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公开(公告)号：US06271313B1
公开(公告)日：2001-08-07
申请号：US09366864
申请日：1999-08-04
IPC分类号： C08F2502
CPC分类号： C08F297/06 , C08F8/04 , C08F297/04 , C08F297/044
摘要： This invention is based upon the unexpected discovery that styrene-butadiene block copolymers having syndiotactic polystyrene (sPS) blocks and cis-1,4-polybutadiene (PBd) blocks can be synthesized by polymerizing styrene and 1,3-butadiene utilizing certain catalyst systems when the polymerization is conducted at a pressure which is within the range of about 10 mm of mercury to about 50 mm of mercury at a temperature which is within the range of about 0° C. to about 100° C. This invention more specifically discloses a styrene-butadiene block copolymer which is comprised of (a) syndiotactic polystyrene blocks and (b) cis-1,4-polybutadiene blocks, wherein said cis-1,4-polybutadiene blocks have a vinyl content of up to about 20 percent, wherein the syndiotactic polystyrene blocks have a syndiotactic microstructure content of at least 50 percent, wherein the block copolymer contains at least five syndiotactic polystyrene blocks and wherein said block copolymer has a number average molecular weight which is within the range of about 10,000 to about 700,000.
摘要翻译： 本发明基于意想不到的发现，即具有间同立构聚苯乙烯（sPS）嵌段和顺式-1,4-聚丁二烯（PBd）嵌段的苯乙烯 - 丁二烯嵌段共聚物可以通过使用某些催化剂体系聚合苯乙烯和1,3-丁二烯来合成， 在约0℃至约100℃的温度范围内，在约10mm汞柱至约50mm汞柱的压力下进行聚合。本发明更具体地公开了一种 苯乙烯 - 丁二烯嵌段共聚物，其由（a）间同立构聚苯乙烯嵌段和（b）顺式-1,4-聚丁二烯嵌段组成，其中所述顺式-1,4-聚丁二烯嵌段具有高达约20％的乙烯基含量，其中 间规聚苯乙烯嵌段具有至少50％的间规微结构含量，其中嵌段共聚物包含至少五个间同立构聚苯乙烯嵌段，并且其中所述嵌段共聚物具有数均分子量 重量在约10,000至约700,000的范围内。
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2.发明申请TYRE COMPRISING AN EPOXIDIZED ELASTOMERIC POLYMER AND CROSSLINKABLE ELASTOMERIC COMPOSITION 审中-公开包含环氧化弹性体聚合物和可交联弹性体组合物的轮胎公开(公告)号：US20090065117A1
公开(公告)日：2009-03-12
申请号：US11658510
申请日：2005-07-13
CPC分类号： C08L23/16 , B60C1/0016 , B60C11/005 , B60C17/0009 , B60C2001/0033 , C08C19/06 , C08K3/346 , C08L15/00 , C08L21/00 , C08L23/0807 , C08L23/30 , C08L2205/02 , Y10T152/10495 , C08L2666/08 , C08L2666/06
摘要： A tyre includes at least one structural element obtained by crosslinking a crosslinkable elastomeric composition including: (a) a crosslinkable elastomeric base comprising at least 10 phr, preferably from 30 phr to 100 phr, of (a1) at least one epoxidized elastomeric polymer including less than 10 mol %, preferably from 0.1 mol % to 5 mol %, of epoxy groups relative to the total number of moles of monomers present in the elastomeric polymer; and (b) from 2 phr to 50 phr, preferably from 5 phr to 30 phr, of at least one layered material. Preferably, the at least one structural element is selected from bead filler, sidewall insert, tread underlayer, and tread base.
摘要翻译： 轮胎包括通过交联可交联弹性体组合物获得的至少一种结构元件，其包括：（a）包含至少10phr，优选30phr至100phr的（a1）至少一种包含较少的环氧化弹性体聚合物的可交联弹性体基体 相对于存在于弹性体聚合物中的单体的总摩尔数，10摩尔％以上，优选为0.1摩尔％〜5摩尔％的环氧基; 和（b）2phr至50phr，优选5phr至30phr的至少一种层状材料。 优选地，所述至少一个结构元件选自胎圈填料，侧壁插入件，胎面底层和胎面基底。
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公开(公告)号：US20080185087A1
公开(公告)日：2008-08-07
申请号：US11665271
申请日：2004-10-15
CPC分类号： C08L23/22 , C08L7/00 , C08L23/283 , C08L2666/06 , C08L2666/04
摘要： A tire, including a carcass structure, includes at least one carcass ply of a substantially toroidal shape, having opposite lateral edges associated with respective right-hand and left-hand bead structures, the bead structures including at least one bead core and at least one bead filler; a belt structure applied in a radially external position with respect to the carcass structure; a tread band radially superimposed on the belt structure; a pair of sidewalls applied laterally on opposite sides with respect to the carcass structure; and at least one layer including a crosslinked elastomeric material applied in a radially inner position with respect to the carcass structure. The crosslinked elastomeric material is obtained by crosslinking a crosslinkable elastomeric composition including (a) less than 50 phr, preferably 15 phr to 40 phr, of at least one butyl rubber; (b) not less than 50 phr, preferably 60 phr to 85 phr, of at least one polyisoprene rubber; and (c) 2 phr to 50 phr, preferably 5 phr to 35 phr, of at least one layered material. Preferably, the layer including a crosslinked elastomeric material is a tire innerliner.
摘要翻译： 包括胎体结构的轮胎包括至少一个基本上环形形状的胎体帘布层，其具有与相应的右手和左侧胎圈结构相关联的相对侧边缘，所述胎圈结构包括至少一个胎圈芯和至少一个胎圈芯 珠填料; 相对于胎体结构施加在径向外部位置的带结构; 径向叠加在带结构上的胎面带; 相对于胎体结构在相对侧面上横向施加的一对侧壁; 以及包括相对于胎体结构在径向内部位置施加的交联的弹性体材料的至少一个层。 交联的弹性体材料通过交联包含（a）小于50phr，优选15phr至40phr的至少一种丁基橡胶的可交联弹性体组合物获得; （b）不低于50phr，优选60phr至85phr的至少一种聚异戊二烯橡胶; 和（c）2phr至50phr，优选5phr至35phr的至少一种层状材料。 优选地，包括交联的弹性体材料的层是轮胎内衬。
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公开(公告)号：US20070276062A1
公开(公告)日：2007-11-29
申请号：US10584400
申请日：2003-12-24
申请人： Diego Tirelli , Michela Caprio , Luigia Rossiello , Lisa Grassi , Emillano Resmini , Stefano Testi
发明人： Diego Tirelli , Michela Caprio , Luigia Rossiello , Lisa Grassi , Emillano Resmini , Stefano Testi
CPC分类号： C08C19/06
摘要： A process for producing an epoxidized elastomeric polymer by feeding at least one elastomeric polymer containing ethylenic unsaturation to a mixing device; feeding at least one hydrogen peroxide precursor to the mixing device; feeding at least one carboxylic acid or a derivative thereof to the mixing device; mixing and reacting, in the presence of water, the at least one elastomeric polymer containing ethylenic unsaturation with the at least one hydrogen peroxide precursor and the at least one carboxylic acid or a derivative thereof, to obtain an epoxidized elastomeric polymer; and discharging the resulting epoxidized elastomeric polymer from the mixing device.
摘要翻译： 一种通过将含有烯属不饱和度的至少一种弹性体聚合物进料到混合装置来制备环氧化弹性体聚合物的方法; 将至少一种过氧化氢前体进料至混合装置; 将至少一种羧酸或其衍生物加入到混合装置中; 在水的存在下，将至少一种含有烯属不饱和的弹性体聚合物与所述至少一种过氧化氢前体和所述至少一种羧酸或其衍生物进行混合和反应，得到环氧化的弹性体聚合物; 并从混合装置中排出所得的环氧化弹性体聚合物。
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5.发明申请公开(公告)号：US20060241213A1
公开(公告)日：2006-10-26
申请号：US10533293
申请日：2002-10-31
IPC分类号： C08J3/22
CPC分类号： C08J3/005
摘要： A crosslinkable elastomeric composition includes at least one thermoplastic polymer selected from amorphous polymers having a glass transition temperature higher than 80° C. or crystalline polymers having a melting temperature higher than 190° C. and at least one diene elastomeric polymer. A method for preparing the composition includes pre-mixing, at a temperature not lower than Tg or (Tm−20° C.), the at least one thermoplastic polymer with a first portion of the at least one diene elastomeric polymer to obtain a masterbatch and mixing the masterbatch with a remaining portion of the at least one diene elastomeric polymer. The composition may include from 1% to 65% of the at least one thermoplastic polymer and from 35% to 99% of the at least one diene elastomeric polymer. The at least one thermoplastic polymer may be dispersed in a form of particles having an average diameter not greater than 20 μm.
摘要翻译： 可交联的弹性体组合物包括至少一种选自玻璃化转变温度高于80℃的无定形聚合物或熔融温度高于190℃的结晶聚合物和至少一种二烯弹性体聚合物的热塑性聚合物。 一种制备该组合物的方法，包括在不低于T g或（T
-20℃）的温度下预混合至少一种热塑性聚合物 与所述至少一种二烯弹性体聚合物的第一部分以获得母料并将所述母料与所述至少一种二烯弹性体聚合物的剩余部分混合。 组合物可以包含1％至65％的至少一种热塑性聚合物和35％至99％的至少一种二烯弹性体聚合物。 至少一种热塑性聚合物可以以平均直径不大于20μm的颗粒的形式分散。 -
公开(公告)号：US20090247682A1
公开(公告)日：2009-10-01
申请号：US12083098
申请日：2005-10-26
CPC分类号： B60C1/00 , C08J3/226 , C08J2307/00 , C08J2421/00 , C08K3/346 , C08L21/00
摘要： Method for producing a crosslinkable elastomeric composition including: (a) at least one first elastomeric polymer; (b) at least one layered material having an individual layer thickness of 0.01 nm to 30 nm, preferably of 0.05 nm to 15 nm; and (c) at least one vulcanizing agent; includes the following steps: (i) feeding the at least one layered material (b) and at least one second elastomeric polymer (d), into at least one extruder including a housing, at least one screw rotatably mounted in the housing including at least one feed opening and a discharge opening, the at least one layered material being fed into the at least one extruder in an amount higher than or equal to 70 phr; (ii) mixing and softening the mixture so as to obtain a masterbatch; (iii) discharging the obtained masterbatch through a discharge opening; and (iv) mixing the obtained masterbatch with the at least one first elastomeric polymer (a) and the at least one vulcanizing agent (c), to obtain the crosslinkable elastomeric composition, the mixing being carried out in a batchwise manner.
摘要翻译： 用于生产可交联弹性体组合物的方法，包括：（a）至少一种第一弹性体聚合物; （b）具有0.01nm至30nm，优选为0.05nm至15nm的单层厚度的至少一种层状材料; 和（c）至少一种硫化剂; 包括以下步骤：（i）将至少一种层状材料（b）和至少一种第二弹性体聚合物（d）进料至包括壳体的至少一个挤出机中，至少一个可旋转地安装在壳体中的螺杆至少包括 一个进料口和排出口，所述至少一个层压材料以高于或等于70phr的量进料到所述至少一个挤出机中; （ii）混合和软化混合物以获得母料; （iii）通过排出口排出所获得的母料; 和（iv）将获得的母料与至少一种第一弹性体聚合物（a）和至少一种硫化剂（c）混合，以获得可交联的弹性体组合物，所述混合以间歇方式进行。
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7.发明申请Tyre comprising a cycloolefin polymer tread band and elastomeric composition used therein 审中-公开轮胎，其包含环烯烃聚合物胎面胶带和其中使用的弹性体组合物公开(公告)号：US20050080190A1
公开(公告)日：2005-04-14
申请号：US10497322
申请日：2001-12-21
申请人： Maurizio Galimberti , Michela Caprio , Luigi Fino
发明人： Maurizio Galimberti , Michela Caprio , Luigi Fino
IPC分类号： B60C1/00 , C08G61/08 , C08L9/00 , C08L21/00 , C08L23/00 , C08L23/08 , C08L45/00 , C08L65/00 , C08F8/00
CPC分类号： C08L65/00 , B60C1/0016 , C08G61/08 , C08L21/00 , C08L23/0823 , C08L2666/06 , C08L2666/08
摘要： Tyre for vehicle wheels, comprising at least one component made of a crosslinked elastomeric material, in which said component includes an elastomeric composition comprising: (a) at least one diene elastomeric polymer, (b) at least one cycloolefin polymer, said cycloolefin polymer having a glass transition temperature (Tg) of not less 50° C. Preferably, said component including said composition is a tyre tread band.
摘要翻译： 用于车轮的轮胎，包括至少一种由交联的弹性体材料制成的部件，其中所述部件包括弹性体组合物，其包含：（a）至少一种二烯弹性体聚合物，（b）至少一种环烯烃聚合物，所述环烯烃聚合物具有 玻璃化转变温度（Tg）不低于50℃。优选地，包括所述组合物的所述组分是轮胎胎面带。
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