公开(公告)号：US20120137664A1

公开(公告)日：2012-06-07

申请号：US13190399

申请日：2011-07-25

Applicant: REYAD AWWAD KHALAF SHAWABKEH ,  ABDALLA MAHMOUD ABULKIBASH ,  MUHAMMAD A. AL-SALEH

Inventor： REYAD AWWAD KHALAF SHAWABKEH ,  ABDALLA MAHMOUD ABULKIBASH ,  MUHAMMAD A. AL-SALEH

IPC: F01N3/10

CPC classification number: F01N3/04 ,  F01N3/0892 ,  F01N3/2006 ,  F01N5/02 ,  F01N2610/04 ,  Y02A50/2322 ,  Y02T10/16 ,  Y02T10/26

Abstract: The vehicle electrocatalyzer for recycling carbon dioxide to fuel hydrocarbons includes a main tubular member having a plurality of tubular catalytic cells, electrically connected in series disposed inside and separated from one another by semipermeable membranes allowing the passage of fluids, but not solids. The electrocatalyzer can be attached in the exhaust system where hydrogen could be generated by the electrolysis of water. Metallic copper, iron, carbonaceous materials (such as activated carbon, carbon nanomaterials, or graphite), metal oxides, or metal-supported catalysts may be used in each catalytic cell. A DC current connected across the cells is used to initiate reaction of the carbon dioxide with hydrogen gas. The resulting hydrocarbons are recycled back to the vehicle engine and used as a makeup fuel.

Abstract translation: 用于将二氧化碳再循环到燃料烃的车辆电催化剂包括具有多个管状催化单元的主管状构件，其串联设置在内部并通过允许流体而不是固体的半透膜彼此分离。 电催化剂可以连接在排气系统中，其中可以通过水的电解产生氢气。 金属铜，铁，碳质材料（如活性炭，碳纳米材料或石墨），金属氧化物或金属负载型催化剂可用于各催化剂。 使用连接在电池上的直流电流来引发二氧化碳与氢气的反应。 所得的碳氢化合物被循环回到车辆发动机并用作补充燃料。

公开(公告)号：US06908876B2

公开(公告)日：2005-06-21

申请号：US10414615

申请日：2003-04-16

Applicant: Muhammad Atiqullah ,  Akhlaq Moman ,  Muhammad Naseem Akhtar ,  Atieh Abu-Raqabah ,  Syriac J. Palackal ,  Muhammad A. Al-Saleh ,  Faizur Rahman ,  Muhammad Ibrahim ,  Javaid H. Khan

Inventor： Muhammad Atiqullah ,  Akhlaq Moman ,  Muhammad Naseem Akhtar ,  Atieh Abu-Raqabah ,  Syriac J. Palackal ,  Muhammad A. Al-Saleh ,  Faizur Rahman ,  Muhammad Ibrahim ,  Javaid H. Khan

IPC: B01J31/00 ,  C08F20060101 ,  C08F2/00 ,  C08F4/44 ,  C08F4/64 ,  C08F4/642 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16

CPC classification number: C08F10/00 ,  C08F4/65925 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/65916 ,  C08F4/65912 ,  C08F2500/12 ,  C08F2500/03 ,  C08F210/14

Abstract: The present invention relates to a supported catalyst system for olefin polymerization which comprises at least one metallocene component and a support of an inorganic oxide of silica, aluminum or a polymer containing hydroxyl groups. The support is modified with an organogermane and/or organotin compound. The inventive catalyst system produces minimal reactor fouling, has excellent productivity and good hydrogen responsiveness. The present invention also relates to a process for preparing the catalyst system and to the slurry/suspension or gas-phase polymerization of olefins using the catalytic system, optionally with a small amount of aluminoxane cocatalyst.

Abstract translation: 本发明涉及一种用于烯烃聚合的负载催化剂体系，其包括至少一种茂金属组分和二氧化硅，铝或含有羟基的聚合物的无机氧化物的载体。 载体用有机锗和/或有机锡化合物改性。 本发明的催化剂体系产生最小的反应器结垢，具有优异的生产率和良好的氢响应性。 本发明还涉及制备催化剂体系的方法以及使用催化体系（任选地少量的铝氧烷助催化剂）进行烯烃的淤浆/悬浮或气相聚合的方法。

公开(公告)号：US08329973B2

公开(公告)日：2012-12-11

申请号：US13353085

申请日：2012-01-18

Applicant: Tomoyuki Inui ,  Masayuki Inui, legal representative ,  Mohammad A. Ali ,  Muhammad A. Al-Saleh ,  Syed A. Ali ,  Khalid Al-Nawad ,  Tsutomo Okamoto ,  Katsuhiko Ishikawa ,  Minoru Hatayama

Inventor： Tomoyuki Inui ,  Mohammad A. Ali ,  Muhammad A. Al-Saleh ,  Syed A. Ali ,  Khalid Al-Nawad ,  Tsutomo Okamoto ,  Katsuhiko Ishikawa ,  Minoru Hatayama

IPC: C07C6/12

CPC classification number: B01J29/80 ,  B01J29/005 ,  B01J29/061 ,  B01J29/064 ,  B01J29/076 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/85 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/126 ,  C07C2521/04 ,  C07C2523/24 ,  C07C2523/28 ,  C07C2523/40 ,  C07C2523/755 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P20/52 ,  C07C15/08 ,  C07C15/06

Abstract: The multiple zeolite catalyst is a catalytic composition used to convert C9+ alkylaromatic hydrocarbons to BTX, particularly commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VIB and Group VIII of the Periodic Table of the Elements. The two zeolites should have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt. % molybdenum. The transalkylation reaction may be conducted in one or more reactors with a fixed bed, moving bed, or radial flow reactor at 200-540° C., a pressure of 1.0-5.0 MPa, and liquid hourly space velocity of 1.0-5.0 per hour.

Abstract translation: 多重沸石催化剂是用于将C 9+烷基芳族烃转化成BTX的催化组合物，特别是商业上有价值的二甲苯。 催化剂是通过混合至少两种选自丝光沸石，β沸石，ZSM-5，ZSM-11，ZSM-12，ZSM-22，ZSM-23，MFI拓扑沸石，NES拓扑沸石，EU-1，MAPO -36，SAPO-5，SAPO-11，SAPO-34和SAPO-41，并加入至少一种选自元素周期表的VIB族和VIII族的金属组分。 两种沸石应具有不同的物理和化学特性，如孔径和酸度。 示例性催化剂包括丝光沸石，ZSM-5和3wt。 ％钼。 烷基转移反应可以在固定床，移动床或径向流动反应器的一个或多个反应器中在200-540℃，压力为1.0-5.0MPa，液时空速为1.0-5.0 /小时 。

公开(公告)号：US08596047B2

公开(公告)日：2013-12-03

申请号：US13190399

申请日：2011-07-25

Applicant: Reyad Awwad Khalaf Shawabkeh ,  Abdalla Mahmoud Abulkibash ,  Muhammad A. Al-Saleh

Inventor： Reyad Awwad Khalaf Shawabkeh ,  Abdalla Mahmoud Abulkibash ,  Muhammad A. Al-Saleh

IPC: F01N3/10

CPC classification number: F01N3/04 ,  F01N3/0892 ,  F01N3/2006 ,  F01N5/02 ,  F01N2610/04 ,  Y02A50/2322 ,  Y02T10/16 ,  Y02T10/26

Abstract: The vehicle electrocatalyzer for recycling carbon dioxide to fuel hydrocarbons includes a main tubular member having a plurality of tubular catalytic cells, electrically connected in series disposed inside and separated from one another by semipermeable membranes allowing the passage of fluids, but not solids. The electrocatalyzer can be attached in the exhaust system where hydrogen could be generated by the electrolysis of water. Metallic copper, iron, carbonaceous materials (such as activated carbon, carbon nanomaterials, or graphite), metal oxides, or metal-supported catalysts may be used in each catalytic cell. A DC current connected across the cells is used to initiate reaction of the carbon dioxide with hydrogen gas. The resulting hydrocarbons are recycled back to the vehicle engine and used as a makeup fuel.

Abstract translation: 用于将二氧化碳再循环到燃料烃的车辆电催化剂包括具有多个管状催化单元的主管状构件，其串联设置在内部并通过允许流体而不是固体的半透膜彼此分离。 电催化剂可以连接在排气系统中，其中可以通过水的电解产生氢气。 金属铜，铁，碳质材料（如活性炭，碳纳米材料或石墨），金属氧化物或金属负载型催化剂可用于各催化剂。 使用连接在电池上的直流电流来引发二氧化碳与氢气的反应。 所得的碳氢化合物被循环回到车辆发动机并用作补充燃料。

公开(公告)号：US20120116139A1

公开(公告)日：2012-05-10

申请号：US13353085

申请日：2012-01-18

Applicant: TOMOYUKI INUI ,  MASAYUKI INUI ,  MOHAMMAD A. ALI ,  MUHAMMAD A. AL-SALEH ,  SYED A. ALI ,  KHALID AL-NAWAD ,  TSUTOMO OKAMOTO ,  KATSUHIKO ISHIKAWA ,  MINORU HATAYAMA

Inventor： TOMOYUKI INUI ,  MASAYUKI INUI ,  MOHAMMAD A. ALI ,  MUHAMMAD A. AL-SALEH ,  SYED A. ALI ,  KHALID AL-NAWAD ,  TSUTOMO OKAMOTO ,  KATSUHIKO ISHIKAWA ,  MINORU HATAYAMA

IPC: C07C7/00

CPC classification number: B01J29/80 ,  B01J29/005 ,  B01J29/061 ,  B01J29/064 ,  B01J29/076 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/85 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/126 ,  C07C2521/04 ,  C07C2523/24 ,  C07C2523/28 ,  C07C2523/40 ,  C07C2523/755 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P20/52 ,  C07C15/08 ,  C07C15/06

Abstract: The multiple zeolite catalyst is a catalytic composition used to convert C9+ alkylaromatic hydrocarbons to BTX, particularly commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VIB and Group VIII of the Periodic Table of the Elements. The two zeolites should have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt. % molybdenum. The transalkylation reaction may be conducted in one or more reactors with a fixed bed, moving bed, or radial flow reactor at 200-540° C., a pressure of 1.0-5.0 MPa, and liquid hourly space velocity of 1.0-5.0 per hour.

Abstract translation: 多重沸石催化剂是用于将C 9+烷基芳族烃转化成BTX的催化组合物，特别是商业上有价值的二甲苯。 催化剂是通过混合至少两种选自丝光沸石，β沸石，ZSM-5，ZSM-11，ZSM-12，ZSM-22，ZSM-23，MFI拓扑沸石，NES拓扑沸石，EU-1，MAPO -36，SAPO-5，SAPO-11，SAPO-34和SAPO-41，并加入至少一种选自元素周期表的VIB族和VIII族的金属组分。 两种沸石应具有不同的物理和化学特性，如孔径和酸度。 示例性催化剂包括丝光沸石，ZSM-5和3wt。 ％钼。 烷基转移反应可以在固定床，移动床或径向流动反应器的一个或多个反应器中在200-540℃，压力为1.0-5.0MPa，液时空速为1.0-5.0 /小时 。

公开(公告)号：US20100029467A1

公开(公告)日：2010-02-04

申请号：US12219927

申请日：2008-07-30

Applicant: Tomoyuki Inui ,  Masayuki Inui ,  Mohammad A. Ali ,  Muhammad A. Al-Saleh ,  Syed A. Ali ,  Khalid Al-Nawad ,  Tsutomu Okamoto ,  Katsuhiko Ishikawa ,  Minoru Hatayama

Inventor： Tomoyuki Inui ,  Masayuki Inui ,  Mohammad A. Ali ,  Muhammad A. Al-Saleh ,  Syed A. Ali ,  Khalid Al-Nawad ,  Tsutomu Okamoto ,  Katsuhiko Ishikawa ,  Minoru Hatayama

IPC: B01J29/46 ,  B01J29/072 ,  B01J29/48 ,  B01J29/26 ,  B01J29/076 ,  B01J29/24 ,  B01J29/40

CPC classification number: B01J29/80 ,  B01J29/005 ,  B01J29/061 ,  B01J29/064 ,  B01J29/076 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/85 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/126 ,  C07C2521/04 ,  C07C2523/24 ,  C07C2523/28 ,  C07C2523/40 ,  C07C2523/755 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/84 ,  C07C2529/85 ,  Y02P20/52 ,  C07C15/08 ,  C07C15/06

Abstract: The multiple zeolite catalyst is a catalytic composition used to convert C9+ alkylaromatic hydrocarbons to BTX, particularly commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VIB and Group VIII of the Periodic Table of the Elements. The two zeolites should have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt. % molybdenum. The transalkylation reaction may be conducted in one or more reactors with a fixed bed, moving bed, or radial flow reactor at 200-540° C., a pressure of 1.0-5.0 MPa, and liquid hourly space velocity of 1.0-5.0 per hour.

Abstract translation: 多重沸石催化剂是用于将C 9+烷基芳族烃转化成BTX的催化组合物，特别是商业上有价值的二甲苯。 催化剂是通过混合至少两种选自丝光沸石，β沸石，ZSM-5，ZSM-11，ZSM-12，ZSM-22，ZSM-23，MFI拓扑沸石，NES拓扑沸石，EU-1，MAPO -36，SAPO-5，SAPO-11，SAPO-34和SAPO-41，并加入至少一种选自元素周期表的VIB族和VIII族的金属组分。 两种沸石应具有不同的物理和化学特性，如孔径和酸度。 示例性催化剂包括丝光沸石，ZSM-5和3wt。 ％钼。 烷基转移反应可以在固定床，移动床或径向流动反应器的一个或多个反应器中在200-540℃，压力为1.0-5.0MPa，液时空速为1.0-5.0 /小时 。