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    Coating composition and process for preparing synthetic resin shaped articles by using same
    1.
    发明授权
    Coating composition and process for preparing synthetic resin shaped articles by using same 失效
    涂料组合物及其制备方法

    公开(公告)号：US4367245A

    公开(公告)日：1983-01-04

    申请号：US246942

    申请日：1981-03-24

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    IPC分类号： C08F20/00 ,  B05D3/06 ,  B05D7/02 ,  C08F2/48 ,  C08F20/10 ,  C08F20/26 ,  C08F22/10 ,  C08F220/28 ,  C08F290/00 ,  C08F299/02 ,  C08J7/04 ,  C09D4/00 ,  C09D133/04

    CPC分类号： C08F22/105 ,  C09D4/00

    摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer mixture comprising (i) 25-75 wt. % of at least one polyfunctional monomer of the formula (I): ##STR1## wherein at least three of X.sub.11, X.sub.12, X.sub.13, X.sub.22, X.sub.23 -X.sub.n2, X.sub.n3 and X.sub.14 are CH.sub.2 .dbd.CH.C00-- and the remaining groups are --OH, and n is an integer of 1-5, (ii) 25-75 wt. % of at least one polyfunctional monomer of the formula (II): ##STR2## wherein at least three of the R groups are CH.sub.2 .dbd.CH COO-- and each of the remaining is H or --OH, n.sub.1, n.sub.2, n.sub.3, n.sub.4, m.sub.1, m.sub.2, m.sub.3 and m.sub.4 are integers of 0, 1 or 2, and X is an integer of 1 to 10 and (iii) 0 to 50 wt. % of a monomer containing one acryloyloxy group and having a boiling point of at least 150.degree. C. at normal pressure and a viscosity of not higher than 20 cps/20.degree. C., and (b) 0.01-6.0 wt. parts, based on 100 wt. parts of the polyfunctional monomer mixture, of at least one photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with utraviolet rays in air to form a crosslinked coating film having a thickness of 1-30 microns.

    摘要翻译： 描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。 该组合物包含（a）多官能单体混合物，其包含（i）25-75wt。 ％的至少一种式（I）的多官能单体：其中X11，X12，X13，X22，X23-Xn2，Xn3和X14中的至少三个是CH2 = CH。 C00-，其余基团为-OH，n为1-5的整数，（ii）25-75wt。 ％的至少一种式（II）的多官能单体：其中至少三个R基团是CH 2 = CH COO-，并且其中每一个是H或-OH， n1，n2，n3，n4，m1，m2，m3和m4为0,1或2的整数，X为1〜10的整数，（iii）0〜50重量％ ％的含有1个丙烯酰氧基的单体，沸点在常压下为至少150℃，粘度不高于20cps / 20℃，（b）0.01-6.0wt。 基于100wt。 部分多官能单体混合物，至少一种光敏剂。 将涂料组合物涂布在合成树脂成型制品上，然后在空气中用紫外线照射，形成厚度为1-30微米的交联涂膜。

    Coating composition and process for preparing synthetic resin shaped articles by using same
    2.
    发明授权
    Coating composition and process for preparing synthetic resin shaped articles by using same 失效
    涂料组合物及其制备方法

    公开(公告)号：US4339474A

    公开(公告)日：1982-07-13

    申请号：US239202

    申请日：1981-03-03

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    IPC分类号： C08F2/48 ,  C09D4/06 ,  B05D3/06 ,  C08F8/00

    CPC分类号： C09D4/06

    摘要： A coating composition for the preparation of synthetic resin shaped articles excellent in abrasion resistance and weatherability is described. This composition comprises (a) a polyfunctional monomer composition comprising (i) 40-100 wt. % of a polyfunctional monomer containing at least three methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 900 and (ii) 0-60 wt. % of a mono- or bi-functional monomer having one or two methacryloyloxy or acryloyloxy groups in the molecule and having a MW of not higher than about 300 per methacryloyloxy or acryloyloxy group, (b) 5-35 parts by wt., based on 100 wt. parts of the monomer composition, of at least one ultraviolet absorber, (c) 0.5-8 wt. parts, based on 100 parts by wt. of the monomer composition, of at least one polymeric material selected from polymers of alkyl methacrylates and alkyl acrylates, and (d) 0.01-6 parts by wt., based on 100 parts by wt. of the monomer composition, of a photosensitizer. The coating composition is coated on a synthetic resin shaped article and then, irradiated with ultraviolet rays in an inert gas or air to form a crosslinked coating film having a thickness of 1 to 30 microns.

    摘要翻译： 描述了用于制备耐磨性和耐候性优异的合成树脂成型制品的涂料组合物。 该组合物包含（a）多官能单体组合物，其包含（i）40-100wt。 ％的分子中含有至少三个甲基丙烯酰氧基或丙烯酰氧基并具有不高于约900的MW的多官能单体和（ii）0-60重量％ ％的分子中具有1个或2个甲基丙烯酰氧基或丙烯酰氧基的单功能或双官能单体，每个甲基丙烯酰氧基或丙烯酰氧基具有不高于约300的MW，（b）5-35重量份，基于 100重量 单体组合物的部分，至少一种紫外线吸收剂，（c）0.5-8wt。 部分，基于100重量份。 至少一种选自甲基丙烯酸烷基酯和丙烯酸烷基酯的聚合物的聚合物材料，和（d）基于100重量份的重量比为0.01-6重量份。 的单体组合物。 将涂料组合物涂布在合成树脂成形制品上，然后在惰性气体或空气中用紫外线照射，形成厚度为1至30微米的交联涂膜。

    Coating composition and process for preparing synthetic resin shaped articles by using same
    3.
    发明授权
    Coating composition and process for preparing synthetic resin shaped articles by using same 失效
    涂料组合物及其制备方法

    公开(公告)号：US4388345A

    公开(公告)日：1983-06-14

    申请号：US343221

    申请日：1982-01-27

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Misao Tamura

    IPC分类号： C09D5/00 ,  C08J7/04 ,  C08J7/16 ,  C09D4/00 ,  B05D3/06

    CPC分类号： C08J7/16 ,  C09D4/00 ,  C08J2331/00 ,  Y10T428/31507

    摘要： A shaped article of synthetic resins, such as polydiethylene glycol bisallylcarbonate, is coated with the following coating composition and then irradiated with ultraviolet rays, whereby the coating composition deposited on the shaped article is cured to form a coating film having an excellent abrasion resistance, surface smoothness, adhesion to the substrate resin, flexibility, heat resistance, solvent resistance and durability. The coating composition comprised of (a) a mixture of, based on the weight of the mixture, (i) 25-99.95 wt. % of at least one polyfunctional monomer having at least three acryloyloxy or methacryloyloxy groups, (ii) 0-50 wt. % of at least one mono- or bi-functional monomer having one or two polymerizable unsaturated groups and (iii) 0.05-25 wt. % of at least one organic acid which has at least one halogen substituent (fluorine, chlorine or bromine) and which is liquid at normal temperature and pressure, and (b) 0.01-10 wt. parts, based on 100 wt. parts of said mixture, of a photosensitizer. The coating composition may contain 0.05-25 wt. % of at least one compound having an acrylamide or methacrylamide group and a hydroxyl group or groups.

    摘要翻译： 合成树脂如聚二甘醇双烯丙基碳酸酯的成形制品用以下涂料组合物涂覆，然后用紫外线照射，由此沉积在成型制品上的涂料组合物固化以形成具有优异耐磨性，表面 平滑性，与基材树脂的粘合性，柔软性，耐热性，耐溶剂性和耐久性。 涂料组合物包含（a）基于混合物重量的混合物，（i）25-99.95wt。 至少一种具有至少三个丙烯酰氧基或甲基丙烯酰氧基的多官能单体的％，（ii）0-50wt。 ％的至少一种具有一个或两个可聚合不饱和基团的单官能或双官能单体和（iii）0.05-25wt。 至少一种具有至少一个卤素取代基（氟，氯或溴）并在常温常压下为液体的有机酸的％，和（b）0.01-10重量％ 基于100wt。 所述混合物的一部分，光敏剂。 涂料组合物可以含有0.05-25wt。 ％的至少一种具有丙烯酰胺或甲基丙烯酰胺基团和羟基或基团的化合物。

    Delustering coating composition excellent in abrasion resistance
    4.
    发明授权
    Delustering coating composition excellent in abrasion resistance 失效
    具有优异耐磨性的清漆涂料组合物

    公开(公告)号：US4518472A

    公开(公告)日：1985-05-21

    申请号：US525895

    申请日：1983-08-24

    申请人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Masahiro Sugimori

    发明人： Kazuo Kishida ,  Isao Sasaki ,  Kenji Kushi ,  Masahiro Sugimori

    IPC分类号： C08F2/48 ,  C08F285/00 ,  C08J7/04 ,  C09D4/06 ,  C08F220/00 ,  C09D3/00

    CPC分类号： C08J7/047 ,  C08F285/00 ,  C09D4/06 ,  C08J2333/06 ,  C08J2433/00

    摘要： A coating composition curable by an activation energy ray, which comprises (a) 100 parts by weight of a monomer mixture (A) comprising at least 30% by weight of a compound having at least 3 acryloyloxy and/or methacryloyloxy groups in the molecule and up to 70% by weight of a compound having 1 to 2 .alpha.,.beta.-ethylenically unsaturated bonds in the molecule, (b) 0.01 to 6.0 parts by weight of at least one photosensitizer and (c) 0.5 to 30 parts by weight of an emulsion type crosslinked polymer or copolymer of a reactive monomer having one .alpha.,.beta.-ethylenically unsaturated bond in the molecule and a reactive monomer having at least two .alpha.,.beta.-ethylenically unsaturated bonds in the molecule.

    摘要翻译： 一种由活化能射线固化的涂料组合物，其包含（a）100重量份的包含至少30重量％的分子中具有至少3个丙烯酰氧基和/或甲基丙烯酰氧基的化合物的单体混合物（A），和 至多70重量％的分子中具有1至2个α，β-烯属不饱和键的化合物，（b）0.01至6.0重量份的至少一种光敏剂和（c）0.5至30重量份的 分子中具有一个α，β-烯属不饱和键的反应性单体的乳液型交联聚合物或共聚物，以及在分子中具有至少两个α，β-烯属不饱和键的反应性单体。

    Liquid photosensitive resin composition containing carboxylated epoxy acrylates or methacrylates
    5.
    发明授权
    Liquid photosensitive resin composition containing carboxylated epoxy acrylates or methacrylates 失效
    含羧基环氧丙烯酸酯或甲基丙烯酸酯的液体感光性树脂组合物

    公开(公告)号：US4789620A

    公开(公告)日：1988-12-06

    申请号：US880738

    申请日：1986-07-01

    申请人： Isao Sasaki ,  Kenji Kushi ,  Ken-ichi Inukai

    发明人： Isao Sasaki ,  Kenji Kushi ,  Ken-ichi Inukai

    IPC分类号： G03F7/027 ,  G03F7/032 ,  H05K3/28 ,  G03C1/68

    CPC分类号： G03F7/032 ,  G03F7/027 ,  H05K3/287 ,  H05K2203/0793

    摘要： Disclosed is a liquid photosensitive resin composition comprising(a) an at least partially carboxyl-modified multifunctional epoxy acrylate and/or multifunctional epoxy methacrylate having an average acid value of 4 to 150 and a number average molecular weight of not greater than 5,000,(b) an acrylic and/or methacrylic cross-linking monomer and/or oligomer other than the epoxy acrylate and/or epoxy methacrylate,(c) an acrylic and/or methacrylic monoethylenically vinyl monomer,(d) an inorganic filler, and(e) a photo-initiator and/or photosensitizer.This liquid photosensitive resin composition has excellent alkali developability, yields a cured coating film having good adhesion and good electrical insulating properties under high-humidity conditions, and is suitable for use as a solder resist in the fabrication of printed circuit boards.

    摘要翻译： 公开了一种液体感光性树脂组合物，其包含（a）至少部分羧基改性的多官能环氧丙烯酸酯和/或平均酸值为4〜150，数均分子量为5000以下的多官能环氧丙烯酸酯（b ）丙烯酸和/或甲基丙烯酸单烯属乙烯基单体以外的丙烯酸和/或甲基丙烯酸交联单体和/或低聚物，（d）无机填料，和（e）丙烯酸和/ 光引发剂和/或光敏剂。 该液体感光性树脂组合物具有优异的碱显影性，得到在高湿度条件下具有良好的粘合性和良好的电绝缘性的固化涂膜，适用于制造印刷电路板的阻焊剂。

    Heat-resistant resin molded article with excellent abrasion resistance and process for producing the same
    8.
    发明授权
    Heat-resistant resin molded article with excellent abrasion resistance and process for producing the same 失效
    具有优异耐磨性的耐热树脂成型体及其制造方法

    公开(公告)号：US4689243A

    公开(公告)日：1987-08-25

    申请号：US783227

    申请日：1985-09-24

    申请人： Isao Sasaki ,  Kozi Nishida ,  Masaru Morimoto ,  Kenji Kushi

    发明人： Isao Sasaki ,  Kozi Nishida ,  Masaru Morimoto ,  Kenji Kushi

    IPC分类号： C08J7/04 ,  C08L33/24 ,  C09D4/00 ,  B05D3/06

    CPC分类号： C08L33/24 ,  C08J7/047 ,  C09D4/00 ,  C08J2423/00 ,  C08J2433/00 ,  Y10T428/261 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/269 ,  Y10T428/31721 ,  Y10T428/31928

    摘要： A heat-resistant resin molded article excellent in abrasion resistance, surface smoothness, solvent resistance, durability and adhesiveness between base material and cured film, consisting of (1) a resin molded article composed of 2% by weight or more of a structural unit represented by the following structural formula ##STR1## (wherein R is a hydrogen atom, an alkyl group, an aryl group or an alicyclic group of 1 to 20 carbon atoms) and 98% by weight or less of an ethylenic monomer unit and (2) a cured film formed on the surface of said resin molded article by curing a crosslinking-curable resin material containing 30% by weight or more of at least one monomer having three or more (meth)acryloyloxy groups in one molecule, as well as a process for producing said heat-resistant resin molded article.

    摘要翻译： PCT No.PCT / JP85 / 00071 Sec。 371日期：1985年9月24日 102（e）1985年9月24日PCT 1985年2月20日PCT PCT。 出版物WO85 / 03670 日本1985年8月29日。耐磨性，表面平滑性，耐溶剂性，耐久性和基材与固化膜之间的粘合性优异的耐热性树脂成型体，由（1）由2重量％ 以下结构式表示的结构单元，其中R为氢原子，烷基，芳基或碳原子数为1〜20的脂环族基），98重量％以下的结构单元 乙烯性单体单元和（2）通过将包含30重量％以上的至少一种具有三个以上（甲基）丙烯酰氧基的单体的交联固化性树脂材料固化在一个上形成在所述树脂成型体的表面上的固化膜 分子，以及制造所述耐热树脂模塑制品的方法。