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1.发明申请公开(公告)号：US20190218674A1
公开(公告)日：2019-07-18
申请号：US16302572
申请日：2017-05-17
发明人： Zhifeng REN , Haiqing ZHOU , Fang YU , Shuo CHEN
CPC分类号： C25B11/0478 , C25B1/04 , C25B11/035 , C25B11/0405 , C25B11/0415 , C25B11/0447 , H01M4/8605 , H01M4/90 , Y02E60/366
摘要： A hybrid three dimensional (3D) hydrogen evolution reaction (HER) catalyst that is formed from a porous Ni foam support, a NiSe2 scaffold positioned on the support; and layered transition metal dichalcogenide (LTMDC) or first-row transition metal dichalcogenide particles positioned on the NiSe2 scaffold. The catalyst provides a low onset potential, large cathode current density, small Tafel slopes, and large exchange current densities, similar in catalytic power to Pt HER catalysts.
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公开(公告)号：US20190194814A1
公开(公告)日：2019-06-27
申请号：US16329428
申请日：2017-09-13
申请人： BIOSYNCAUCHO, S.L.
CPC分类号： C25B3/04 , C25B9/18 , C25B11/035 , C25B11/04 , C25B11/0405 , C25B11/0415 , C25B11/0447
摘要： It is provided a process for the preparation of methyl ethyl ketone by electroreduction of acetoin in aqueous media using a high hydrogen overvoltage cathode made of lead, the process comprising the steps of a) forming a solution by mixing acetoin with an aqueous medium and a supporting electrolyte soluble in such a medium, and b) electrolyzing said solution continuously or discontinuously in an electrochemical reactor by applying a voltage between an anode and the cathode using a direct current power supply at a current density from 500 to 5000 A/m2.
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公开(公告)号：US20190186026A1
公开(公告)日：2019-06-20
申请号：US16324765
申请日：2017-08-11
CPC分类号： C25B3/02 , C25B9/08 , C25B11/04 , C25B11/0405 , C25B11/0415 , C25B11/0478
摘要： Disclosed are methods for the electrochemical oxidation of a C—H bond in a compound to give a C—O bond or C—S bond. The oxidation of methane to methanol is described, as well as an electrochemical cell for performing the reaction.
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公开(公告)号：US20190186023A1
公开(公告)日：2019-06-20
申请号：US15847457
申请日：2017-12-19
申请人： Matthew L. McConnell
发明人： David L. Knies , Steven C. Hamm , Olga Y. Dmitriyeva , Richard F. Cantwell , Matthew L. McConnell
CPC分类号： C25B1/12 , C25B11/0405 , C25B11/0415 , C25B11/0447
摘要： An electrochemical hydrogen compression apparatus and a method for the collection and compression of hydrogen. The apparatus includes a cathode having a surface that is modified with a Tafel inhibitor that inhibits the Tafel reaction at the cathode surface. The same cathode surface may also include a Volmer catalyst to enhance the Volmer reaction at the cathode surface. The apparatus and method can advantageously increase the pressure of collected hydrogen, and may be useful for supplying the hydrogen to energy producing devices, such as a fuel cell.
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公开(公告)号：US20180334751A1
公开(公告)日：2018-11-22
申请号：US15775267
申请日：2016-12-22
申请人： DE NORA PERMELEC LTD
发明人： Akiyoshi MANABE
CPC分类号： C25B1/10 , C25B11/0405 , C25B11/0415 , C25B11/0473 , C25B15/00 , C25B15/08
摘要： Provided is an alkaline water electrolysis method capable of reducing or preventing degradation in cathode and anode performance even in an operation of repeated cycles of frequent starting and stopping, and/or even in an operation involving a significant output variation.The present invention provides an alkaline water electrolysis method including repeated cycles of intermittent operation, including an electrolysis step of performing alkaline water electrolysis including storing an electrolytic solution (16) in a circulation tank (5), feeding the electrolytic solution (16) in the circulation tank (5) to an anode chamber (2) and to a cathode chamber (3), returning an electrolytic solution generated in the cathode chamber (3) and an electrolytic solution generated in the anode chamber (2) to the circulation tank (5), mixing together these electrolytic solutions in the circulation tank (5), and recirculating the mixed electrolytic solution to the anode chamber (2) and to the cathode chamber (3), and a step of adding a catalyst activation material formed of a metal salt soluble in the electrolytic solution (16) prior to starting of the electrolysis step; and in the electrolysis step, a metal component in the catalyst activation material is deposited on a surface of the cathode.
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公开(公告)号：US20180327918A1
公开(公告)日：2018-11-15
申请号：US15777523
申请日：2016-11-02
发明人： Xiaoguang WANG , Lifeng LIU
CPC分类号： C25B11/0405 , C23C14/0021 , C25B1/04 , C25B11/035 , C25B11/0415 , C25B11/0447 , C25D3/12 , C25D5/48 , C25D5/54 , C25D7/00 , Y02E60/366
摘要： A system which includes two electrodes for use as cathode and anode, respectively, can perform water electrolysis. Each of the two electrodes includes a self-supporting electrode material containing a porous core material and a coating material. The porous core material includes carbon, and the coating material contains a transition metal phosphide. The two electrodes include identical electrode material, and each of the electrodes contains a connector to connect to a power source.
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公开(公告)号：US20180274113A1
公开(公告)日：2018-09-27
申请号：US15699689
申请日：2017-09-08
发明人： Ryota KITAGAWA , Yoshitsune SUGANO , Masakazu YAMAGIWA , Jun TAMURA , Yuki KUDO , Akihiko ONO , Satoshi MIKOSHIBA
CPC分类号： C25B15/02 , C25B1/00 , C25B1/003 , C25B1/10 , C25B3/04 , C25B9/08 , C25B9/10 , C25B11/04 , C25B11/0405 , C25B11/0415 , C25B11/0473 , Y02E60/366
摘要： An electrochemical reaction device of an embodiment includes: a reaction tank which includes a first storage storing a first electrolytic solution containing carbon dioxide, and a second storage storing a second electrolytic solution containing water; a reduction electrode which is disposed at the first storage, an oxidation electrode which is disposed at the second storage; a counter electrode which is used for potential sweep using the reduction electrode as a working electrode; a first power supply which is electrically connected to the reduction electrode and the oxidation electrode, to generate a reduction reaction and an oxidation reaction; and a second power supply which is electrically connected to the reduction electrode and the counter electrode, to sweep a potential while setting an oxidation potential of the reduction electrode or less as an upper limit potential.
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8.发明申请公开(公告)号：US20180265995A1
公开(公告)日：2018-09-20
申请号：US15695698
申请日：2017-09-05
发明人： Asahi MOTOSHIGE , Ryota Kitagawa , Yoshitsune Sugano , Akihiko Ono , Satoshi Mikoshiba , Yuki Kudo , Jun Tamura , Masakazu Yamagiwa , Eishi Tsutsumi , Takayuki Tsukagoshi
CPC分类号： C25B11/0405 , C25B1/00 , C25B1/04 , C25B1/10 , C25B3/04 , C25B9/08 , C25B11/0415 , C25B11/0426 , C25B11/0478 , Y02E60/366
摘要： An anode of an electrochemical reaction device includes: a stack having a conductive substrate and an oxide layer on the conductive substrate, the conductive substrate containing nickel or iron, and the oxide layer containing a nickel oxide or an iron oxide; and an oxidation catalyst layer disposed on the stack and containing an oxidation catalyst to oxidize water. A Raman spectrum of the oxide layer measured by a Raman spectroscopic analysis has a peak at a Raman shift of 500 cm−1 or more and 600 cm−1 or less or at a Raman shift of 1270 cm−1 or more and 1370 cm−1 or less.
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公开(公告)号：US20180258543A1
公开(公告)日：2018-09-13
申请号：US15761124
申请日：2016-09-22
发明人： Magnus ROSVALL , Bernth NORDIN
CPC分类号： C25B11/0405 , C02F1/46109 , C02F2001/46142 , C25B11/0431 , C25B11/0484
摘要： An electrode (10) is disclosed in which a first layer (30) of TiOx with a porosity in the range 0-3% is present on at least one surface of an electrode substrate (20), a second layer (40) of TiOx with a porosity of greater than 3 and up to 20% is present on the first layer (30) of TiOx. An electro-catalytic layer (50) is present on the second layer (40) of TiOx. x is in the range 1-2 for the first (30) and second layer (40) of TiOx. A process for the manufacture of the electrode (10) is disclosed as are uses thereof.
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公开(公告)号：US20180252677A1
公开(公告)日：2018-09-06
申请号：US15960542
申请日：2018-04-23
IPC分类号： G01N27/48 , G01N27/327 , C23C14/02 , C23C14/20 , C23C14/58 , C23C14/34 , G03F7/20 , G01N33/483
CPC分类号： G01N27/48 , A61B5/1473 , C23C14/0005 , C23C14/022 , C23C14/205 , C23C14/3464 , C23C14/5806 , C23C14/5846 , C25B1/02 , C25B9/06 , C25B11/0405 , C25B11/0415 , C25B11/0478 , G01N27/327 , G01N33/4833 , G01N33/49 , G03F7/70
摘要： A method for cancer diagnosis is disclosed. The method includes forming a plurality of cultured cells on an electrochemical biosensor placing the electrochemical biosensor in a medium solution comprising a cell culture solution of a plurality of biological cells, measuring a first electrochemical response from the electrochemical biosensor with the plurality of cultured cells, forming a plurality of stimulated cells on the electrochemical biosensor by ultrasonically stimulating of the plurality of cultured cells, measuring a second electrochemical response from the electrochemical biosensor with the plurality of stimulated cells, and detecting presence of cancer cells responsive to a difference between the first electrochemical response and the second electrochemical response being less than a threshold. Where, the first electrochemical response includes an electrochemical response of the plurality of cultured cells and the second electrochemical response includes an electrochemical response of the plurality of stimulated cells.
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