摘要:
The present disclosure provides a photocatalyst that can utilize plasmon resonance based, near-perfect optical absorption for performing and enhancing photocatalytic reactions. The photocatalyst comprises a substrate and a reflective layer adjacent to the substrate. The reflective layer is configured to reflect light. The photocatalyst further comprises a spacer layer adjacent to the reflective layer. The spacer layer is formed of a semiconductor material or insulator and is at least partially transparent to light. A nanocomposite layer adjacent to the spacer layer is formed of a particles embedded in a matrix. The matrix can comprise a semiconductor, insulator or in some cases metallic pores. The particles can be metallic. Upon exposure to light, the particles can absorb far field electromagnetic radiation and excite plasmon resonances that interact with the reflective layer to form electromagnetic resonances.
摘要:
A system for collecting electromagnetic energy is provided. The system can include one or more electromagnetic energy collection devices. An individual device comprises a first electrically conductive layer adjacent to a semiconductor layer. The first electrically conductive layer forms a Schottky barrier to charge flow at an interface between the first electrically conductive layer and the semiconductor layer. A second electrically conductive layer is disposed adjacent to the semiconductor layer and away from the first electrically conductive layer. The second electrically conductive layer forms an ohmic contact with the semiconductor layer. Upon exposure of the device to electromagnetic energy, the first electrically conductive layer generates localized surface plasmon resonances that resonantly interact with the second electrically conductive layer, providing near perfect absorption of light. The absorption of light creates hot electrons in the first layer that cross the Schottky barrier to drive an external load.
摘要:
Electromagnetic energy collecting devices are described wherein a plasmonic near field resonating system absorbs light and transfers the light energy by plasmonic near field resonance to a semiconducting material that then separates the charge. The charge is then transported out of the device, converting light energy into electrical energy. The multiple nanoparticle plasmonic resonators are closely coupled with an electrically-conductive layer that creates electromagnetic resonances that provide for near perfect absorption of the incoming light. The device can be used both as an optical sensor and as a photovoltaic electromagnetic energy to electrical energy converter.
摘要:
An electromagnetic energy collector and sensor use enhanced fields to emit electrons for energy collection. The collector and sensor collect energy from visible light, infrared radiation and ultraviolet electromagnetic radiation. The collector and sensor include a waveguide with a geometry selected to enhance the electric field along a conductor to create a high, localized electric field, which causes electron emission across a gap to a return plane.