摘要:
The invention relates to compounds of the group of so-called sterically hindered amines (HALS) which are substituted by phospho groups. The invention also relates to flame retardant compositions wherein these compounds are added to the polymer substrate.
摘要:
The instant invention discloses a process for the preparation a polyolefin nanocomposite which comprises melt mixing a mixture of a polyolefin, a filler and a non-ionic surfactant.
摘要:
The instant invention discloses a composition, preferably a nanocomposite material, comprising (a) a synthetic polymer, (b) a filler selected from a natural or synthetic phyllosilicate or a mixture of such phyllosilicates, preferably in nanoparticles, and (c) a dispersing agent prepared by controlled free radical polymerization (CFRP).
摘要:
The invention pertains to a method of producing comb block copolymers from epoxy-functionalized nitroxylethers and further monomers by anionic polymerization followed by nitroxyl mediated controlled free radical polymerization. The block copolymer backbone has defined initiating points where radical grafting of ethylenically unsaturated monomers can take place. Further aspects of the invention are comb block copolymers obtained by this process and the use of such polymers for plastic applications.
摘要:
The instant invention relates to a process for the preparation of star and block-copolymers, which are prepared by controlled free radical polymerization using epoxy-functionalized alkoxyamines and multifunctional compounds capable of reacting with the epoxy group.
摘要:
The invention relates to hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer and methods for achieving a controlled increase in the molecular weight of polyethylene.
摘要:
The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one hydroxylamine of high molecular weight, preferably a long chain alkyl substituted hydroxylamine. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of high molecular weight hydroxylamines for controlled polymerization.
摘要:
The invention relates to a process and compositions suitable for reducing by heat the molecular weight of polypropylene, propylene copolymers or polypropylene blends. Azo compounds bearing different substituents are added to the polymers.
摘要:
The present invention relates to a method for the radical polymerization or copolymerization of ethylene at high pressures using a hydroxylamine ester as radical initiator. The hydroxylamine esters according to the invention are suitable initiators for the high pressure polymerization of ethylene leading to high molecular weight polyethylenes with narrow molecular weight distributions (Polydispersed Index PD=1.2−4.5).
摘要:
The present invention relates to a process for increasing the molecular weight and for the modification of polycondensates, to the use of an additive blend effecting the increase in molecular weight without imparting color to the polycondensates as well as to the polycondensates obtainable by that process. The additive blend contains at least one bis-acyllactam, at least one phosphite, phosphinate or phosphonate; or at least one benzofuran-2-one type compound or at least one phosphite, phosphinate or phosphonate and one benzofuran-2-one type compound.