MONOLITHIC STRUCTURED CATALYST FOR CARBON MONOXIDE GASE-PHASE COUPLING TO DIALKYL OXALATE & PREPARATION METHOD AND APPLICATION THEREOF
    3.
    发明申请
    MONOLITHIC STRUCTURED CATALYST FOR CARBON MONOXIDE GASE-PHASE COUPLING TO DIALKYL OXALATE & PREPARATION METHOD AND APPLICATION THEREOF 审中-公开
    一氧化碳气相偶联二氧化二油的相联合催化剂及其制备方法及应用

    公开(公告)号:US20130150617A1

    公开(公告)日:2013-06-13

    申请号:US13701508

    申请日:2011-05-31

    IPC分类号: B01J29/04 C07C67/36 B01J23/89

    摘要: Provided is a monolithic catalyst for synthesizing an oxalate by carbon monoxide (CO) gaseous-phase coupling, a preparation method and the use thereof. In the catalyst, a ceramic honeycomb or a metal honeycomb was used as skeletal carrier, metal oxides were used as a carrier coating, precious metals Pt, Pd, Ir, Rh were used as active ingredients, as well as Fe, Co, Ni were used as additives, wherein the carrier coating accounts for 5 to 50 wt % of the honeycomb carrier the active ingredients of the catalyst account for 0.1 to 5 wt. % of the carrier coating; the additives of the catalyst account for 0.3 to 10 wt. % of the carrier coating; and the atomic ratio of the active ingredients to the additives was 0.1 to 3. the reaction for synthesizing the oxalate was carried out in a fixed bed reactor, wherein, N2 was used as a carrier gas. The volume ratio of N2:CO: Alkyl nitrite was 20-80:5-60:10-40, and the retention time was 0.5-10 s.

    摘要翻译: 提供了一种通过一氧化碳(CO)气相偶联合成草酸盐的整体式催化剂,其制备方法及其用途。 在催化剂中,使用陶瓷蜂窝体或金属蜂窝体作为骨架载体,使用金属氧化物作为载体涂层,使用贵金属Pt,Pd,Ir,Rh作为活性成分,以及Fe,Co,Ni分别为 用作添加剂,其中载体涂料占蜂窝载体的5至50重量%,催化剂的活性成分占0.1至5重量%。 载体涂层的%; 催化剂的添加剂占0.3至10wt。 载体涂层的%; 并且活性成分与添加剂的原子比为0.1〜3。用于合成草酸盐的反应在固定床反应器中进行,其中使用N 2作为载气。 N2:CO:亚硝酸烷基酯的体积比为20-80:5-60:10-40,保留时间为0.5-10秒。