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    HIGH ENERGY DENSITY REDOX FLOW DEVICE
    3.
    发明申请
    HIGH ENERGY DENSITY REDOX FLOW DEVICE 有权
    高能量密度回流流量装置

    公开(公告)号：US20110200848A1

    公开(公告)日：2011-08-18

    申请号：US12970753

    申请日：2010-12-16

    申请人： Yet-Ming Chiang ,  W. Craig Carter ,  Bryan Y. Ho ,  Mihai Duduta ,  Pimpa Limthongkul

    发明人： Yet-Ming Chiang ,  W. Craig Carter ,  Bryan Y. Ho ,  Mihai Duduta ,  Pimpa Limthongkul

    IPC分类号： H01M4/36 ,  H01M14/00 ,  C01B21/24 ,  C01B21/22 ,  C01B31/24 ,  C01B21/36 ,  C07C69/96 ,  C07D307/33 ,  C07C43/11 ,  C07D307/06 ,  C07D317/12 ,  G01N33/00

    CPC分类号： H01M8/188 ,  B60L11/1875 ,  B60L11/1898 ,  H01M8/20 ,  Y02E60/528 ,  Y02T10/705 ,  Y02T90/34

    摘要： Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.

    摘要翻译： 描述了氧化还原流动装置，其中正极或负极活性材料中的至少一个是半固体或是冷凝离子存储电活性材料，并且其中至少一个电极活性材料被输送到 并且从发生电化学反应的组件产生电能。 半固体的电子导电性通过向悬浮液中添加导电颗粒和/或通过半固体中的固体的表面改性（例如，通过用更多的电子传导涂层材料涂覆固体以增加功率而增加） 的设备）。 公开了高能量密度和高功率氧化还原流量装置。 本文描述的氧化还原流动装置还可以包括一个或多个本发明的设计特征。 此外，还描述了用于氧化还原流动装置的发明化学物质。

    High Energy Density Redox Flow Device
    6.
    发明申请
    High Energy Density Redox Flow Device 有权
    高能量密度氧化还原流量装置

    公开(公告)号：US20140154546A1

    公开(公告)日：2014-06-05

    申请号：US14002304

    申请日：2011-12-16

    申请人： W. Craig Carter ,  Yet-Ming Chiang ,  Mihai Duduta ,  Pimpa Limthongkul

    发明人： W. Craig Carter ,  Yet-Ming Chiang ,  Mihai Duduta ,  Pimpa Limthongkul

    IPC分类号： H01M8/18 ,  H01M8/20

    CPC分类号： H01M8/0234 ,  B60L11/1879 ,  H01M8/0206 ,  H01M8/0215 ,  H01M8/0221 ,  H01M8/0228 ,  H01M8/188 ,  H01M8/20 ,  Y02E60/528 ,  Y02T10/7005 ,  Y02T10/7011 ,  Y02T10/705

    摘要： Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

    摘要翻译： 描述了氧化还原流动装置，其包括正极集电器，负极集电器和分离所述正集电器和负极集电器的离子可渗透膜，所述正和负集电器被定位和布置以限定正电活性区和负电活性区; 其中所述正电活性区和负电活性区中的至少一个包含可流动的半固体组合物，其包含能够在电池操作期间吸收或释放所述离子的离子存储化合物颗粒，并且其中所述离子存储化合物颗粒具有多分散尺寸分布 其中最细颗粒以总体积的至少5体积％存在，至少比总体积的至少5体积％中存在的最大颗粒小5倍。

    High energy density redox flow device
    7.
    发明授权
    High energy density redox flow device 有权
    高能量密度氧化还原流量装置

    公开(公告)号：US08722226B2

    公开(公告)日：2014-05-13

    申请号：US12970773

    申请日：2010-12-16

    申请人： Yet-Ming Chiang ,  William Craig Carter ,  Mihai Duduta ,  Pimpa Limthongkul

    发明人： Yet-Ming Chiang ,  William Craig Carter ,  Mihai Duduta ,  Pimpa Limthongkul

    IPC分类号： H01M4/36 ,  H01M6/30 ,  H01M2/38

    CPC分类号： H01M8/0234 ,  B60L11/1879 ,  H01M8/0206 ,  H01M8/0215 ,  H01M8/0221 ,  H01M8/0228 ,  H01M8/188 ,  H01M8/20 ,  Y02E60/528 ,  Y02T10/7005 ,  Y02T10/7011 ,  Y02T10/705

    摘要： Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

    摘要翻译： 描述了氧化还原流动装置，其包括正极集电器，负极集电器和分离所述正集电器和负极集电器的离子可渗透膜，所述正和负集电器被定位和布置以限定正电活性区和负电活性区; 其中所述正电活性区和负电活性区中的至少一个包含可流动的半固体组合物，其包含能够在电池操作期间吸收或释放所述离子的离子存储化合物颗粒，并且其中所述离子存储化合物颗粒具有多分散尺寸分布 其中最细颗粒以总体积的至少5体积％存在，至少比总体积的至少5体积％中存在的最大颗粒小5倍。

    HIGH ENERGY DENSITY REDOX FLOW DEVICE
    8.
    发明申请
    HIGH ENERGY DENSITY REDOX FLOW DEVICE 有权
    高能量密度回流流量装置

    公开(公告)号：US20110189520A1

    公开(公告)日：2011-08-04

    申请号：US12970773

    申请日：2010-12-16

    申请人： William C. CARTER ,  Yet-Ming CHIANG ,  Mihai DUDUTA ,  Pimpa LIMTHONGKUL

    发明人： William C. CARTER ,  Yet-Ming CHIANG ,  Mihai DUDUTA ,  Pimpa LIMTHONGKUL

    IPC分类号： H01M10/02 ,  H01M4/64

    CPC分类号： H01M8/0234 ,  B60L11/1879 ,  H01M8/0206 ,  H01M8/0215 ,  H01M8/0221 ,  H01M8/0228 ,  H01M8/188 ,  H01M8/20 ,  Y02E60/528 ,  Y02T10/7005 ,  Y02T10/7011 ,  Y02T10/705

    摘要： Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

    摘要翻译： 描述了氧化还原流动装置，其包括正极集电器，负极集电器和分离所述正集电器和负极集电器的离子可渗透膜，所述正和负集电器被定位和布置以限定正电活性区和负电活性区; 其中所述正电活性区和负电活性区中的至少一个包含可流动的半固体组合物，其包含能够在电池操作期间吸收或释放所述离子的离子存储化合物颗粒，并且其中所述离子存储化合物颗粒具有多分散尺寸分布 其中最细颗粒以总体积的至少5体积％存在，至少比总体积的至少5体积％中存在的最大颗粒小5倍。

    Electroactive material for secondary batteries and methods of preparation
    9.
    发明授权
    Electroactive material for secondary batteries and methods of preparation 失效
    二次电池用电极材料及其制备方法

    公开(公告)号：US06599662B1

    公开(公告)日：2003-07-29

    申请号：US09479154

    申请日：2000-01-07

    申请人： Yet-Ming Chiang ,  Gerbrand Ceder ,  Pimpa Limthongkul

    发明人： Yet-Ming Chiang ,  Gerbrand Ceder ,  Pimpa Limthongkul

    IPC分类号： H01M458

    CPC分类号： C01G3/00 ,  C01B3/001 ,  C01G23/00 ,  C01G31/00 ,  C01G37/00 ,  C01G45/1221 ,  C01G45/1235 ,  C01G45/1242 ,  C01G49/00 ,  C01G51/00 ,  C01P2002/32 ,  C01P2002/34 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2006/40 ,  H01M4/36 ,  H01M4/364 ,  H01M4/383 ,  H01M4/485 ,  H01M6/40 ,  H01M2004/027 ,  Y02E60/324

    摘要： This invention provides a composite material for use as an electrode in electrochemical devices. An electroactive composite material includes a first electroactive metal, the electroactive material including a phase enriched in a metal or metal alloy, MeI, capable of intercalating or alloying with a species selected from the group consisting of alkali metals and hydrogen, and a second material having the first active material intimately mixed therein. The second material includes a metal oxide, MeyIIOz, wherein the metals MeI have a less negative Gibbs free energy for alloying or compound formation with oxygen than the metals that comprise MeIIO. The materials of the invention comprise a first material that is an elemental metal, metal alloy, metal oxide, or other metal compound, selected so that it is able to alloy with lithium, and prepared in a dispersed one-, two- or three-dimensional form. The first material is intimately mixed with or dispersed within a second material that may be substantially conductive to electrons or electron holes or lithium ions. The composite material may be prepared by a process known as “partial reduction” or “internal reduction,” in which a precursor to the first material is preferentially reduced, or the process known as “partial oxidation,” in which a precursor to the second material is preferentially oxidized.

    摘要翻译： 本发明提供一种用作电化学装置中的电极的复合材料。 电活性复合材料包括第一电活性金属，所述电活性材料包括富含金属或金属合金的相，能够与选自碱金属和氢的物质嵌入或合金化的MeI，以及具有 第一活性物质在其中密切混合。 第二种材料包括金属氧化物MeyIIOz，其中金属MeI具有比包含MeIIO的金属更少的负Gibbs自由能来合金化或与氧形成化合物。 本发明的材料包括第一种材料，它是元素金属，金属合金，金属氧化物或其它金属化合物，其选择为能够与锂合金，并且以分散的一，二或三维制备， 三维形式。 第一种材料与可能对电子或电子空穴或锂离子基本上导电的第二种材料紧密混合或分散。 复合材料可以通过称为“部分还原”或“内部还原”的方法制备，其中第一种材料的前体优先被还原，或称为“部分氧化”的方法，其中第二种 材料被优先氧化。