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公开(公告)号：US08013072B2
公开(公告)日：2011-09-06
申请号：US12465080
申请日：2009-05-13
申请人： Royce E. Ennis
发明人： Royce E. Ennis
CPC分类号： C08L23/34 , C08F8/26 , C08F8/38 , C08F2800/20 , C08F2810/20 , C08F2810/30 , C08L2205/02 , C08L2205/025 , C08F110/02 , C08F210/16 , C08L2666/06 , C08F210/06 , C08F210/02
摘要： At least partially hydrolyzed chlorosulfonated polyolefin elastomers containing 0.5-10 weight percent chlorine and 0.25 to 5 weight percent sulfur are prepared from low density polyethylene or from linear ethylene/alpha-olefin copolymer base resins having a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) less than 3.5.
摘要翻译： 含有0.5-10重量％氯和0.25-5重量％硫的至少部分水解的氯磺化聚烯烃弹性体由低密度聚乙烯或线性乙烯/α-烯烃共聚物基础树脂制备，所述线性乙烯/α-烯烃共聚物基础树脂的重均分子量（Mw）与 数均分子量（Mn）小于3.5。
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公开(公告)号：US5102946A
公开(公告)日：1992-04-07
申请号：US722450
申请日：1991-06-27
申请人： John C. Chen , Royce E. Ennis
发明人： John C. Chen , Royce E. Ennis
IPC分类号： C08L23/28 , C08L23/00 , C08L23/26 , C08L23/34 , C08L27/06 , C08L57/08 , C08L101/00 , C08L101/04 , C09D5/16 , C09J123/28 , C09J123/34 , C09J157/08
CPC分类号： C09J123/34 , C08L57/08 , C09D5/1668 , C09J123/28 , C09J157/08
摘要： A stabilized chlorinated resin latex comprising a mixture in water of A) 50-95 wt. %, based on the weight of A and B, of a chlorinated resin, substantially free of acid moieties, having a chlorine content of 15-70 wt. %, and B) 5-50 wt. %, based on the weight of A and B, of a salt of a water-insoluble C.sub.2 -C.sub.12 alpha, beta- unsaturated olefin copolymer which contains at least 2 mole % acid moieties and is compatible with the chlorinated resin.
摘要翻译： 一种稳定的氯化树脂胶乳，其包含在水中的混合物，A）50-95wt。 ％，基于A和B的重量，氯基树脂基本上不含酸部分，氯含量为15-70重量％。 ％，和B）5-50wt。 ％，基于A和B的重量，含有至少2摩尔％酸部分并与氯化树脂相容的水不溶性C2-C12α，β-不饱和烯烃共聚物的盐。
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公开(公告)号：US4824906A
公开(公告)日：1989-04-25
申请号：US166487
申请日：1988-03-10
申请人： Wolfgang Honsberg , Royce E. Ennis
发明人： Wolfgang Honsberg , Royce E. Ennis
CPC分类号： C08L23/286
摘要： A blend of 80-99 weight percent chlorinated polyethylene containing 15-60 weight percent chlorine with 20-1 weight percent of polyethylene containing up to 5 weight percent chlorine and 0.5-5 weight percent of a grafted unsaturated dicarboxylic acid or anhydride is disclosed. The preferred chlorinated polyethylene is made by chlorinating a blend of high and low density polyethylene.
摘要翻译： 公开了80-99重量％的含有15-60重量％氯的氯化聚乙烯和20-1重量％的含有至多5重量％氯和0.5-5重量％接枝的不饱和二羧酸或酸酐的聚乙烯的混合物。 优选的氯化聚乙烯通过氯化高密度和低密度聚乙烯的共混物制成。
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公开(公告)号：US4591621A
公开(公告)日：1986-05-27
申请号：US518744
申请日：1983-07-29
申请人： Royce E. Ennis
发明人： Royce E. Ennis
摘要： An uncured chlorinated polyethylene elastomer having a molecular weight distribution of about 6-13, as determined by the ratio of Mw/Mn where Mw represents the weight average molecular weight and Mn represents the number average molecular weight, a chlorine content of about 20-28% by weight, a Mooney viscosity value, determined according to ASTM D 1646-81, ML.sub.(1+4) at 100.degree. C., of about 15-36; and, optionally, a sulfur content of about 0.2-2% by weight and a process for their preparation.
摘要翻译： 分子量分布为约6-13的未固化的氯化聚乙烯弹性体，其通过＆lt;上＆gt;＆lt; Mw /＆lt;上＆gt; Mn的比率确定，其中＆Upbar＆Mw表示重均分子量和＆lt;上＆ 约20-28重量％，根据ASTM D 1646-81测定的门尼粘度值，在100℃下ML（1 + 4）为约15-36; 和任选的硫含量为约0.2-2重量％的硫含量及其制备方法。
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公开(公告)号：US20100292405A1
公开(公告)日：2010-11-18
申请号：US12465080
申请日：2009-05-13
申请人： Royce E. Ennis
发明人： Royce E. Ennis
CPC分类号： C08L23/34 , C08F8/26 , C08F8/38 , C08F2800/20 , C08F2810/20 , C08F2810/30 , C08L2205/02 , C08L2205/025 , C08F110/02 , C08F210/16 , C08L2666/06 , C08F210/06 , C08F210/02
摘要： At least partially hydrolyzed chlorosulfonated polyolefin elastomers containing 0.5-10 weight percent chlorine and 0.25 to 5 weight percent sulfur are prepared from low density polyethylene or from linear ethylene/alpha-olefin copolymer base resins having a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) less than 3.5.
摘要翻译： 含有0.5-10重量％氯和0.25-5重量％硫的至少部分水解的氯磺化聚烯烃弹性体由低密度聚乙烯或线性乙烯/α-烯烃共聚物基础树脂制备，所述线性乙烯/α-烯烃共聚物基础树脂的重均分子量（Mw）与 数均分子量（Mn）小于3.5。
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公开(公告)号：US5234989A
公开(公告)日：1993-08-10
申请号：US863635
申请日：1992-04-06
申请人： John C. Chen , Royce E. Ennis
发明人： John C. Chen , Royce E. Ennis
IPC分类号： C08F210/02 , C08F8/20 , C08F210/00 , C08L23/28 , C09J123/28 , C09J161/12
CPC分类号： C08F8/20
摘要： Self-stabilized resin latexes are provided which contain carboxylate salts of post-chlorinated ethylene copolymers having chlorine contents of 20-60 weight percent. The ethylene copolymer salts are derived from ethylene/acrylic acid or ethylene/methacrylic acid copolymers containing 1.5-12 mole percent copolymerized units of acrylic or methacrylic acid. The latexes are particularly useful for preparing resorcinol formaldehyde adhesives.
摘要翻译： 提供了自稳定的树脂胶乳，其含有氯含量为20-60重量％的后氯化乙烯共聚物的羧酸盐。 乙烯共聚物盐衍生自含有1.5-12％（摩尔）共聚单元的丙烯酸或甲基丙烯酸的乙烯/丙烯酸或乙烯/甲基丙烯酸共聚物。 胶乳特别适用于制备间苯二酚甲醛粘合剂。
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7.发明申请PROCESS FOR THE MANUFACTURE OF AT LEAST PARTIALLY HYDROLYZED CHLOROSULFONATED POLYOLEFIN ELASTOMERS IN OIL 审中-公开油中部分水解氯化聚硅氧烷弹性体的制备方法公开(公告)号：US20100292395A1
公开(公告)日：2010-11-18
申请号：US12465139
申请日：2009-05-13
申请人： Royce E. Ennis
发明人： Royce E. Ennis
CPC分类号： C09D123/34 , C08F8/12 , C08F8/38 , C08F210/16 , C08F210/06 , C08F210/14 , C08F210/08
摘要： A process for the manufacture of an oil concentrate comprising oil and one or more at least partially hydrolyzed chlorosulfonated polyolefin elastomers containing 0.5-50 weight percent chlorine and 0.25 to 5 weight percent sulfur is disclosed.
摘要翻译： 公开了一种制备油浓缩物的方法，其包含油和一种或多种至少部分水解的含0.5-50重量％氯和0.25-5重量％硫的氯磺化聚烯烃弹性体。
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8.依法登记的发明
公开(公告)号：USH1582H
公开(公告)日：1996-08-06
申请号：US260123
申请日：1994-06-15
摘要： Non-discolored chlorinated and chlorosulfonated olefin polymers having low levels of residual solvent are prepared in a process wherein monofluorobenzene is used as a reaction medium and isolation of the polymer is by means of a series of vented closed loop extruders. The process also results in suppression of the formation of monochloromonofluorobenzene as a by-product.
摘要翻译： 在其中使用单氟苯作为反应介质并通过一系列排气闭环挤出机分离聚合物的方法中制备具有低水平残留溶剂的非变色氯化和氯磺化烯烃聚合物。 该方法还导致抑制作为副产物的一氯一氟苯的形成。
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公开(公告)号：US4749751A
公开(公告)日：1988-06-07
申请号：US75824
申请日：1987-07-20
申请人： Royce E. Ennis , Wolfgang Honsberg
发明人： Royce E. Ennis , Wolfgang Honsberg
CPC分类号： C08F8/20 , C08L23/286
摘要： A process is disclosed for producing a blend of chlorinated low density polyethylene and chlorinated high density polyethylene wherein the polyethylenes are placed in a solvent and the temperature raised to a point where the low density polyethylene goes into solution and the high density polyethylene does not go into solution. The low density polyethylene is chlorinated up to the desired level and then the temperature is raised to dissolve the high density polyethylene and chlorination of both polyethylenes is continued to the desired level.
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公开(公告)号：US20090247719A1
公开(公告)日：2009-10-01
申请号：US12401844
申请日：2009-03-11
申请人： Royce E. Ennis
发明人： Royce E. Ennis
IPC分类号： C08F210/00
CPC分类号： C08F8/38 , C08F210/16 , C08F210/18 , C08F210/12
摘要： Chlorosulfonated polyolefin elastomers containing 1-10 weight percent chlorine and 0.5 to 5 weight percent sulfur and having with a Cl:S weight ratio of 10 or less are prepared in a batch solution process employing a chlorosulfonation agent of sulfuryl chloride or the combination of Cl2 and SO2.
摘要翻译： 含有1-10重量％氯和0.5-5重量％硫并且Cl:S重量比为10或更小的氯磺化聚烯烃弹性体是以间歇溶液方法制备的，其使用磺酰氯的氯磺化剂或Cl 2和 SO2。
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