公开(公告)号：US20090266245A1

公开(公告)日：2009-10-29

申请号：US12095445

申请日：2006-11-28

申请人： Yoshihiko Kanuma ,  Morihisa Shioya ,  Katsuhiko Kusakabe ,  Misao Tamura

发明人： Yoshihiko Kanuma ,  Morihisa Shioya ,  Katsuhiko Kusakabe ,  Misao Tamura

IPC分类号： A47J43/00 ,  B05B15/06 ,  B05B1/24

CPC分类号： A47J31/4489 ,  A47J27/16 ,  G07F13/10

摘要： A liquid food heating apparatus includes: a steam jet nozzle (36), a nozzle holder (18) to which the steam jet nozzle (36) is attached; a steam feed pipe (17), nozzle coupling means (14a, 14b, 14c) capable of coupling the steam jet nozzle (36) attached to the nozzle holder (18) to the steam feed pipe (17), and nozzle discard means (12b, 12c, 12d, 18c) capable of detaching from the nozzle holder (18) the steam jet nozzle (36) attached to the nozzle holder (18) and discarding the nozzle. The nozzle discard means detaches from the nozzle holder (18) the steam jet nozzle (36) attached to the nozzle holder (18) and discards the nozzle after releasing the coupling between the steam jet nozzle (36) attached to the nozzle holder (18) and the steam feed pipe (17).

摘要翻译： 一种液体食品加热设备包括：蒸汽喷嘴（36），安装蒸汽喷嘴（36）的喷嘴支架（18）; 蒸汽供给管（17），能够将附接到喷嘴保持器（18）的蒸汽喷嘴（36）与蒸汽供给管（17）连接的喷嘴联接装置（14a，14b，14c）和喷嘴废弃装置 12b，12c，12d，18c），其能够从喷嘴保持器（18）分离附接到喷嘴保持器（18）的蒸汽喷嘴（36）并且丢弃喷嘴。 喷嘴丢弃装置从安装在喷嘴保持架（18）上的蒸汽喷嘴（36）的喷嘴保持器（18）上分离，并且在释放安装在喷嘴座（18）上的蒸汽喷嘴（36） ）和蒸汽供给管（17）。

公开(公告)号：US06306502B1

公开(公告)日：2001-10-23

申请号：US09043486

申请日：1998-03-19

申请人： Hiroshi Fukushima ,  Misao Tamura ,  Osamu Takemoto ,  Katsumi Yonekura

发明人： Hiroshi Fukushima ,  Misao Tamura ,  Osamu Takemoto ,  Katsumi Yonekura

IPC分类号： C09D402

CPC分类号： C09D4/00 ,  Y10T428/31507 ,  Y10T428/31663 ,  C08F222/1006

摘要： A coating composition forming a abrasion resistant coating comprising (A) an ultraviolet-curable silicone prepared by chemically modifying particulate colloidal silica with a specific silane compound, (B) a monomer mixture comprising a (meth)acrylate having a specific isocyanate skeleton and a urethane poly(meth)acrylate having an alicyclic skeleton, and (C) a photo-polymerization initiator. By using a urethane poly(meth)acrylate having an alicyclic skeleton as part of the component (B) and the component (A) having an enhanced reactivity of chemical modification, the compatibility of the component (A) with the component (B) is improved to give a cured coating with excellent wear resistance, weather resistance and durability.

摘要翻译： 一种形成耐磨涂层的涂料组合物，其包含（A）通过用特定硅烷化合物化学改性颗粒状胶体二氧化硅制备的紫外线固化性硅氧烷，（B）包含具有特定异氰酸酯骨架的（甲基）丙烯酸酯和氨基甲酸酯 具有脂环骨架的聚（甲基）丙烯酸酯，（C）光聚合引发剂。 通过使用具有脂环骨架的聚氨酯聚（甲基）丙烯酸酯作为组分（B）的一部分和具有增强的化学改性反应性的组分（A），组分（A）与组分（B）的相容性为 改进以提供具有优异耐磨性，耐候性和耐久性的固化涂层。

公开(公告)号：US5494645A

公开(公告)日：1996-02-27

申请号：US498435

申请日：1995-07-05

申请人： Suehiro Tayama ,  Misao Tamura ,  Tsukasa Mizobuchi

发明人： Suehiro Tayama ,  Misao Tamura ,  Tsukasa Mizobuchi

IPC分类号： C08F2/48 ,  C09D4/00 ,  C09D183/04 ,  C09D183/06 ,  B05D3/06

CPC分类号： C09D4/00 ,  C09D183/04 ,  C09D183/06

摘要： Disclosed is a coating composition comprising(A) 5 to 60 parts by weight, on a solid basis, of colloidal silica,(B) 5 to 70 parts by weight of a hydrolyzate and/or hydrolyzed and partially condensed product of a compound of the general formula ##STR1## (C) 10 to 80 parts by weight of a polyfunctional monomer containing a monomer of the general formula ##STR2## and (D) 0.01 to 5 parts by weight of a photopolymerization initiator containing a compound of the general formula ##STR3## provided that the combined amount of components (A), (B), (C) and (D) is 100 parts by weight.This coating composition can be cured in air by exposure to ultraviolet light, and the resulting cured film is excellent in various properties (such as abrasion resistance) and adhesion to the substrate.

摘要翻译： 公开了一种涂料组合物，其包含（A）5至60重量份的基于固体的胶态二氧化硅，（B）5至70重量份的水解产物和/或水解和部分缩合的产物 通式（I）（C）（C）10〜80重量份含有通式（II）的单体和（D）的多官能单体0.01〜5重量份的光聚合引发剂，其含有 组分（A），（B），（C）和（D）的组合量为100重量份，通式为（IMA）（III）的化合物。 该涂料组合物可以通过暴露在紫外线下在空气中固化，所得到的固化膜具有优异的各种性能（如耐磨性）和对基材的粘合性。

公开(公告)号：US5635544A

公开(公告)日：1997-06-03

申请号：US481836

申请日：1995-06-07

申请人： Misao Tamura ,  Hiroshi Fukushima

发明人： Misao Tamura ,  Hiroshi Fukushima

IPC分类号： C08F2/48 ,  C09D4/00 ,  C09D183/04 ,  C09D183/06 ,  C08F2/46

CPC分类号： C09D4/00 ,  C09D183/04 ,  C09D183/06

摘要： Disclosed is a process for preparing a UV-curable coating material comprising the steps of effecting a hydrolysis reaction of (a-1) 40 to 90 parts by weight of colloidal silica, and (a-2) 60 to 10 parts by weight of a hydrolyzate of an alkoxy silane compound containing not less than 50% by weight of a compound of the formula (I) ##STR1## replacing the dispersion medium of the colloidal silica with a nonpolar solvent when the amount of dehydration is in the range of 50 to 90% of theoretical value; and effecting a further condensation reaction while maintaining in the state of 30 to 90% by weight of solid components in the presence of the nonpolar solvent.A coating composition containing the UV-curable coating material can form an anti-abrasion-coating film having excellent abrasion resistance, surface smoothness, thermal resistance, chemical resistance, durability, weather resistance and adhesion to the substrate.

摘要翻译： 公开了一种制备紫外线固化涂料的方法，包括以下步骤：（a-1）40至90重量份的胶体二氧化硅的水解反应，和（a-2）60至10重量份的 含有不低于50重量％的式（I）化合物的烷氧基硅烷化合物的水解产物（I）当脱水量在一定范围内时，用非极性溶剂代替胶体二氧化硅的分散介质 理论值的50〜90％; 并在非极性溶剂的存在下保持30至90重量％的固体组分的状态进行进一步的缩合反应。 含有紫外线固化型涂料的涂料组合物可以形成耐磨性，表面平滑性，耐热性，耐化学性，耐久性，耐候性和对基材的粘合性优异的抗磨损涂膜。

公开(公告)号：US5260361A

公开(公告)日：1993-11-09

申请号：US978423

申请日：1992-11-18

申请人： Hiroshi Fukushima ,  Misao Tamura ,  Osamu Takemoto ,  Takaji Kawaguchi

发明人： Hiroshi Fukushima ,  Misao Tamura ,  Osamu Takemoto ,  Takaji Kawaguchi

IPC分类号： C08F2/44 ,  C08F20/10 ,  C08F20/34 ,  C08F220/28 ,  C08F220/36 ,  C08F290/00 ,  C08F299/02 ,  C08F299/06 ,  C09D4/00 ,  C09D4/02 ,  C09D5/00 ,  C09D171/00 ,  C09D175/14 ,  C08L75/04

CPC分类号： C09D4/00 ,  Y10T428/31551

摘要： Disclosed is a coating composition comprising (A) 10 to 70 parts by weight of a poly(meth)acrylate of mono- or polypentaerythritol, (B) 5 to 50 parts by weight of a urethane poly(meth)acrylate having at least two unsaturated double bonds in the molecule, (C) 5 to 50 parts by weight of a poly[(meth)acryloyloxyalkyl] (iso)cyanurate, (D) 2 to 30 parts by weight of an ultraviolet absorber, (E) 0.1 to 10 parts by weight of a photopolymerization initiator, and (F) 0.1 to 5 parts by weight of a hindered amine type light stabilizer, provided that the combined amount of components (A) to (F) is 100 parts by weight. This coating composition can form a crosslinked and cured film having excellent abrasion resistance, surface smoothness, thermal resistance, chemical resistance, durability, weather resistance and adhesion to the substrate.

公开(公告)号：US4367245A

公开(公告)日：1983-01-04

申请号：US246942

申请日：1981-03-24

申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

IPC分类号： C08F20/00 ,  B05D3/06 ,  B05D7/02 ,  C08F2/48 ,  C08F20/10 ,  C08F20/26 ,  C08F22/10 ,  C08F220/28 ,  C08F290/00 ,  C08F299/02 ,  C08J7/04 ,  C09D4/00 ,  C09D133/04

CPC分类号： C08F22/105 ,  C09D4/00

摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer mixture comprising (i) 25-75 wt. % of at least one polyfunctional monomer of the formula (I): ##STR1## wherein at least three of X.sub.11, X.sub.12, X.sub.13, X.sub.22, X.sub.23 -X.sub.n2, X.sub.n3 and X.sub.14 are CH.sub.2 .dbd.CH.C00-- and the remaining groups are --OH, and n is an integer of 1-5, (ii) 25-75 wt. % of at least one polyfunctional monomer of the formula (II): ##STR2## wherein at least three of the R groups are CH.sub.2 .dbd.CH COO-- and each of the remaining is H or --OH, n.sub.1, n.sub.2, n.sub.3, n.sub.4, m.sub.1, m.sub.2, m.sub.3 and m.sub.4 are integers of 0, 1 or 2, and X is an integer of 1 to 10 and (iii) 0 to 50 wt. % of a monomer containing one acryloyloxy group and having a boiling point of at least 150.degree. C. at normal pressure and a viscosity of not higher than 20 cps/20.degree. C., and (b) 0.01-6.0 wt. parts, based on 100 wt. parts of the polyfunctional monomer mixture, of at least one photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with utraviolet rays in air to form a crosslinked coating film having a thickness of 1-30 microns.

摘要翻译： 描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。 该组合物包含（a）多官能单体混合物，其包含（i）25-75wt。 ％的至少一种式（I）的多官能单体：其中X11，X12，X13，X22，X23-Xn2，Xn3和X14中的至少三个是CH2 = CH。 C00-，其余基团为-OH，n为1-5的整数，（ii）25-75wt。 ％的至少一种式（II）的多官能单体：其中至少三个R基团是CH 2 = CH COO-，并且其中每一个是H或-OH， n1，n2，n3，n4，m1，m2，m3和m4为0,1或2的整数，X为1〜10的整数，（iii）0〜50重量％ ％的含有1个丙烯酰氧基的单体，沸点在常压下为至少150℃，粘度不高于20cps / 20℃，（b）0.01-6.0wt。 基于100wt。 部分多官能单体混合物，至少一种光敏剂。 将涂料组合物涂布在合成树脂成型制品上，然后在空气中用紫外线照射，形成厚度为1-30微米的交联涂膜。

公开(公告)号：US5449702A

公开(公告)日：1995-09-12

申请号：US982726

申请日：1992-11-27

申请人： Suehiro Tayama ,  Misao Tamura ,  Tsukasa Mizobuchi

发明人： Suehiro Tayama ,  Misao Tamura ,  Tsukasa Mizobuchi

IPC分类号： C08F290/06 ,  C09D4/00 ,  C09D4/02 ,  C09D5/00 ,  C09D183/04 ,  C09D183/06 ,  C09D183/07 ,  C08F2/46 ,  C08J3/28

CPC分类号： C09D183/04 ,  C09D183/06 ,  C09D4/00

摘要： Disclosed is a coating composition comprising(A) 5 to 60 parts by weight, on a solid basis, of colloidal silica,(B) 5 to 70 parts by weight of a hydrolyzate and/or hydrolyzed and partially condensed product of a compound of the general formula ##STR1## (C) 10 to 80 parts by weight of a polyfunctional monomer containing a monomer of the general formula ##STR2## and (D) 0.01 to 5 parts by weight of a photopolymerization initiator containing a compound of the general formula ##STR3## provided that the combined amount of components (A), (B), (C) and (D) is 100 parts by weight.This coating composition can be cured in air by exposure to ultraviolet light, and the resulting cured film is excellent in various properties (such as abrasion resistance) and adhesion to the substrate.

摘要翻译： 公开了一种涂料组合物，其包含（A）5至60重量份的基于固体的胶态二氧化硅，（B）5至70重量份的水解产物和/或水解和部分缩合的产物 通式（I）（C）（C）10〜80重量份含有通式（II）的单体和（D）的多官能单体0.01〜5重量份的光聚合引发剂，其含有 组分（A），（B），（C）和（D）的通式nt的化合物为100重量份。 该涂料组合物可以通过暴露在紫外线下在空气中固化，所得到的固化膜具有优异的各种性能（如耐磨性）和对基材的粘合性。

公开(公告)号：US4339474A

公开(公告)日：1982-07-13

申请号：US239202

申请日：1981-03-03

申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

IPC分类号： C08F2/48 ,  C09D4/06 ,  B05D3/06 ,  C08F8/00

CPC分类号： C09D4/06

摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer composition comprising (i) 40-100 wt. % of a polyfunctional monomer containing at least three methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 900 and (ii) 0-60 wt. % of a mono- or bi-functional monomer having one or two methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 300 per methacryloyloxy or acryloyloxy group, (b) 5-35 parts by wt., based on 100 wt. parts of the monomer composition, of at least one ultraviolet absorber, (c) 0.5-8 wt. parts, based on 100 parts by wt. of the monomer composition, of at least one polymeric material selected from polymers of alkyl methacrylates and alkyl acrylates, and (d) 0.01-6 parts by wt., based on 100 parts by wt. of the monomer composition, of a photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with ultraviolet rays in an inert gas or air to form a crosslinked coating film having a thickness of 1 to 30 microns.

摘要翻译： 描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。 该组合物包含（a）多官能单体组合物，其包含（i）40-100wt。 ％的分子中含有至少三个甲基丙烯酰氧基或丙烯酰氧基并具有不高于约900的MW的多官能单体和（ii）0-60重量％ ％的分子中具有1个或2个甲基丙烯酰氧基或丙烯酰氧基的单功能或双官能单体，每个甲基丙烯酰氧基或丙烯酰氧基具有不高于约300的MW，（b）5-35重量份，基于 100重量 单体组合物的部分，至少一种紫外线吸收剂，（c）0.5-8wt。 部分，基于100重量份。 至少一种选自甲基丙烯酸烷基酯和丙烯酸烷基酯的聚合物的聚合物材料，和（d）基于100重量份的重量比为0.01-6重量份。 的单体组合物。 将涂料组合物涂布在合成树脂成形制品上，然后在惰性气体或空气中用紫外线照射，形成厚度为1至30微米的交联涂膜。

公开(公告)号：US4388345A

公开(公告)日：1983-06-14

申请号：US343221

申请日：1982-01-27

申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

IPC分类号： C09D5/00 ,  C08J7/04 ,  C08J7/16 ,  C09D4/00 ,  B05D3/06

CPC分类号： C08J7/16 ,  C09D4/00 ,  C08J2331/00 ,  Y10T428/31507

摘要： A shaped article of synthetic resins, such as polydiethylene glycol bisallylcarbonate, is coated with the following coating composition and then irradiated with ultraviolet rays, whereby the coating composition deposited on the shaped article is cured to form a coating film having an excellent abrasion resistance, surface smoothness, adhesion to the substrate resin, flexibility, heat resistance, solvent resistance and durability. The coating composition comprised of (a) a mixture of, based on the weight of the mixture, (i) 25-99.95 wt. % of at least one polyfunctional monomer having at least three acryloyloxy or methacryloyloxy groups, (ii) 0-50 wt. % of at least one mono- or bi-functional monomer having one or two polymerizable unsaturated groups and (iii) 0.05-25 wt. % of at least one organic acid which has at least one halogen substituent (fluorine, chlorine or bromine) and which is liquid at normal temperature and pressure, and (b) 0.01-10 wt. parts, based on 100 wt. parts of said mixture, of a photosensitizer. The coating composition may contain 0.05-25 wt. % of at least one compound having an acrylamide or methacrylamide group and a hydroxyl group or groups.

摘要翻译： 合成树脂如聚二甘醇双烯丙基碳酸酯的成形制品用以下涂料组合物涂覆，然后用紫外线照射，由此沉积在成型制品上的涂料组合物固化以形成具有优异耐磨性，表面 平滑性，与基材树脂的粘合性，柔软性，耐热性，耐溶剂性和耐久性。 涂料组合物包含（a）基于混合物重量的混合物，（i）25-99.95wt。 至少一种具有至少三个丙烯酰氧基或甲基丙烯酰氧基的多官能单体的％，（ii）0-50wt。 ％的至少一种具有一个或两个可聚合不饱和基团的单官能或双官能单体和（iii）0.05-25wt。 至少一种具有至少一个卤素取代基（氟，氯或溴）并在常温常压下为液体的有机酸的％，和（b）0.01-10重量％ 基于100wt。 所述混合物的一部分，光敏剂。 涂料组合物可以含有0.05-25wt。 ％的至少一种具有丙烯酰胺或甲基丙烯酰胺基团和羟基或基团的化合物。