Combined primer/basecoat island coating system
    1.
    发明授权
    Combined primer/basecoat island coating system 失效
    底漆/底漆岛涂层系统

    公开(公告)号:US5468518A

    公开(公告)日:1995-11-21

    申请号:US248957

    申请日:1994-05-25

    CPC分类号: C23C28/00 B05D5/068

    摘要: A process for manufacturing a metallized part comprises the following steps. A part is provided made from a substrate material selected from the group consisting of thermoplastic urethane (TPU), TPU alloys, polyester alloys, nylon, thermoplastic olefins (TPO) and aluminum. A single protective layer (combined primer/basecoat) is spray deposited, flashed and cured over the substrate. Over the combined primer/basecoat layer, a layer of corrosion prone metal is vacuum deposited to form a discontinuous film covering the combined primer/basecoat layer. A layer of clear resinous protective dielectric topcoat is spray deposited and cured to completely cover the layer of vacuum deposited corrosion prone metal material and fill channels formed in the discontinuous film layer.

    摘要翻译: 一种制造金属化部件的方法包括以下步骤。 由从热塑性聚氨酯(TPU),TPU合金,聚酯合金,尼龙,热塑性烯烃(TPO)和铝组成的组中选择的基材提供部件。 将单一保护层(组合底漆/底涂层)喷涂沉积,闪蒸并固化在基材上。 在组合的底漆/底涂层上,真空沉积一层易腐蚀的金属以形成覆盖组合的底漆/底涂层的不连续膜。 将一层透明的树脂保护电介质面漆喷涂并固化,以完全覆盖形成在不连续膜层中的真空沉积易腐蚀金属材料层和填充通道的层。

    System for making bright aluminum parts
    2.
    发明授权
    System for making bright aluminum parts 失效
    制造亮铝件的系统

    公开(公告)号:US5384161A

    公开(公告)日:1995-01-24

    申请号:US176788

    申请日:1994-01-03

    摘要: An aluminum object is manufactured by a process including chromate conversion coating of the aluminum object; sequentially applying a primer coat to the outer surface and thereafter applying a dielectric substrate basecoat; vacuum metallizing a corrosion prone metal, namely indium, on the dielectric substrate basecoat to form "islands" of the indium that are top coated with a clear resinous layer to encapsulate and insulate the islands, one from another. The indium islands are less than one thousand angstroms thick and have an average diameter of less than three thousand angstroms. The island structure is etched following the growth of the metal as it is deposited between the nucleation stage and the stage of channelization of formation of an electrically conductive film. The etchant is selected to clear channels between island structures to improve adhesion of a dielectric resinous top coat to the dielectric substrate by order of magnitude to adhesion to the islands.

    摘要翻译: 通过包括铝物质的铬酸盐转化涂层的方法制造铝物体; 依次将底漆涂布到外表面,然后施加电介质基底底漆; 真空金属化电介质基底基底上的易腐蚀金属,即铟,以形成铟的“岛”,其顶部涂覆有透明树脂层,以彼此之间封装并绝缘岛。 铟岛的厚度小于一千埃,平均直径小于三千埃。 随着金属沉积在成核阶段和形成导电膜的通道化阶段之后,金属的生长被蚀刻。 选择蚀刻剂以清除岛结构之间的通道,以改善电介质树脂表面涂层与电介质基片的粘附力,以达到与岛的粘附的数量级。

    Vacuum metallizing a dielectric substrate with indium and products
thereof
    4.
    发明授权
    Vacuum metallizing a dielectric substrate with indium and products thereof 失效
    用铟真空金属化电介质基板及其制品

    公开(公告)号:US4431711A

    公开(公告)日:1984-02-14

    申请号:US309784

    申请日:1981-10-08

    摘要: A surprisingly corrosion and abuse resistant plastic object vacuum-metallized with a corrosion prone metal, namely indium, on a dielectric substrate consists of minute specular electrically-discrete "islands" of the indium topcoated with a clear resinous layer which encapsulates and insulates the islands, one from another. The indium islands are less than one thousand angstroms thick and have an average diameter of less than three thousand angstroms. This island structure is secured by stopping the growth of the metal as it is deposited between the nucleation stage and the stage of channelization or formation of an electrically conductive film. The island structure permits the dielectric resinous topcoat to penetrate in, about and under the metal islands encapsulating and securely bonding them to the substrate.The vacuum deposited indium gives a bright sheeny appearance which, when properly topcoated, very closely duplicates the appearance of electrodeposited chrome. A preferred application of this invention is the manufacture of exterior automobile trim components the base structure of which is a flexible elastomer such as a thermoplastic urethane.

    摘要翻译: 在电介质基底上用易腐蚀金属(即铟)真空金属化的令人惊讶的耐腐蚀和耐腐蚀的塑料物体由铟的顶部涂覆的明亮的电离离子“岛”组成,其具有封装并绝缘岛的透明树脂层, 一个从另一个。 铟岛的厚度小于一千埃,平均直径小于三千埃。 通过在沉积在成核阶段和通道化阶段或形成导电膜之间停止金属的生长来确保该岛结构。 岛状结构允许电介质树脂面涂层渗透到金属岛的大约和下方,并将其牢固地粘合到基底上。 真空沉积的铟具有明亮的光泽外观,当正确地涂覆时,非常接近电沉积铬的外观。 本发明的优选应用是制造其基础结构为诸如热塑性聚氨酯的柔性弹性体的外部汽车装饰部件。

    Method for producing high gloss bright colored plastic articles
    6.
    发明授权
    Method for producing high gloss bright colored plastic articles 失效
    高光泽色彩塑料制品的制造方法

    公开(公告)号:US5320869A

    公开(公告)日:1994-06-14

    申请号:US986439

    申请日:1992-12-04

    摘要: A high gloss color finish for a plastic article is formed by coating and curing a colored primer layer (12) onto a plastic substrate (10). A light transmissive basecoat (14) is applied and cured onto the primer layer (12) to form a substrate (10) with a colored surface. Indium islands (20) are vacuum deposited onto the basecoat (12) to a thickness up to 100 Angstroms to form a visually macroscopically continuous layer (21). The island layer (21) is etched to remove smaller sized islands. A transparent topcoat (24) is applied onto the basecoat and indium islands and cured in place.

    摘要翻译: 通过将着色底漆层(12)涂覆并固化到塑料基材(10)上来形成用于塑料制品的高光泽颜色。 将透光底漆(14)施加并固化到底漆层(12)上以形成具有着色表面的基材(10)。 将铟岛(20)真空沉积到底涂层(12)上至达100埃的厚度以形成视觉宏观连续层(21)。 蚀刻岛层(21)以除去较小尺寸的岛。 将透明面漆(24)施加到底漆和铟岛上并固化就位。

    System for making bright aluminum parts
    7.
    发明授权
    System for making bright aluminum parts 失效
    制造亮铝件的系统

    公开(公告)号:US5290625A

    公开(公告)日:1994-03-01

    申请号:US886496

    申请日:1992-05-22

    IPC分类号: B05D5/06 C23C14/20 B32B7/10

    摘要: An aluminum object is manufactured by a process including chromate conversion coating of the aluminum object; sequentially applying a primer coat to the outer surface and thereafter applying a dielectric substrate basecoat; vacuum metallizing a corrosion prone metal, namely indium, on the dielectric substrate basecoat to form "islands" of the indium that are top coated with a clear resinous layer to encapsulate and insulate the islands, one from another. The indium islands are less than one thousand angstroms thick and have an average diameter of less than three thousand angstroms. The island structure is etched following the growth of the metal as it is deposited between the nucleation stage and the stage of channelization of formation of an electrically conductive film. The etchant is selected to clear channels between island structures to improve adhesion of a dielectric resinous top coat to the dielectric substrate by order of magnitude to adhesion to the islands.

    摘要翻译: 通过包括铝物质的铬酸盐转化涂层的方法制造铝物体; 依次将底漆涂布到外表面,然后施加电介质基底底漆; 真空金属化电介质基底基底上的易腐蚀金属,即铟,以形成铟的“岛”,其顶部涂覆有透明树脂层,以彼此之间封装并绝缘岛。 铟岛的厚度小于一千埃,平均直径小于三千埃。 随着金属沉积在成核阶段和形成导电膜的通道化阶段之后,金属的生长被蚀刻。 选择蚀刻剂以清除岛结构之间的通道,以改善电介质树脂表面涂层与电介质基片的粘附力,以达到与岛的粘附的数量级。

    Thermal evaporation in two planes
    8.
    发明授权
    Thermal evaporation in two planes 失效
    两个平面的热蒸发

    公开(公告)号:US5198272A

    公开(公告)日:1993-03-30

    申请号:US856713

    申请日:1992-03-24

    CPC分类号: C23C14/505 C23C14/24

    摘要: Vacuum metallizing substrates having both vertical and horizontal surfaces occurs by directing metal from two remote sources by thermal evaporation. One source is connected horizontally below the object to depose metal vertically toward the object to the horizontal surface thereof. The second source is connected vertically to the object to depose metal horizontally toward the object to the vertical surface thereof. A vacuum chamber contains a rotating carousel supporting the objects with the sources located fixedly within the chamber to perform the thermal evaporation.

    Etching of vacuum metallized indium
    9.
    发明授权
    Etching of vacuum metallized indium 失效
    真空金属铟蚀刻

    公开(公告)号:US4713143A

    公开(公告)日:1987-12-15

    申请号:US039064

    申请日:1987-04-16

    CPC分类号: B05D5/067 C23C14/20

    摘要: A plastic object is manufactured by a process including vacuum metallizing with a corrosion prone metal, namely indium, a dielectric substrate to form "islands" of the indium top coated with a clear resinous layer which encapsulates and insulates the islands, one from another. The indium islands are less than one thousand angstroms thick and have an average diameter of less than three thousand angstroms. The island structure is etched following the growth of the metal as it is deposited between the nucleation stage and the stage of channelization of formation of an electrically conductive film. The etchant is selected to clear channels between island structures to improve adhesion of a dielectric resinous top coat to the dielectric substrate by order of magnitude to adhesion to the islands.A preferred application of this invention is the manufacture of exterior automobile trim components the base structure of which is a flexible elastomer such as a thermoplastic urethane.

    Vacuum metallized dielectric substrates and method of making same
    10.
    发明授权
    Vacuum metallized dielectric substrates and method of making same 失效
    真空金属化电介质基板及其制造方法

    公开(公告)号:US4407871A

    公开(公告)日:1983-10-04

    申请号:US309783

    申请日:1981-10-08

    摘要: A surprisingly corrosion and abuse resistant plastic object vacuum-metallized with a corrosion prone metal, on a dielectric substrate consists of minute specular electrically-discrete "islands" of the metal topcoated with a clear resinous layer which encapsulates and insulates the islands, one from another. The metal islands are less than one thousand angstroms thick and have an average diameter of less than three thousand angstroms. This island structure is secured by stopping the growth of the metal as it is deposited between the nucleation stage and the stage of channelization or formation of an electrically conductive film. The island structure permits the dielectric resinous topcoat to penetrate in, about and under the metal islands encapsulating and securely bonding them to the substrate.A preferred application of this invention is the manufacture of exterior automobile trim components the base structure of which is a flexible elastomer such as a thermoplastic urethane and which have the appearance of electrodeposited chrome parts.

    摘要翻译: 在电介质基底上,用易腐蚀金属真空金属化的令人惊奇的耐腐蚀和抗滥用塑料物体由金属顶层的微小的镜面电离散“岛”构成,其具有透明树脂层,其将岛密封并绝缘 。 金属岛小于一千埃厚,平均直径小于三千埃。 通过在沉积在成核阶段和通道化阶段或形成导电膜之间停止金属的生长来确保该岛结构。 岛状结构允许电介质树脂面涂层渗透到金属岛的大约和下方,并将其牢固地粘合到基底上。 本发明的优选应用是制造其基础结构是柔性弹性体如热塑性聚氨酯并且具有电沉积铬部件的外观的汽车外饰部件。