having at least two alkoxy groups and a radical which contains at least one secondary or tertiary amino group bonded to silicon by a divalent C1-2 hydrocarbon radical, the reaction being catalyzed by an acidic ester of phosphoric acid having the formula (HO)aOP—(O—R7)3−a Where R7 is an oxyalkylated active hydrogen component, preferably an oxyalkylated fatty alcohol. RTV-1 compositions containing the reaction product exhibit extended storage life.
摘要:
The invention relates to a method for producing organopolysiloxane terminated with alkoxy groups, wherein A) organopolysiloxane terminated with HO is reacted with B) alkoxysilane having at least three alkoxy groups and/or whose partial hydrolysate is made to react in the presence of C) acid phosphoric acid ester of general formula (I): (HO)aOP(—O—[(CR12)b—O]c[(CR22)d]e—L—M)(3−a), wherein a=1 or 2; R1 and R2=a hydrogen, methyl or hydroxyl radical; b and d=2 or 3; c=integral values from 2 to 15; e=0 or 1; L=a radical from the group —O—, —COO—, —OOC—, —CONR3—, —NR4CO— and —CO—; R3 and R4=a hydrogen or a C1-C10-alkyl radical and M=a monovalent, optionally a hydroxyl, fluorine, chlorine, bromine, C1-C10-alkoxylalkyl or cyano group substituted C1- to C20-hydrocarbon radical, provided that the radicals R1 and R2 can only be at one given time a hydroxyl radical in each hydrocarbon atom. The invention further relates to RTV-1-alkoxy masses comprising the reaction product containing organopolysiloxane terminated with alkoxy groups as the essential constituent.
摘要翻译:本发明涉及一种制备用烷氧基封端的有机聚硅氧烷的方法,其中A)用HO封端的有机聚硅氧烷与B反应,B)具有至少三个烷氧基的烷氧基硅烷和/或其部分水解产物在C)酸存在下反应 (I)的磷酸酯:(HO)aOP(-O - [(CR12)bO] c [(CR22)d] eLM)(3-a),其中a = 1或2; R1和R2 =氢,甲基或羟基; b和d = 2或3; c =从2到15的积分值; e = 0或1; L =从-O - , - O - , - OOC - , - CONR 3 - , - NR 4 CO - 和-CO - 基团的基团; R 3和R 4 =氢或C 1 -C 10 - 烷基,M =单价,任选的羟基,氟,氯,溴,C 1 -C 10 - 烷氧基烷基或氰基取代的C 1 -C 20烃基,条件是 基团R 1和R 2只能在一个给定时间在每个烃原子中具有羟基。 本发明还涉及包含以烷氧基为终点的有机聚硅氧烷作为必要成分的反应产物的RTV-1-烷氧基团。
摘要:
A paste composition which is used in the preparation of dental impression compositions containing:(a) at least 100 ppm by weight, based on the weight of the paste composition of platinum calculated as the element;(b) 35 to 75 percent by weight, based on the weight of the paste composition, of a diorganopolysiloxane which contains at least 2 SiC-bonded vinyl groups per molecule and has a viscosity of at least 100 mPa.s at 25.degree. C.;(c) 10 to 25 percent by weight, based on the weight of the paste composition, of a hydrocarbon which is liquid or spreadable at room temperature and is free of aliphatic carbon-carbon multiple bonds; and(d) 3 to 15 percent by weight, based on the weight of the paste composition, of hydrophobic silicon dioxide having a surface area of at least 50 m.sup.2 /g;in which the sum of the percentages of (a) to (d) including other additives which may be present in the paste composition is equal to 100 percent. The paste composition is mixed with the other ingredients of the dental impression compositions such as diorganopolysiloxanes having SiC-bonded vinyl groups, organopolysiloxanes having at least 3 Si-bond hydrogen atoms per molecule and filler to form dental impression compositions.
摘要:
Silicon-tin compounds of the formulaR.sub.a Si(OSnR.sup.1 R.sup.2 OOCR.sup.3).sub.4-ain which R represents an alkyl or phenyl radical, R.sup.1, R.sup.2 and R.sup.3 are alkyl radicals and a is 0 or 1 and their use as condensation catalysts in the preparation of organopolysiloxane elastomers.
摘要:
The invention relates to paste-like mixtures that are used in the preparation of room temperature vulcanizable compositions comprising a cross-linking agent, a condensation catalyst and a hydrophobic silicon dioxide thickening agent which is solid at room temperature.
摘要:
The invention relates to a preparation for producing a polymer crosslinkable by condensation reaction, which comprises at least one aminopropyltriethoxysilane and at least one polydialkylsiloxane having two terminal hydroxyl groups, wherein the polydialkylsiloxane is represented by the following formula (1): HO—[—SiR1R2—O—]x—OH formula (1) wherein in formula (1) R1 and R2 may be the same or different and may be selected from the group consisting of alkyl groups having 1 to 8 carbon atoms and wherein x is an integer from 30 to 2500.
摘要:
A device for removing an injection-molded substrate with attached sprue from an injection mold having half-molds, in particular a substrate for optical data carriers, includes a lever that can swing in and out of a position between the half-molds of the injection mold and is constructed to include a substrate retaining mechanism with a substrate retaining member with a recess or an opening sized to hold the substrate and configured to receive the sprue with a pass fit. The substrate retaining member secures the substrate in place as the lever swings in and out of the open half-molds. An injection molding machine using the device is also described. The substrate can be quickly demolded and the sprue removed in a single operation without producing dust in the mold.
摘要:
Hydroxyl terminated diorganopolysiloxanes may be crosslinked with a mixture containing (1) a product obtained from the reaction of (a) silicic acid esters with (b) an organic tin compound of the formulaR.sub.2 Sn(OCOR.sup.1).sub.2 (I),where R represents a butyl or an octyl radical and R.sup.1 represents a monovalent hydrocarbon radical having from 1 to 15 carbon atoms, in which at most one of the valences of the carbon atom that is bonded to the carboxyl group is saturated by a carbon atom other than that of the carboxyl group, and (2) an organic tin compound of the formulaR.sub.2 Sn(OCOR.sup.2).sub.2 (II),where R is the same as above and R.sup.2 represents a monovalent aliphatic hydrocarbon radical having from 3 to 15 carbon atoms, in which at least two of the valences of the carbon atom that is bonded to the carboxyl group are saturated by two carbon atoms other than that of the carboxyl group.
摘要:
This invention relates to adhesive compositions which may be used for bonding laminated glass and for glueing silicon semiconductor elements onto substrates in manufacturing solar cells. These adhesive compositions contain organopolysiloxanes having SiC-bonded vinyl groups and Si-bonded hydrogen as well as catalysts which promote the addition of Si-bonded hydrogen to vinyl groups. All of the organopolysiloxanes in these compositions are free of Si-bonded hydroxylk or alkoxy groups and contain on the average 2 to 1,000 silicon atoms per molecule in which at least 99.5 percent and preferably 99.9 percent of the number of Si-bonded hydrogen atoms are present in organopolysiloxanes containing one Si-bonded hydrogen atom per molecule and one SiC-bonded vinyl group per molecule or containing 2 Si-bonded hydrogen atoms per molecule and at least 99.5 percent and preferably 99.9 percent of the number of SiC-bonded vinyl groups are present in organopolysiloxanes containing one Si-bonded hydrogen atom per molecule and one SiC-bonded vinyl group per molecule or containing 2 SiC-bonded vinyl groups per molecule.