公开(公告)号：US20080051529A1

公开(公告)日：2008-02-28

申请号：US11572241

申请日：2005-07-02

申请人： Rudolf Kampf

发明人： Rudolf Kampf

IPC分类号： C08F2/01

CPC分类号： B01J19/20 ,  B01J19/18 ,  B01J2219/00006 ,  B01J2219/00777 ,  B01J2219/00779 ,  C08G63/785 ,  C08G64/205

摘要： Disclosed are a method and a device for batchwise production of high-molecular polyphosphonates, polysulfones, polyarylates, polyamides, polyarylene ethers, or polyether ketones by melt-condensing a monomer compound carrying hydroxyl groups, carboxyl groups, anhydride groups, phosphoric acid groups, phosphono groups, phosphonate groups, phosphino groups, phosphinate groups, carbonyl groups, sulfonyl groups, sulfonate groups, siloxane groups or amino groups on its own or along with at least one diphenol, dialcohol, diamine, or a dicarbonate component. According to the invention, a) esterification or reesterification and precondensation are performed in a batchwise operated first reactor (1) in the presence of an esterification catalyst or reesterification catalyst; b) polycondensation is then optionally performed in a batchwise operated intermediate reactor (6) by optionally adding one or several additional monomers, another catalyst, and additives until a predetermined polycondensation level or viscosity level has been attained; and finally (c) condensation is continued in a batchwise operated final reactor (12) until the desired polycondensation level or viscosity level has been reached; and d) branching molecules comprising more than two functional groups are optionally added prior to or during esterification or reesterification, prior to or during polycondensation optionally performed in the intermediate reactor, or prior to or during polycondensation performed in the final reactor. The dwell time in the reactors ranges between 5 minutes and 15 hours while the temperature is set to 180 to 300° C. in reactors (1) and (6) and to 240 to 400° C. in reactor (12), the pressure being continuously or gradually lowered from 2000 to 100 mbar in reactors (1) and (6) and to 100 to 0.01 mbar in reactor (12) by sucking off the vapors produced during condensation.

公开(公告)号：US20090114523A1

公开(公告)日：2009-05-07

申请号：US11918636

申请日：2006-02-27

申请人： Rudolf Kampf ,  Andreas Karpf ,  Rainer Linke ,  Oliver Schmidt ,  Gerhard Scholz

发明人： Rudolf Kampf ,  Andreas Karpf ,  Rainer Linke ,  Oliver Schmidt ,  Gerhard Scholz

IPC分类号： B01D3/10

CPC分类号： C08G63/785 ,  B01D3/148 ,  C08G63/19

摘要： The invention relates to a method for treating vapours and condensates which arise during the production of polycondensates from bisphenols or high-value phenols by esterification and/or transesterification with alkyl or aryl esters of at least bivalent organic or inorganic acids. According to the invention, the treatment is carried out in a plurality of condensates and/or distillation columns which are connected in a step-by-step manner behind each other, each distillation column comprising a connected condensate. The dew point and the pressure in each condensate are adjusted such that in each step, monomers, oligomers or decomposition and transformation products are removed.

摘要翻译： 本发明涉及一种处理蒸气和缩合物的方法，其通过至少二价有机或无机酸的烷基或芳基酯进行酯化和/或酯交换在双酚或高价酚类生产缩聚物期间产生。 根据本发明，处理在多个冷凝物和/或蒸馏塔中进行，这些冷凝物和/或蒸馏塔逐步相互连接，每个蒸馏塔包括连接的冷凝物。 调整每个冷凝物中的露点和压力，使得在每个步骤中，除去单体，低聚物或分解和转化产物。

公开(公告)号：US20080230687A1

公开(公告)日：2008-09-25

申请号：US10575142

申请日：2004-09-23

申请人： Rudolf Kampf

发明人： Rudolf Kampf

IPC分类号： H01J49/26

CPC分类号： B01J19/1862 ,  B01J19/0033 ,  B01J19/20 ,  B01J2219/00184 ,  B01J2219/00186 ,  B01J2219/002 ,  B01J2219/00218 ,  B01J2219/00234 ,  C08F2/00 ,  C08F2400/02 ,  C08G63/785 ,  G01N33/442 ,  H01J49/00

摘要： The invention relates to a method, which is used to monitor the composition of a polymer blend, melt and/or solution used to produce a polymer and to an automatic analysis device (27). To produce the polymer, the polymer blend, melt and/or solution is guided through an installation volume and a sample gas that is formed from said polymer blend, melt and/or solution is withdrawn, preferably at several sampling sites (30 to 36). The sample gas is fed to a mass spectrometer (28), which automatically emits an analysis signal representing the composition of the sample gas. The sampling site is connected to the mass spectrometer in a switchable manner via an automatically switchable shut-off device (47, 48), in such a way that several sampling sites can be sampled in succession by the mass spectrometer (28). The use of the mass spectrometer (28) permits an extremely accurate analysis of the composition of the sample gas and precise control of the process parameters of the reactor systems that are used for the polymer production. Said method and automatic analysis device can be used, in particular, during a polycondensation process.

摘要翻译： 本发明涉及一种用于监测用于生产聚合物的聚合物共混物，熔体和/或溶液的组成以及自动分析装置（27）的方法。 为了生产聚合物，将聚合物共混物，熔体和/或溶液引导通过安装体积，并且从所述聚合物共混物，熔体和/或溶液形成的样品气体优选在几个取样点（30至36℃） 。 将样品气体供给到质谱仪（28），其自动发出表示样品气体组成的分析信号。 采样点通过可自动切换的切断装置（47,48）以可切换的方式连接到质谱仪，使得可以通过质谱仪（28）连续取样几个采样点。 使用质谱仪（28）可以对样品气体的组成进行非常精确的分析，并精确控制用于聚合物生产的反应器系统的工艺参数。 所述方法和自动分析装置特别可以在缩聚过程中使用。

公开(公告)号：US07129347B2

公开(公告)日：2006-10-31

申请号：US10897472

申请日：2004-07-23

申请人： Rudolf Kampf ,  Reinhard Wolf ,  Joachim Seelig

发明人： Rudolf Kampf ,  Reinhard Wolf ,  Joachim Seelig

IPC分类号： C07D201/12

CPC分类号： C07D201/16 ,  C07D201/12

摘要： The invention relates to a method for the continuous production of caprolactam from waste containing polyamide, comprising a) depolymerisation of the waste containing polyamide, whereby a caprolactam raw material and, where applicable, a flow containing secondary constituents or additives is obtained, and b) irradiation of the caprolactam raw material with UV radiation.

摘要翻译： 本发明涉及一种从含有聚酰胺的废物中连续生产己内酰胺的方法，其包括：a）含有聚酰胺的废物的解聚，由此得到己内酰胺原料，并且在适用的情况下获得含有二级成分或添加剂的流动，以及b） 紫外线照射己内酰胺原料。

公开(公告)号：US20050056532A1

公开(公告)日：2005-03-17

申请号：US10897472

申请日：2004-07-23

申请人： Rudolf Kampf ,  Reinhard Wolf ,  Joachim Seelig

发明人： Rudolf Kampf ,  Reinhard Wolf ,  Joachim Seelig

IPC分类号： C07D201/12 ,  C07D201/16

CPC分类号： C07D201/16 ,  C07D201/12

摘要： The invention relates to a method for the continuous production of caprolactam from waste containing polyamide, comprising a) depolymerisation of the waste containing polyamide, whereby a caprolactam raw material and, where applicable, a flow containing secondary constituents or additives is obtained, and b) irradiation of the caprolactam raw material with UV radiation.

摘要翻译： 本发明涉及一种从含有聚酰胺的废物中连续生产己内酰胺的方法，其包括：a）含有聚酰胺的废物的解聚，由此得到己内酰胺原料，并且在适用的情况下获得含有二级成分或添加剂的流动，以及b） 紫外线照射己内酰胺原料。

公开(公告)号：US20090134756A1

公开(公告)日：2009-05-28

申请号：US12268516

申请日：2008-11-11

申请人： Rudolf Kampf ,  Andreas Karpf ,  Rainer Linke ,  Oliver Schmidt ,  Gerhard Scholz

发明人： Rudolf Kampf ,  Andreas Karpf ,  Rainer Linke ,  Oliver Schmidt ,  Gerhard Scholz

IPC分类号： E06B3/70

CPC分类号： C08G63/785 ,  B01D3/148 ,  C08G63/19

摘要： A safety cabinet has a plurality of walls defining a front open side and a pair of doors pivotal about respective horizontally spaced axes on the walls between a closed and an open position. Guides in the cabinet are each associated with a respective one of the doors, and respective links each have a front end connected to a respective one of the doors and a rear end shiftable front-to-back in a respective one of the guides. A connector extends between the rear ends of the links and shifts front-to-back with them. A closer is operatively engageable with the connector, and a spring applies bears on the closer to urge it against the connector for pushing same into the rear end position and closing the doors. An actuator normally holds the closer out of engagement with the connector during movement of same between the front and rear end positions.

摘要翻译： 安全柜具有限定前开口侧的多个壁和在关闭和打开位置之间围绕壁上的相应水平间隔的轴枢转的一对门。 机柜中的引导件各自与相应的一个门相关联，并且相应的连接件各自具有连接到相应的一个门的前端和相应的一个引导件中的后端可前后移动。 连接器在连杆的后端之间延伸并且与它们前后移动。 靠近器可操作地与连接器接合，并且弹簧施加在更靠近的部分上，以将其推压到连接器上，以将其推入后端位置并关闭门。 致动器通常在相对于前端位置和后端位置之间移动时保持与连接器更接近的接合状态。

公开(公告)号：US20060247412A1

公开(公告)日：2006-11-02

申请号：US10554436

申请日：2004-03-31

申请人： Rudolf Kampf

发明人： Rudolf Kampf

IPC分类号： C08G64/00 ,  C08G16/00

CPC分类号： F04F5/54 ,  B01J3/006 ,  B01J2219/00006 ,  B01J2219/00162 ,  C08G63/785 ,  C08G64/205 ,  C08G65/4093 ,  C08G75/23 ,  C08G79/04

摘要： The invention relates to a method for the production of polymers by means of melt-phase polycondensation in at least one reaction step under vacuum. The vapor produced is drawn off by at least one steam jet vacuum pump with a downstream injection condenser from the reaction step. In order to improve the method, the steam jet vacuum pump is driven with alkylene carbonate in vapor form and liquid alkylene carbonate is supplied to the injection condenser as coolant.

摘要翻译： 本发明涉及通过在至少一个反应步骤中在真空下通过熔融相缩聚制备聚合物的方法。 所产生的蒸汽由至少一个蒸汽喷射真空泵从反应步骤用下游注入冷凝器抽出。 为了改进方法，蒸汽喷射真空泵由蒸气形式的碳酸亚烃驱动，并且液体碳酸亚烃酯作为冷却剂供应到注射冷凝器。

公开(公告)号：US20050127285A1

公开(公告)日：2005-06-16

申请号：US10959732

申请日：2004-10-06

申请人： Rudolf Kampf ,  Reinhard Wolf

发明人： Rudolf Kampf ,  Reinhard Wolf

IPC分类号： B07C5/34 ,  G01N33/44 ,  H01J49/00

CPC分类号： G01N33/442 ,  B07C5/34

摘要： The invention relates to a method for the analysis of refuse objects (2) containing polymers, in particular of carpets, in a recycling plant (1) and an automatic analytical device (7). In order to determine the polymer constituents of the refuse object (2), according to the invention, part of the refuse object (2) is vaporised and examined by a mass spectrometer (18). Using the method according to the invention and the automatic analytical device according to the invention, the refuse objects (2) can be classified for further processing (9, 10, 11) more accurately and more reliably during transport on a conveyor device (6).

摘要翻译： 本发明涉及一种用于分析在回收厂（1）和自动分析装置（7）中含有聚合物，特别是地毯的垃圾（2）的方法。 为了确定垃圾物体（2）的聚合物组分，根据本发明，垃圾对象（2）的一部分被质谱仪（18）蒸发和检查。 使用根据本发明的方法和根据本发明的自动分析装置，垃圾物体（2）可以在传送装置（6）上更精确和更可靠地分类用于进一步处理（9,10,11） 。

公开(公告)号：US20080161530A1

公开(公告)日：2008-07-03

申请号：US11579941

申请日：2005-02-23

申请人： Rudolf Kampf

发明人： Rudolf Kampf

IPC分类号： C08G63/183

CPC分类号： C08G63/78 ,  C08G63/672

摘要： A process for continuous or discontinuous synthesis of elastomeric copolyesters from polybutylene terephthalate (PBT) and polyoxytetramethylene glycol is described in which the tetrahydrofuran (THF) obtained as a byproduct in synthesis of polybutylene terephthalate from 1,4-butanediol is rectified and then reacted by ring-opening polymerization to form polyoxytetramethylene glycol which condenses with the free or esterified carboxyl groups of PBT to form the copolyester, whereby chain termination and catalyst deactivation are accomplished by adding 1,4-butanediol without separating the catalyst.

摘要翻译： 描述了从聚对苯二甲酸丁二醇酯（PBT）和聚氧四亚甲基二醇连续或不连续地合成弹性体共聚酯的方法，其中将由1,4-丁二醇合成聚对苯二甲酸丁二醇酯的副产物获得的四氢呋喃（THF）精制，然后通过环 开始聚合以形成与PBT的游离或酯化羧基缩合形成共聚酯的聚氧四亚甲基二醇，由此通过加入1,4-丁二醇而不分离催化剂来实现链终止和催化剂失活。

公开(公告)号：US20050054739A1

公开(公告)日：2005-03-10

申请号：US10897473

申请日：2004-07-23

申请人： Rudolf Kampf ,  Reinhard Wolf ,  Joachim Seelig

发明人： Rudolf Kampf ,  Reinhard Wolf ,  Joachim Seelig

IPC分类号： C07D201/12 ,  C08F6/00

CPC分类号： C07D201/12

摘要： The invention relates to a method for the treatment of waste containing polyamide comprising a) depolymerisation of the waste containing polyamide, whereby a caprolactam raw material (6) and a flow (3), comprising the secondary constituents and additives from the depolymerisation, are obtained, and b) leaching of the flow (3) at least once using an extracting agent.

摘要翻译： 本发明涉及一种处理含有聚酰胺的废物的方法，包括：a）含有聚酰胺的废物的解聚，由此获得包含来自解聚的第二组分和添加剂的己内酰胺原料（6）和流动物（3） ，和b）使用提取剂至少一次浸出所述流（3）。