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    Coating composition and process for preparing synthetic resin shaped articles by using same
    1.
    发明授权
    Coating composition and process for preparing synthetic resin shaped articles by using same 失效
    涂料组合物及其制备方法

    公开(公告)号：US4367245A

    公开(公告)日：1983-01-04

    申请号：US246942

    申请日：1981-03-24

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    IPC分类号： C08F20/00 ,  B05D3/06 ,  B05D7/02 ,  C08F2/48 ,  C08F20/10 ,  C08F20/26 ,  C08F22/10 ,  C08F220/28 ,  C08F290/00 ,  C08F299/02 ,  C08J7/04 ,  C09D4/00 ,  C09D133/04

    CPC分类号： C08F22/105 ,  C09D4/00

    摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer mixture comprising (i) 25-75 wt. % of at least one polyfunctional monomer of the formula (I): ##STR1## wherein at least three of X.sub.11, X.sub.12, X.sub.13, X.sub.22, X.sub.23 -X.sub.n2, X.sub.n3 and X.sub.14 are CH.sub.2 .dbd.CH.C00-- and the remaining groups are --OH, and n is an integer of 1-5, (ii) 25-75 wt. % of at least one polyfunctional monomer of the formula (II): ##STR2## wherein at least three of the R groups are CH.sub.2 .dbd.CH COO-- and each of the remaining is H or --OH, n.sub.1, n.sub.2, n.sub.3, n.sub.4, m.sub.1, m.sub.2, m.sub.3 and m.sub.4 are integers of 0, 1 or 2, and X is an integer of 1 to 10 and (iii) 0 to 50 wt. % of a monomer containing one acryloyloxy group and having a boiling point of at least 150.degree. C. at normal pressure and a viscosity of not higher than 20 cps/20.degree. C., and (b) 0.01-6.0 wt. parts, based on 100 wt. parts of the polyfunctional monomer mixture, of at least one photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with utraviolet rays in air to form a crosslinked coating film having a thickness of 1-30 microns.

    摘要翻译： 描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。 该组合物包含（a）多官能单体混合物，其包含（i）25-75wt。 ％的至少一种式（I）的多官能单体：其中X11，X12，X13，X22，X23-Xn2，Xn3和X14中的至少三个是CH2 = CH。 C00-，其余基团为-OH，n为1-5的整数，（ii）25-75wt。 ％的至少一种式（II）的多官能单体：其中至少三个R基团是CH 2 = CH COO-，并且其中每一个是H或-OH， n1，n2，n3，n4，m1，m2，m3和m4为0,1或2的整数，X为1〜10的整数，（iii）0〜50重量％ ％的含有1个丙烯酰氧基的单体，沸点在常压下为至少150℃，粘度不高于20cps / 20℃，（b）0.01-6.0wt。 基于100wt。 部分多官能单体混合物，至少一种光敏剂。 将涂料组合物涂布在合成树脂成型制品上，然后在空气中用紫外线照射，形成厚度为1-30微米的交联涂膜。

    Coating composition and process for preparing synthetic resin shaped articles by using same
    2.
    发明授权
    Coating composition and process for preparing synthetic resin shaped articles by using same 失效
    涂料组合物及其制备方法

    公开(公告)号：US4388345A

    公开(公告)日：1983-06-14

    申请号：US343221

    申请日：1982-01-27

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    IPC分类号： C09D5/00 ,  C08J7/04 ,  C08J7/16 ,  C09D4/00 ,  B05D3/06

    CPC分类号： C08J7/16 ,  C09D4/00 ,  C08J2331/00 ,  Y10T428/31507

    摘要： A shaped article of synthetic resins, such as polydiethylene glycol bisallylcarbonate, is coated with the following coating composition and then irradiated with ultraviolet rays, whereby the coating composition deposited on the shaped article is cured to form a coating film having an excellent abrasion resistance, surface smoothness, adhesion to the substrate resin, flexibility, heat resistance, solvent resistance and durability. The coating composition comprised of (a) a mixture of, based on the weight of the mixture, (i) 25-99.95 wt. % of at least one polyfunctional monomer having at least three acryloyloxy or methacryloyloxy groups, (ii) 0-50 wt. % of at least one mono- or bi-functional monomer having one or two polymerizable unsaturated groups and (iii) 0.05-25 wt. % of at least one organic acid which has at least one halogen substituent (fluorine, chlorine or bromine) and which is liquid at normal temperature and pressure, and (b) 0.01-10 wt. parts, based on 100 wt. parts of said mixture, of a photosensitizer. The coating composition may contain 0.05-25 wt. % of at least one compound having an acrylamide or methacrylamide group and a hydroxyl group or groups.

    摘要翻译： 合成树脂如聚二甘醇双烯丙基碳酸酯的成形制品用以下涂料组合物涂覆，然后用紫外线照射，由此沉积在成型制品上的涂料组合物固化以形成具有优异耐磨性，表面 平滑性，与基材树脂的粘合性，柔软性，耐热性，耐溶剂性和耐久性。 涂料组合物包含（a）基于混合物重量的混合物，（i）25-99.95wt。 至少一种具有至少三个丙烯酰氧基或甲基丙烯酰氧基的多官能单体的％，（ii）0-50wt。 ％的至少一种具有一个或两个可聚合不饱和基团的单官能或双官能单体和（iii）0.05-25wt。 至少一种具有至少一个卤素取代基（氟，氯或溴）并在常温常压下为液体的有机酸的％，和（b）0.01-10重量％ 基于100wt。 所述混合物的一部分，光敏剂。 涂料组合物可以含有0.05-25wt。 ％的至少一种具有丙烯酰胺或甲基丙烯酰胺基团和羟基或基团的化合物。

    Coating composition and process for preparing synthetic resin shaped articles by using same
    3.
    发明授权
    Coating composition and process for preparing synthetic resin shaped articles by using same 失效
    涂料组合物及其制备方法

    公开(公告)号：US4339474A

    公开(公告)日：1982-07-13

    申请号：US239202

    申请日：1981-03-03

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    IPC分类号： C08F2/48 ,  C09D4/06 ,  B05D3/06 ,  C08F8/00

    CPC分类号： C09D4/06

    摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer composition comprising (i) 40-100 wt. % of a polyfunctional monomer containing at least three methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 900 and (ii) 0-60 wt. % of a mono- or bi-functional monomer having one or two methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 300 per methacryloyloxy or acryloyloxy group, (b) 5-35 parts by wt., based on 100 wt. parts of the monomer composition, of at least one ultraviolet absorber, (c) 0.5-8 wt. parts, based on 100 parts by wt. of the monomer composition, of at least one polymeric material selected from polymers of alkyl methacrylates and alkyl acrylates, and (d) 0.01-6 parts by wt., based on 100 parts by wt. of the monomer composition, of a photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with ultraviolet rays in an inert gas or air to form a crosslinked coating film having a thickness of 1 to 30 microns.

    摘要翻译： 描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。 该组合物包含（a）多官能单体组合物，其包含（i）40-100wt。 ％的分子中含有至少三个甲基丙烯酰氧基或丙烯酰氧基并具有不高于约900的MW的多官能单体和（ii）0-60重量％ ％的分子中具有1个或2个甲基丙烯酰氧基或丙烯酰氧基的单功能或双官能单体，每个甲基丙烯酰氧基或丙烯酰氧基具有不高于约300的MW，（b）5-35重量份，基于 100重量 单体组合物的部分，至少一种紫外线吸收剂，（c）0.5-8wt。 部分，基于100重量份。 至少一种选自甲基丙烯酸烷基酯和丙烯酸烷基酯的聚合物的聚合物材料，和（d）基于100重量份的重量比为0.01-6重量份。 的单体组合物。 将涂料组合物涂布在合成树脂成形制品上，然后在惰性气体或空气中用紫外线照射，形成厚度为1至30微米的交联涂膜。

    Delustering coating composition excellent in abrasion resistance
    4.
    发明授权
    Delustering coating composition excellent in abrasion resistance 失效
    具有优异耐磨性的清漆涂料组合物

    公开(公告)号：US4518472A

    公开(公告)日：1985-05-21

    申请号：US525895

    申请日：1983-08-24

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Masahiro Sugimori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Masahiro Sugimori

    IPC分类号： C08F2/48 ,  C08F285/00 ,  C08J7/04 ,  C09D4/06 ,  C08F220/00 ,  C09D3/00

    CPC分类号： C08J7/047 ,  C08F285/00 ,  C09D4/06 ,  C08J2333/06 ,  C08J2433/00

    摘要： A coating composition curable by an activation energy ray, which comprises (a) 100 parts by weight of a monomer mixture (A) comprising at least 30% by weight of a compound having at least 3 acryloyloxy and/or methacryloyloxy groups in the molecule and up to 70% by weight of a compound having 1 to 2 .alpha.,.beta.-ethylenically unsaturated bonds in the molecule, (b) 0.01 to 6.0 parts by weight of at least one photosensitizer and (c) 0.5 to 30 parts by weight of an emulsion type crosslinked polymer or copolymer of a reactive monomer having one .alpha.,.beta.-ethylenically unsaturated bond in the molecule and a reactive monomer having at least two .alpha.,.beta.-ethylenically unsaturated bonds in the molecule.

    摘要翻译： 一种由活化能射线固化的涂料组合物，其包含（a）100重量份的包含至少30重量％的分子中具有至少3个丙烯酰氧基和/或甲基丙烯酰氧基的化合物的单体混合物（A），和 至多70重量％的分子中具有1至2个α，β-烯属不饱和键的化合物，（b）0.01至6.0重量份的至少一种光敏剂和（c）0.5至30重量份的 分子中具有一个α，β-烯属不饱和键的反应性单体的乳液型交联聚合物或共聚物，以及在分子中具有至少两个α，β-烯属不饱和键的反应性单体。

    Flame retardant polyester resin compositions
    6.
    发明授权
    Flame retardant polyester resin compositions 失效
    阻燃聚酯树脂组合物

    公开(公告)号：US4504608A

    公开(公告)日：1985-03-12

    申请号：US461228

    申请日：1983-01-26

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    IPC分类号： C08L67/00 ,  C08G59/00 ,  C08K3/00 ,  C08K3/22 ,  C08K5/3492 ,  C08K5/3495 ,  C08L63/00 ,  C08L67/02 ,  C08L63/02

    CPC分类号： C08K5/34924

    摘要： Flame retardant reinforced with polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-30 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant component (I) to (II) is in the range of 0.2

    摘要翻译： 公开了用聚酯树脂组合物增强的阻燃剂，由下列通式（I）和（II）表示的玻璃纤维和阻燃剂体系以及三氧化锑。 阻燃剂体系是1-20重量份组分（I）和2-30重量份组分（II）的混合物，只要阻燃组分的重量比（I）/（II） I）至（II）在0.2 <（I）/（II）<4的范围内，阻燃剂（I）+（II）的总量在3-40重量份的范围内。 存在2至30重量份的三氧化锑，并且还存在5至60重量％的玻璃纤维，这两个百分比基于总树脂组合物的重量来表示。 树脂组合物除了是阻燃剂外还具有出色的机械，热性能和成型性。 其中X是氢，氯或溴，m的平均值为0至11，n的平均值为0至7，卤素 含量为10重量％以上。 R1和R2的值在附件说明书中给出。

    Flame retardant polyester resin compositions
    7.
    发明授权
    Flame retardant polyester resin compositions 失效
    阻燃聚酯树脂组合物

    公开(公告)号：US4562216A

    公开(公告)日：1985-12-31

    申请号：US568531

    申请日：1984-01-05

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    IPC分类号： C08L67/00 ,  C08K5/06 ,  C08K5/1515 ,  C08L67/02

    CPC分类号： C08K5/06 ,  C08K5/1515 ,  C08L67/02

    摘要： Flame retardant reinforced with thermoplastic polyester resin compositions are disclosed glass fiber and a system of flame retardants represented by the following general formulas (I) and (II), together with antimony trioxide. The flame retardant system is a blend of 1-20 parts by weight of component (I), and 2-40 parts by weight of component (II), provided the weight ratio (I)/(II) of the flame retardant components (I) to (II) is in the range of 0

    摘要翻译： 公开了用热塑性聚酯树脂组合物增强的阻燃剂，由下列通式（I）和（II）表示的玻璃纤维和阻燃剂体系以及三氧化锑。 阻燃剂体系是1-20重量份组分（I）和2-40重量份组分（II）的混合物，只要阻燃组分的重量比（I）/（II） I）至（II）的范围在0 <（I）/（II）≤5的范围内，阻燃剂（I）+（II）的总量在3-40份的范围内， 重量。 存在2至3重量份的三氧化锑，并且还存在5至60重量％的玻璃纤维，这两个百分比基于总树脂组合物的重量来表示。 树脂组合物除了具有阻燃性外，还具有突出的机械，热，成型和机加工性能。 其中X是氢，氯或溴，其中1和m的平均值分别为0〜11，卤素含量为10％以上， 重量。 R1和R2的值在附件说明书中给出。

    Glass fiber reinforced polyethylene terephthalate resin composition
    8.
    发明授权
    Glass fiber reinforced polyethylene terephthalate resin composition 失效
    玻璃纤维增​​强聚对苯二甲酸乙二醇酯树脂组合物

    公开(公告)号：US4351751A

    公开(公告)日：1982-09-28

    申请号：US217095

    申请日：1980-12-16

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Hiroshi Mori

    IPC分类号： C08K5/098 ,  C08K7/14 ,  C08L67/02 ,  C08L91/08

    CPC分类号： C08K5/098 ,  C08K7/14 ,  C08L67/02

    摘要： Polyethylene terephthalate type resin-containing molding compositions reinforced with glass fibers also containing from 0.03 to 5 weight percent of an organic caboxylic acid metal salt such as sodium stearate and an ether compound such as polyoxyethylene monononylphenyl ether present in an amount of from 0.1 up to 20 weight percent in which the average number of recurring alkylene oxide units is from 5 to 200 are disclosed. Also a solid or liquid paraffin or polyethylene wax may be included in an amount of from 0.3 to 5 weight percent. Moldings made from the disclosed compositions have a uniform appearance and exhibit improved heat resistance.

    摘要翻译： 还含有0.03〜5重量％的有机羧酸金属盐如硬脂酸钠和乙醚化合物如聚氧乙烯单壬基苯基醚的玻璃纤维增​​强聚对苯二甲酸乙二醇酯型树脂成型组合物，其量为0.1至20 公开了其中平均循环氧化烯单元数为5至200的重量百分数。 固体或液体石蜡或聚乙烯蜡的含量也可以为0.3〜5重量％。 由所公开的组合物制成的模制品具有均匀的外观并且显示出改进的耐热性。

    Novel polymer composition
    10.
    发明授权
    Novel polymer composition 失效
    新型聚合物组成

    公开(公告)号：US4510024A

    公开(公告)日：1985-04-09

    申请号：US542950

    申请日：1983-10-18

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai ,  Hajime Asai

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Nobuhiro Mukai ,  Hajime Asai

    IPC分类号： C08F2/58 ,  C09D5/44 ,  C25B3/00

    CPC分类号： C08F2/58 ,  C09D5/4476

    摘要： A polymer composition in which an organic polymer and carbon fiber are strongly combined and a process for producing the polymer composition by the electrolytic polymerization of a reactive monomer using the carbon fiber as an electrode, which process is characterized in that the polymerization is carried out by adding an aliphatic epoxy compound, alicyclic epoxy compound, organic titanate compound, or vinylsilane compound, as part or all of the reactive monomer.

    摘要翻译： 其中有机聚合物和碳纤维被强力组合的聚合物组合物和通过使用碳纤维作为电极的反应性单体的电解聚合制备聚合物组合物的方法，该方法的特征在于聚合由 添加脂族环氧化合物，脂环族环氧化合物，有机钛酸酯化合物或乙烯基硅烷化合物作为反应性单体的一部分或全部。