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公开(公告)号:US20120116139A1
公开(公告)日:2012-05-10
申请号:US13353085
申请日:2012-01-18
申请人: TOMOYUKI INUI , MASAYUKI INUI , MOHAMMAD A. ALI , MUHAMMAD A. AL-SALEH , SYED A. ALI , KHALID AL-NAWAD , TSUTOMO OKAMOTO , KATSUHIKO ISHIKAWA , MINORU HATAYAMA
发明人: TOMOYUKI INUI , MASAYUKI INUI , MOHAMMAD A. ALI , MUHAMMAD A. AL-SALEH , SYED A. ALI , KHALID AL-NAWAD , TSUTOMO OKAMOTO , KATSUHIKO ISHIKAWA , MINORU HATAYAMA
IPC分类号: C07C7/00
CPC分类号: B01J29/80 , B01J29/005 , B01J29/061 , B01J29/064 , B01J29/076 , B01J29/18 , B01J29/26 , B01J29/40 , B01J29/48 , B01J29/85 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C6/126 , C07C2521/04 , C07C2523/24 , C07C2523/28 , C07C2523/40 , C07C2523/755 , C07C2529/18 , C07C2529/40 , C07C2529/84 , C07C2529/85 , Y02P20/52 , C07C15/08 , C07C15/06
摘要: The multiple zeolite catalyst is a catalytic composition used to convert C9+ alkylaromatic hydrocarbons to BTX, particularly commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VIB and Group VIII of the Periodic Table of the Elements. The two zeolites should have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt. % molybdenum. The transalkylation reaction may be conducted in one or more reactors with a fixed bed, moving bed, or radial flow reactor at 200-540° C., a pressure of 1.0-5.0 MPa, and liquid hourly space velocity of 1.0-5.0 per hour.
摘要翻译: 多重沸石催化剂是用于将C 9+烷基芳族烃转化成BTX的催化组合物,特别是商业上有价值的二甲苯。 催化剂是通过混合至少两种选自丝光沸石,β沸石,ZSM-5,ZSM-11,ZSM-12,ZSM-22,ZSM-23,MFI拓扑沸石,NES拓扑沸石,EU-1,MAPO -36,SAPO-5,SAPO-11,SAPO-34和SAPO-41,并加入至少一种选自元素周期表的VIB族和VIII族的金属组分。 两种沸石应具有不同的物理和化学特性,如孔径和酸度。 示例性催化剂包括丝光沸石,ZSM-5和3wt。 %钼。 烷基转移反应可以在固定床,移动床或径向流动反应器的一个或多个反应器中在200-540℃,压力为1.0-5.0MPa,液时空速为1.0-5.0 /小时 。
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公开(公告)号:US20100029467A1
公开(公告)日:2010-02-04
申请号:US12219927
申请日:2008-07-30
申请人: Tomoyuki Inui , Masayuki Inui , Mohammad A. Ali , Muhammad A. Al-Saleh , Syed A. Ali , Khalid Al-Nawad , Tsutomu Okamoto , Katsuhiko Ishikawa , Minoru Hatayama
发明人: Tomoyuki Inui , Masayuki Inui , Mohammad A. Ali , Muhammad A. Al-Saleh , Syed A. Ali , Khalid Al-Nawad , Tsutomu Okamoto , Katsuhiko Ishikawa , Minoru Hatayama
IPC分类号: B01J29/46 , B01J29/072 , B01J29/48 , B01J29/26 , B01J29/076 , B01J29/24 , B01J29/40
CPC分类号: B01J29/80 , B01J29/005 , B01J29/061 , B01J29/064 , B01J29/076 , B01J29/18 , B01J29/26 , B01J29/40 , B01J29/48 , B01J29/85 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C6/126 , C07C2521/04 , C07C2523/24 , C07C2523/28 , C07C2523/40 , C07C2523/755 , C07C2529/18 , C07C2529/40 , C07C2529/84 , C07C2529/85 , Y02P20/52 , C07C15/08 , C07C15/06
摘要: The multiple zeolite catalyst is a catalytic composition used to convert C9+ alkylaromatic hydrocarbons to BTX, particularly commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VIB and Group VIII of the Periodic Table of the Elements. The two zeolites should have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt. % molybdenum. The transalkylation reaction may be conducted in one or more reactors with a fixed bed, moving bed, or radial flow reactor at 200-540° C., a pressure of 1.0-5.0 MPa, and liquid hourly space velocity of 1.0-5.0 per hour.
摘要翻译: 多重沸石催化剂是用于将C 9+烷基芳族烃转化成BTX的催化组合物,特别是商业上有价值的二甲苯。 催化剂是通过混合至少两种选自丝光沸石,β沸石,ZSM-5,ZSM-11,ZSM-12,ZSM-22,ZSM-23,MFI拓扑沸石,NES拓扑沸石,EU-1,MAPO -36,SAPO-5,SAPO-11,SAPO-34和SAPO-41,并加入至少一种选自元素周期表的VIB族和VIII族的金属组分。 两种沸石应具有不同的物理和化学特性,如孔径和酸度。 示例性催化剂包括丝光沸石,ZSM-5和3wt。 %钼。 烷基转移反应可以在固定床,移动床或径向流动反应器的一个或多个反应器中在200-540℃,压力为1.0-5.0MPa,液时空速为1.0-5.0 /小时 。
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公开(公告)号:US06175046B1
公开(公告)日:2001-01-16
申请号:US09078058
申请日:1998-05-13
IPC分类号: C07C510
摘要: There is provided a catalyst that is highly resistant to sulfur and nitrogen compounds and active for hydrogenation and shows a low hydrocracking rate and a long service life as well as a method of converting aromatic hydrocarbons in hydrocarbon oil containing sulfur and nitrogen compounds into saturated hydrocarbons by using such a catalyst. A method of hydrogenating aromatic hydrocarbons in hydrocarbon oil containing 80 wt % or more of a fraction having a boiling point of 170 to 390° C. and said aromatic hydrocarbons is characterized in that the hydrocarbon oil is brought into contact with hydrogen in the presence of a catalyst containing clay minerals having principal ingredients of Si and Mg as carrier and at least one of the VIII-group metals of periodic table as active metal.
摘要翻译: 提供了一种对硫和氮化合物具有高度抗性并且对氢化有活性并且显示出低加氢裂化速率和较长使用寿命的催化剂,以及通过以下方法将含有硫和氮化合物的烃油中的芳族烃转化成饱和烃: 使用这种催化剂。 将含有80重量%以上的沸点为170〜390℃的馏分的烃油中的芳香烃氢化的方法和所述芳香烃的特征在于,烃油在氢气存在下与氢气接触 含有主要成分为Si和Mg作为载体的粘土矿物和作为活性金属的元素周期表中的至少一种VIII族金属的催化剂。
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公开(公告)号:US5316658A
公开(公告)日:1994-05-31
申请号:US914847
申请日:1992-07-15
申请人: Masaru Ushio , Tamio Nakano , Minoru Hatayama , Katuhiko Ishikawa , Masaru Sato
发明人: Masaru Ushio , Tamio Nakano , Minoru Hatayama , Katuhiko Ishikawa , Masaru Sato
CPC分类号: C10G65/04 , C10G2400/04 , F02B3/06
摘要: A process for the production of a low-sulfur diesel gas oil having a sulfur content of 0.05% by weight or lower and having a Saybolt color number of -10 or higher, from a petroleum distillate having a sulfur content of 0.1 to 2.0% by weight and having an inferior color and inferior oxidation stability comprises contacting the petroleum distillate with hydrogen in the presence of a hydro-treating catalyst which has at least one metal supported on said porous carrier, at a temperature of 350.degree. to 450.degree. C., and a pressure of 45 to 100 kg/cm.sup.2 in the first step to thereby produce materials having a sulfur content of 0.05% by weight or lower, and contacting further the materials issued from the first step with hydrogen in the presence of a hydro-treating catalyst which has at least one metal supported on said porous carrier, at a temperature of 200.degree. to 300.degree. C., and a pressure of 45 to 100 kg/cm.sup.2 in the second step to thereby produce the finished low-sulfur diesel gas oil.
摘要翻译: 一种硫含量为0.05重量%以下,Saybolt色数为-10以上的低硫柴油瓦斯油,其硫含量为0.1〜2.0%的石油馏分,由 重量较差,具有较差的颜色和较差的氧化稳定性包括在350℃至450℃的温度下,在至少一种负载在所述多孔载体上的金属的氢化处理催化剂存在下使石油馏分与氢气接触, 并且在第一步中的压力为45-100kg / cm2,从而制备硫含量为0.05重量%以下的材料,并在第一步骤中发出的材料与氢气在氢化处理 催化剂,其在至少一种负载在所述多孔载体上的金属,在200℃至300℃的温度和45至100kg / cm 2的压力下在第二步骤中,从而生产成品的低硫柴油机油 。
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公开(公告)号:US08329973B2
公开(公告)日:2012-12-11
申请号:US13353085
申请日:2012-01-18
申请人: Tomoyuki Inui , Masayuki Inui, legal representative , Mohammad A. Ali , Muhammad A. Al-Saleh , Syed A. Ali , Khalid Al-Nawad , Tsutomo Okamoto , Katsuhiko Ishikawa , Minoru Hatayama
发明人: Tomoyuki Inui , Mohammad A. Ali , Muhammad A. Al-Saleh , Syed A. Ali , Khalid Al-Nawad , Tsutomo Okamoto , Katsuhiko Ishikawa , Minoru Hatayama
IPC分类号: C07C6/12
CPC分类号: B01J29/80 , B01J29/005 , B01J29/061 , B01J29/064 , B01J29/076 , B01J29/18 , B01J29/26 , B01J29/40 , B01J29/48 , B01J29/85 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C07C6/126 , C07C2521/04 , C07C2523/24 , C07C2523/28 , C07C2523/40 , C07C2523/755 , C07C2529/18 , C07C2529/40 , C07C2529/84 , C07C2529/85 , Y02P20/52 , C07C15/08 , C07C15/06
摘要: The multiple zeolite catalyst is a catalytic composition used to convert C9+ alkylaromatic hydrocarbons to BTX, particularly commercially valuable xylenes. The catalyst is formed by mixing at least two zeolites selected from mordenite, beta zeolite, ZSM-5, ZSM-11, ZSM-12, ZSM-22, ZSM-23, MFI topology zeolite, NES topology zeolite, EU-1, MAPO-36, SAPO-5, SAPO-11, SAPO-34, and SAPO-41, and adding at least one metal component selected from Group VIB and Group VIII of the Periodic Table of the Elements. The two zeolites should have different physical and chemical characteristics, such as pore size and acidity. An exemplary catalyst includes mordenite, ZSM-5, and 3 wt. % molybdenum. The transalkylation reaction may be conducted in one or more reactors with a fixed bed, moving bed, or radial flow reactor at 200-540° C., a pressure of 1.0-5.0 MPa, and liquid hourly space velocity of 1.0-5.0 per hour.
摘要翻译: 多重沸石催化剂是用于将C 9+烷基芳族烃转化成BTX的催化组合物,特别是商业上有价值的二甲苯。 催化剂是通过混合至少两种选自丝光沸石,β沸石,ZSM-5,ZSM-11,ZSM-12,ZSM-22,ZSM-23,MFI拓扑沸石,NES拓扑沸石,EU-1,MAPO -36,SAPO-5,SAPO-11,SAPO-34和SAPO-41,并加入至少一种选自元素周期表的VIB族和VIII族的金属组分。 两种沸石应具有不同的物理和化学特性,如孔径和酸度。 示例性催化剂包括丝光沸石,ZSM-5和3wt。 %钼。 烷基转移反应可以在固定床,移动床或径向流动反应器的一个或多个反应器中在200-540℃,压力为1.0-5.0MPa,液时空速为1.0-5.0 /小时 。
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公开(公告)号:US20090159490A1
公开(公告)日:2009-06-25
申请号:US12161998
申请日:2007-01-18
申请人: Hiroyuki Seki , Masahiro Higashi , Minoru Hatayama
发明人: Hiroyuki Seki , Masahiro Higashi , Minoru Hatayama
IPC分类号: C10G73/02
CPC分类号: B01J29/084 , B01J21/02 , B01J29/126 , B01J35/023 , B01J2229/20 , B01J2229/42 , C10G47/12 , C10G47/16 , C10G47/18 , C10G2300/1022 , C10G2300/4081
摘要: The hydrocracking method of wax of the invention is a hydrocracking process wherein crude wax is subjected to hydrocracking and the untreated wax fraction that is produced after the hydrocracking is re-supplied for hydrocracking, and wherein hydrocracking of the mixture of the crude wax and untreated wax fraction is carried out in such a manner for a conversion ratio of 50-85% by mass from the wax fraction with a boiling point of 360° C. or above to the light fraction with a boiling point of below 360° C. in the presence of a hydrocracking catalyst. It is thereby possible to simultaneously achieve both an increased heart-cut fraction yield (as the product of the hydrocracking) and a reduced normal paraffin content in the heart-cut fraction when the untreated wax is hydrocracked by a bottom recycling system.
摘要翻译: 本发明的蜡的加氢裂化方法是加氢裂化方法,其中粗蜡经受加氢裂化,再加氢裂化后产生的未处理的蜡馏分用于加氢裂化,其中粗蜡和未处理的蜡的混合物的加氢裂化 以与沸点为360℃以上的蜡馏分相比,沸点低于360℃的轻馏分的转化率为50〜85质量%的转化率进行分馏, 存在加氢裂化催化剂。 因此,当未处理的蜡被底部回收系统加氢裂化时,可以同时实现增加的心脏馏分馏分收率(作为加氢裂化产物)和减少馏分馏分中的正常链烷烃含量。
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公开(公告)号:US5888379A
公开(公告)日:1999-03-30
申请号:US696069
申请日:1996-08-13
申请人: Masaru Ushio , Minoru Hatayama
发明人: Masaru Ushio , Minoru Hatayama
CPC分类号: C10G65/04
摘要: A process for producing a fuel oil base material having a lower sulfur content than that of stock oil and a dry sludge content of 0.05 mass % or less, which involves hydrotreating the stock oil having a dry sludge content of 0 to 5.0 mass % and a sulfur content of 1.0 to 10 mass % in two stages is provided, wherein the temperature of first-stage hydrotreatment is 340.degree. to 450.degree. C. and the temperature of second-stage hydrotreatment is 200.degree. to 440.degree. C. and maintained at a temperature lower than the temperature of the first-stage hydrotreatment.
摘要翻译: 一种生产硫含量低于原料油,干渣含量为0.05质量%以下的燃料油基材的制造方法,其特征在于,对干渣含量为0〜5.0质量%的原油进行加氢处理, 提供两级为1.0〜10质量%的硫含量,其中一级加氢处理的温度为340〜450℃,二级加氢处理的温度为200〜440℃,保持在 温度低于第一阶段加氢处理的温度。
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