公开(公告)号：US06863925B1

公开(公告)日：2005-03-08

申请号：US09670189

申请日：2000-09-26

申请人： Gary Eugene Wheat ,  Terri Kay Brown ,  Roger Dale Wustman ,  Joseph David Rigney

发明人： Gary Eugene Wheat ,  Terri Kay Brown ,  Roger Dale Wustman ,  Joseph David Rigney

IPC分类号： C23C10/02 ,  C23C10/06 ,  C23C16/08 ,  C23C28/00

CPC分类号： C23C10/02 ,  C23C10/14 ,  C23C16/08 ,  C23C28/021 ,  C23C28/028 ,  C23C28/321 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y02T50/67

摘要： An article is coasted by preparing a coating source having an aluminum halide, a fluoride or an iodide of a modifying element as a source of the modifying element, and a carrier gas. The modifying element is zirconium, hafnium, and yttrium, or combinations thereof. The coating source is contacted to the article, and the coating source and the article are heated to a coating temperature of at least about 1850° F. for a period of time sufficient to permit aluminum and the modifying element to coat onto the surface of the article. The preferred fluorides of modifying elements are zirconium tetrafluoride and hafnium tetrafluoride.

摘要翻译： 通过制备具有改性元素的卤化铝，氟化物或碘化物作为改性元素的来源的涂料源和载气来制备物品。 改性元素是锆，铪和钇，或其组合。 将涂料源与制品接触，并将涂料源和制品加热至至少约1850°F的涂布温度一段足以允许铝和改性元素涂覆在表面上的时间 文章。 改性元素的优选氟化物是四氟化锆和四氟化铪。

公开(公告)号：US08545185B2

公开(公告)日：2013-10-01

申请号：US11959595

申请日：2007-12-19

申请人： David John Wortman ,  Roger Dale Wustman ,  Nicole Marie Polley ,  Kathleen Diana Brammer ,  Brian Thomas Hazel

发明人： David John Wortman ,  Roger Dale Wustman ,  Nicole Marie Polley ,  Kathleen Diana Brammer ,  Brian Thomas Hazel

IPC分类号： F01D5/18

CPC分类号： F01D5/187 ,  F01D5/288 ,  F05D2230/30 ,  F05D2230/31 ,  F05D2230/80 ,  F05D2230/90 ,  Y02T50/67 ,  Y02T50/671 ,  Y02T50/676

摘要： Turbine airfoil components with protective layers and methods therefore. The components are each formed to have a platform, an airfoil extending upwardly from the platform, and a shank extending downwardly from the platform. The shank has an exterior wall and an internal passage, and the airfoil has a cooling flow channel inside the airfoil for flowing a cooling flow therethrough. The component has an interior chromide coating contacting at least a portion of an interior surface of the shank and interdiffused with a base metal thereof, and an exterior chromide coating contacting at least a portion of an exterior surface of the shank and interdiffused with the base metal thereof. The interior and exterior chromide coatings do not have an aluminide coating deposited thereon.

摘要翻译： 涡轮机翼部件具有保护层和方法。 这些部件各自形成为具有平台，从平台向上延伸的翼型件和从平台向下延伸的柄部。 柄具有外壁和内部通道，并且翼型件具有用于使冷却流通过其中的翼型件内的冷却流动通道。 该组件具有内部铬化物涂层，其接触柄的内表面的至少一部分并且与其基体金属相互扩散，并且外部铬化物涂层与柄的外表面的至少一部分接触并与基底金属相互扩散 其中。 内部和外部铬酸盐涂层不具有沉积在其上的铝化物涂层。

公开(公告)号：US07910173B2

公开(公告)日：2011-03-22

申请号：US12183665

申请日：2008-07-31

申请人： Irene Spitsberg ,  Brett Allen Rohrer Boutwell ,  Robert William Bruce ,  Curtis Alan Johnson ,  Bangalore Aswatha Nagaraj ,  William Scott Walston ,  Rudolfo Viguie ,  Joshua Leigh Miller ,  Roger Dale Wustman

发明人： Irene Spitsberg ,  Brett Allen Rohrer Boutwell ,  Robert William Bruce ,  Curtis Alan Johnson ,  Bangalore Aswatha Nagaraj ,  William Scott Walston ,  Rudolfo Viguie ,  Joshua Leigh Miller ,  Roger Dale Wustman

IPC分类号： B05D5/00 ,  B05D1/36 ,  C23C26/00 ,  B32B9/00

CPC分类号： C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/249953 ,  Y10T428/249955

摘要： A thermal barrier coating and deposition process for a component intended for use in a hostile thermal environment, such as the turbine, combustor and augmentor components of a gas turbine engine. The TBC has a first coating portion on at least a first surface portion of the component. The first coating portion is formed of a ceramic material to have at least an inner region, at least an outer region overlying the inner region, and a columnar microstructure whereby the inner and outer regions comprise columns of the ceramic material. The columns of the inner region are more closely spaced than the columns of the outer region so that the inner region of the first coating portion is denser than the outer region of the first coating portion, wherein the higher density of the inner region promotes the impact resistance of the first coating portion.

摘要翻译： 用于在敌对热环境中使用的部件的热障涂层和沉积工艺，例如燃气轮机的涡轮机，燃烧器和增压器部件。 所述TBC在所述部件的至少第一表面部分上具有第一涂覆部分。 第一涂覆部分由陶瓷材料形成，至少具有内部区域，至少覆盖内部区域的外部区域和柱状微结构，由此内部和外部区域包括陶瓷材料的列。 内部区域的列与外部区域的列紧密地间隔开，使得第一涂覆部分的内部区域比第一涂覆部分的外部区域更致密，其中内部区域的较高密度促进了冲击 第一涂布部分的电阻。

公开(公告)号：US20090162692A1

公开(公告)日：2009-06-25

申请号：US11963993

申请日：2007-12-24

申请人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Nicole Marie Polley ,  William Bryan Connor ,  Roger Dale Wustman

发明人： Bangalore Aswatha Nagaraj ,  David John Wortman ,  Nicole Marie Polley ,  William Bryan Connor ,  Roger Dale Wustman

IPC分类号： B32B15/01

CPC分类号： B32B15/01 ,  C22C19/05 ,  C22C19/057 ,  C23C4/073 ,  C23C4/134 ,  C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/3455 ,  F05B2230/312 ,  F05B2230/90 ,  Y02T50/67 ,  Y02T50/6765 ,  Y10T428/12944

摘要： Coated superalloy article includes a bond coat comprising an inner bond coat layer disposed on the first surface being formed by deposition of a bond coat composition comprising, in weight percent, 14-20% Cr, 5-8% Al, 8-12% Co, 3-7% Ta, 0.1-0.6% Hf, 0.1-0.5% Y, up to about 1% Si, 0.005-0.020% Zr, 0.04-0.08% C, 0.01-0.02% B, with a remainder including nickel (Ni) and incidental impurities, wherein the bond coating composition is substantially free of rhenium. An aluminum-containing layer overlies the inner bond coat layer. Optionally, a thermal barrier coating overlies the aluminum-containing layer, wherein the thermal barrier coating, if present, is formed by deposition of a thermal barrier coating composition.

摘要翻译： 涂覆的超合金制品包括粘合涂层，其包含通过沉积粘结涂层组合物形成的第一表面上的内粘合涂层，所述粘合涂层组合物包含重量百分比为14-20％的Cr，5-8％的Al，8-12％的Co ，3-7％Ta，0.1-0.6％Hf，0.1-0.5％Y，至多约1％Si，0.005-0.020％Zr，0.04-0.08％C，0.01-0.02％B，余量包括镍（ Ni）和杂质，其中粘合涂料组合物基本上不含铼。 含铝层覆盖在内粘合涂层上。 任选地，热障涂层覆盖在含铝层上，其中通过沉积热障涂层组合物形成热障涂层（如果存在）。

公开(公告)号：US07093335B2

公开(公告)日：2006-08-22

申请号：US10189087

申请日：2002-07-03

申请人： Jeffrey Allen Conner ,  Roger Dale Wustman ,  Jonathan Philip Clarke

发明人： Jeffrey Allen Conner ,  Roger Dale Wustman ,  Jonathan Philip Clarke

IPC分类号： B23P6/00

CPC分类号： C23C28/021 ,  C23C4/02 ,  C23C10/02 ,  C23C10/58 ,  C23C28/028 ,  Y10T29/49718 ,  Y10T29/49734 ,  Y10T29/49746 ,  Y10T29/49885 ,  Y10T29/49982 ,  Y10T428/12611 ,  Y10T428/12875 ,  Y10T428/12931 ,  Y10T428/12944

摘要： A method is provided for repairing a surface portion of an article including a metallic environmental resistant coating on a substrate. The coating includes a coating outer portion bonded with the substrate through a diffusion zone that includes at least one feature, for example Al and/or an intermetallic phase, in an amount detrimental to application of a metallic replacement coating and/or repair of the article. The method comprises removing the coating outer portion to expose a surface of the diffusion zone. The substrate and the diffusion zone are heated at a temperature and for a time sufficient to diffuse and/or dissolve at least a portion of the at least one feature in the exposed surface and in a portion of the diffusion zone beneath the exposed surface to a level below the detrimental amount. This provides a replacement surface portion integral with diffusion zone. Then a metallic replacement coating outer portion is applied to the replacement surface portion. Provided is a coated article comprising a substrate and a metallic environmental resistant coating bonded with the substrate. The coating comprises an inner modified portion of the substrate integral with the substrate, an outer diffusion zone integral with the inner portion, and a metallic environmental resistant coating outer portion integral with the outer diffusion zone. In some forms, the coated article includes a thermal barrier coating over the metallic coating outer portion.

公开(公告)号：US06932570B2

公开(公告)日：2005-08-23

申请号：US10155452

申请日：2002-05-23

申请人： John Peter Heyward ,  Carl Anthony Flecker, III ,  Timothy Lane Norris ,  Todd Stephen Heffron ,  Roger Dale Wustman

发明人： John Peter Heyward ,  Carl Anthony Flecker, III ,  Timothy Lane Norris ,  Todd Stephen Heffron ,  Roger Dale Wustman

IPC分类号： F01D5/08 ,  F01D5/14 ,  F01D5/18 ,  F01D5/28

CPC分类号： F01D5/081 ,  F01D5/087 ,  F01D5/147 ,  F01D5/187 ,  F05D2240/81

摘要： A method enables a gas turbine engine blade to be manufactured to include an airfoil, a platform, a shank, and a dovetail. The platform extends between the airfoil and the shank, the shank extends between the dovetail and the platform, and the dovetail includes at least one tang for securing the blade within the engine. The method comprises defining a cooling cavity in the blade that extends through the airfoil, the platform, the shank, and the dovetail, such that a portion of the cavity defined within the dovetail includes a root passage portion having a first width, and a transition portion extending between the root passage and the portion of the cavity defined within the shank, and wherein the portion of the cavity defined within the shank has a second width that is larger than the root passage first width. The blade is then coated with an environmental resistive coating.

摘要翻译： 一种方法能够使燃气涡轮发动机叶片制造成包括翼型件，平台，柄和燕尾榫。 平台在翼型件和柄之间延伸，柄部在燕尾榫和平台之间延伸，并且燕尾榫包括用于将叶片固定在发动机内的至少一个柄脚。 该方法包括限定叶片中的冷却空腔，其延伸穿过翼型件，平台，柄部和燕尾榫，使得限定在燕尾榫内部的空腔的一部分包括具有第一宽度的根部通道部分和过渡部分 所述部分在所述根部通道和限定在所述柄部内的所述腔的部分之间延伸，并且其中限定在所述柄内的所述腔的所述部分具有大于所述根部通道第一宽度的第二宽度。 然后用环保电阻涂层涂覆刀片。

公开(公告)号：US06605364B1

公开(公告)日：2003-08-12

申请号：US09618576

申请日：2000-07-18

申请人： Jeffrey Allen Conner ,  Roger Dale Wustman ,  Jonathan Philip Clarke

发明人： Jeffrey Allen Conner ,  Roger Dale Wustman ,  Jonathan Philip Clarke

IPC分类号： B32B1504

CPC分类号： C23C28/021 ,  C23C4/02 ,  C23C10/02 ,  C23C10/58 ,  C23C28/028 ,  Y10T29/49718 ,  Y10T29/49734 ,  Y10T29/49746 ,  Y10T29/49885 ,  Y10T29/49982 ,  Y10T428/12611 ,  Y10T428/12875 ,  Y10T428/12931 ,  Y10T428/12944

摘要： A method is provided for repairing a surface portion of an article including a metallic environmental resistant coating on a substrate. The coating includes a coating outer portion bonded with the substrate through a diffusion zone that includes at least one feature, for example Al and/or an intermetallic phase, in an amount detrimental to application of a metallic replacement coating and/or repair of the article. The method comprises removing the coating outer portion to expose a surface of the diffusion zone. The substrate and the diffusion zone are heated at a temperature and for a time sufficient to diffuse and/or dissolve at least a portion of the at least one feature in the exposed surface and in a portion of the diffusion zone beneath the exposed surface to a level below the detrimental amount. This provides a replacement surface portion integral with diffusion zone. Then a metallic replacement coating outer portion is applied to the replacement surface portion. Provided is a coated article comprising a substrate and a metallic environmental resistant coating bonded with the substrate. The coating comprises an inner modified portion of the substrate integral with the substrate, an outer diffusion zone integral with the inner portion, and a metallic environmental resistant coating outer portion integral with the outer diffusion zone. In some forms, the coated article includes a thermal barrier coating over the metallic coating outer portion.

摘要翻译： 提供一种用于修复在基材上包含金属耐环境涂层的制品的表面部分的方法。 涂层包括通过扩散区与基底结合的涂层外部部分，该扩散区包括至少一个特征，例如Al和/或金属间相，其量不利于施加金属替代涂层和/或修复物品 。 该方法包括去除涂层外部部分以暴露扩散区域的表面。 衬底和扩散区在足以在暴露表面和暴露表面下方的扩散区的一部分中的至少一部分的至少一部分扩散和/或溶解的温度下加热至 低于有害量。 这提供了与扩散区一体的替换表面部分。 然后将金属替换涂层外部施加到更换表面部分。 本发明提供一种包含基材和与该基材结合的耐金属金属涂层的涂布制品。 所述涂层包括与所述基底一体的所述基底的内部改性部分，与所述内部一体的外部扩散区，以及与所述外部扩散区一体的金属防环境涂层外部。 在一些形式中，涂覆制品在金属涂层外部部分上包括热障涂层。

公开(公告)号：US06379749B2

公开(公告)日：2002-04-30

申请号：US09730373

申请日：2000-12-05

申请人： Robert George Zimmerman, Jr. ,  William Clarke Brooks ,  Roger Dale Wustman ,  John Douglas Evans, Sr.

发明人： Robert George Zimmerman, Jr. ,  William Clarke Brooks ,  Roger Dale Wustman ,  John Douglas Evans, Sr.

IPC分类号： B05D310

CPC分类号： C23G1/10 ,  B23P2700/06 ,  C23C4/02

摘要： A method of removing a ceramic coating (18), and particularly zirconia-containing thermal barrier coating (TBC) materials such as yttria-stabilized zirconia (YSZ), that has been either intentionally or unintentionally deposited on the surface of a component (10). The method entails subjecting the ceramic coating (18) to an aqueous solution containing an acid fluoride salt, such as ammonium bifluoride (NH4HF2) or sodium bifluoride (NaHF2), and a corrosion inhibitor. The method is capable of completely removing the ceramic coating (18) without removing or damaging the underlying substrate material, which may include a metallic bond coat (16).

摘要翻译： 已经有意或无意沉积在组件（10）的表面上的去除陶瓷涂层（18），特别是含氧化锆的热障涂层（TBC）材料如氧化钇稳定的氧化锆（YSZ）的方法， 。 该方法需要使陶瓷涂层（18）经受含氟化氢盐如氟化氢铵（NH 4 HF 2）或氟化氢钠（NaHF 2）的水溶液和腐蚀抑制剂。 该方法能够完全去除陶瓷涂层（18），而不会移除或损坏可能包括金属粘结涂层（16）的下面的基底材料。

公开(公告)号：US20090162209A1

公开(公告)日：2009-06-25

申请号：US11959595

申请日：2007-12-19

申请人： DAVID JOHN WORTMAN ,  Roger Dale Wustman ,  Nicole Marie Polley ,  Kathleen Diana Brammer ,  Brian Thomas Hazel

发明人： DAVID JOHN WORTMAN ,  Roger Dale Wustman ,  Nicole Marie Polley ,  Kathleen Diana Brammer ,  Brian Thomas Hazel

IPC分类号： F01D5/18 ,  F04D29/58

CPC分类号： F01D5/187 ,  F01D5/288 ,  F05D2230/30 ,  F05D2230/31 ,  F05D2230/80 ,  F05D2230/90 ,  Y02T50/67 ,  Y02T50/671 ,  Y02T50/676

摘要： A gas turbine blade comprises a base metal, a platform, an airfoil extending upwardly from the platform, a shank extending downwardly from the platform. The shank has an exterior wall and an internal passage, and the airfoil has a cooling flow channel inside the airfoil for flowing a cooling flow therethrough. The blade has a first chromide coating contacting the base metal of at least a portion of an interior surface of the shank and interdiffused therewith, wherein the first chromide coating does not have an aluminide coating deposited over it. The blade has a second chromide coating contacting the base metal of at least a portion of an interior surface of the airfoil and interdiffused therewith. A method for preparing a gas turbine blade comprises the steps of applying chromide coatings, sealing the interior passages of the shank and airfoil and applying an aluminide or platinum aluminide coating and an optional ceramic layer on the airfoil.

摘要翻译： 燃气轮机叶片包括贱金属，平台，从平台向上延伸的翼型件，从平台向下延伸的柄部。 柄具有外壁和内部通道，并且翼型件具有用于使冷却流通过其中的翼型件内的冷却流动通道。 刀片具有与柄的内表面的至少一部分的贱金属接触并与之相互扩散的第一铬化物涂层，其中第一铬化物涂层不具有沉积在其上的铝化物涂层。 叶片具有与翼型件的内表面的至少一部分的基底金属接触并与其相互扩散的第二铬化物涂层。 制备燃气轮机叶片的方法包括以下步骤：施加铬酸盐涂层，密封柄和翼型件的内部通道，并在翼型件上施加铝化物或铂铝化物涂层和可选的陶瓷层。

公开(公告)号：US07026011B2

公开(公告)日：2006-04-11

申请号：US10357972

申请日：2003-02-04

申请人： Roger Dale Wustman ,  William Scott Walston ,  Matthew David Saylor ,  Brian Harvey Pilsner ,  Jeffrey Allan Pfaendtner

发明人： Roger Dale Wustman ,  William Scott Walston ,  Matthew David Saylor ,  Brian Harvey Pilsner ,  Jeffrey Allan Pfaendtner

IPC分类号： C23C16/08

CPC分类号： C23C10/08 ,  F01D5/288 ,  F05D2230/313 ,  Y02T50/67 ,  Y02T50/671

摘要： A method for applying an aluminide coating on a gas turbine engine blade having an external surface and an internal cooling cavity having an internal surface that is connected to the external surface by cooling holes. The method is conducted in a vapor coating container having a hollow interior coating chamber, and includes the steps of loading the coating chamber with the blade to be coated; providing an aluminide coating gas in the loaded coating chamber; maintaining the loaded coating chamber comprising the aluminide coating gas at a specified temperature and time to deposit an aluminide coating on the external surface of the blade; and then flowing an inert carrier gas into the loaded coating chamber comprising the aluminide coating gas at a specified gas flow rate and time to move the aluminide coating gas through the cooling holes and internal cooling cavity and deposit an aluminide coating on the internal surface of the blade.

摘要翻译： 一种在具有外表面的燃气涡轮发动机叶片上施加铝化物涂层的方法和具有通过冷却孔连接到外表面的内表面的内部冷却腔。 该方法在具有中空的内部涂覆室的蒸气涂覆容器中进行，并且包括以下步骤：将涂覆室与待涂覆的刀片装载; 在装载的涂覆室中提供铝化物涂覆气体; 将包含铝化物涂层气体的装载涂层室保持在规定温度和时间，以将铝化物涂层沉积在叶片的外表面上; 然后使惰性载体气体以特定的气体流速和时间流入包含铝化物涂层气体的装载的涂覆室中，以移动铝化物涂层气体通过冷却孔和内部冷却腔，并将铝化物涂层沉积在 刀。