Electrically conducting fiber and method of making same
    1.
    发明授权
    Electrically conducting fiber and method of making same 失效
    导电纤维及其制造方法

    公开(公告)号:US4410593A

    公开(公告)日:1983-10-18

    申请号:US183639

    申请日:1980-09-03

    摘要: Electrically conducting acrylic and modacrylic fibers are prepared by subjecting the fibers to a first heat-treatment in a bath containing a copper compound and a reducing agent to adsorb monovalent copper ions within the fibers. The heat-treated fibers are washed thoroughly and then subjected to a second heat-treatment in the presence of a sulfur-containing compound to convert the adsorbed monovalent copper ions to copper sulfide. The electrically conducting fibers have superior conductivity which is not lost in repeated washings. The electrically conductive fibers can be dyed readily with cationic dyes without loss of electrical conductivity. The electrically conductive fibers of the present invention possess the touch and other physical characteristics of the starting acrylic or modacrylic fibers.

    摘要翻译: 通过在含有铜化合物和还原剂的浴中对纤维进行第一次热处理以吸附纤维内的一价铜离子来制备导电丙烯酸和改性聚丙烯腈纤维。 将经热处理的纤维充分洗涤,然后在含硫化合物的存在下进行第二次热处理,将吸附的一价铜离子转化成硫化铜。 导电纤维具有优异的导电性,其在反复洗涤中不会损失。 导电纤维可以用阳离子染料容易地染色而不损失导电性。 本发明的导电纤维具有起始丙烯酸或改性聚丙烯腈纤维的触感和其它物理特性。

    Method of producing an electrically conductive polymeric material with
adsorbed metal sulfide and product
    3.
    发明授权
    Method of producing an electrically conductive polymeric material with adsorbed metal sulfide and product 失效
    用吸附的金属硫化物和产品制备导电聚合材料的方法

    公开(公告)号:US4681820A

    公开(公告)日:1987-07-21

    申请号:US736777

    申请日:1985-05-22

    摘要: An electrically conducting material including a polymeric material having adsorbed sulfides of a first metal selected from copper, cobalt, tin, mercury and lead and of a second metal selected from silver, gold and elements of the platinum group. The polymeric material is in the form of powder or a shaped body such as a fiber, film or string and is formed of a synthetic polymer without cyanic groups such as a polyester or a polyamide or a naturally occurring polymeric substance such as silk or wool. The electrically conducting material may be prepared by treating the polymeric material with hydrogen sulfide, and then treating the resultant material having absorbed hydrogen sulfide with (a) a source of ions containing the first metal, (b) a source of ions containing the second metal and, optionally, (c) a sulfur-containing compound to form sulfides of the first and second metals adsorbed by the polymeric material.

    摘要翻译: 一种导电材料,包括具有吸附的选自铜,钴,锡,汞和铅的第一金属的硫化物和选自银,金和铂族元素的第二金属的聚合物材料。 聚合物材料为粉末或成形体的形式,如纤维,薄膜或线,由不含氰基的合成聚合物形成,如聚酯或聚酰胺或天然存在的聚合物质如丝或羊毛。 导电材料可以通过用硫化氢处理聚合材料制备,然后用(a)含有第一金属的离子源处理所吸收的硫化氢的所得材料,(b)含有第二金属的离子源 和(c)含硫化合物以形成由聚合物材料吸附的第一和第二金属的硫化物。

    Package dyeing method
    4.
    发明授权
    Package dyeing method 失效
    包装染色方法

    公开(公告)号:US3998585A

    公开(公告)日:1976-12-21

    申请号:US592988

    申请日:1975-07-03

    摘要: A batchwise packaging dyeing method is disclosed wherein a loose stock of fiber is charged into a basket carrier of a high temperature, high pressure package dyeing machine. The loose stock of fiber is charged in such a manner that the change rate (a) is 10% or less and is defined as the difference between the open space value before dyeing (E.sub.1) of the fiber layer and the open space value after dyeing (E.sub.2) of the fiber layer.

    摘要翻译: 公开了一种分批包装染色方法,其中将松散的纤维原料装入高温高压包装染色机的筐架中。 纤维的松散原料以使得变化率(a)为10%以下并且被定义为纤维层染色前的开放空间值(E1)与染色后的开放空间值之间的差异的方式进行充电 (E2)。

    Electrically conducting material and process of preparing same
    6.
    发明授权
    Electrically conducting material and process of preparing same 失效
    导电材料及其制备方法

    公开(公告)号:US4556508A

    公开(公告)日:1985-12-03

    申请号:US461250

    申请日:1983-01-26

    摘要: An electrically conducting material including a cyanic group-containing material substrate and adsorbed sulfides of copper and an auxiliary metal selected from silver, gold and elements of the platinum group. The cyanic group-containing substrate may be in the form of powder or a shaped body such as a fiber, film, plate, rod or like suitable substrate include a synthetic polymers such as polyacrylonitrile and polyamides having cyanic groups; naturally occurring polymeric substances such as cotton having introduced thereinto cyanic groups; and low molecular weight compounds such as phthalonitrile. The electrically conducting material may be prepared by treating the cyanic group-containing substrate with (a) a source of monovalent copper ions, (b) a source of ions containing the auxiliary metal and (c) a sulfur-containing compound to form sulfides of copper and the auxiliary metal adsorbed by the cyanic group-containing material.

    摘要翻译: 包含含有氰基的材料的导电材料,其吸附有铜的硫化物和选自银,金和铂族的元素的辅助金属。 含氰基的材料为粉末或成形体的形式,例如纤维,薄膜,板,棒等,并且由合成聚合物如聚丙烯腈或引入氰基的聚酰胺形成; 天然存在的聚合物质,例如已经引入氰基的棉花; 或低分子化合物如邻苯二甲腈。 可以通过用(a)一价铜离子源,(b)含有辅助金属的离子源和(c)含硫化合物来处理含氰基材料来制备导电材料,以形成硫化物 铜和辅助金属被含氰基材料吸附。

    Electrically conducting material and method of preparing same
    7.
    发明授权
    Electrically conducting material and method of preparing same 失效
    导电材料及其制备方法

    公开(公告)号:US4556507A

    公开(公告)日:1985-12-03

    申请号:US461035

    申请日:1983-01-26

    摘要: An electrically conducting material including a polymeric material having adsorbed sulfides of a first metal selected from copper, cobalt, tin, mercury and of lead and a second metal selected from silver, gold and elements of the platinum group. The polymeric material is in the form of powder or a shaped body such as a fiber, film or string and is formed of a synthetic polymer without cyanic groups such as a polyester or a polyamide or a naturally occurring polymeric substance such as silk or wool. The electrically conducting material may be prepared by treating the polymeric material with hydrogen sulfide, and then treating the resultant material having adsorbed hydrogen sulfide with (a) a source of ions containing the first metal, (b) a source of ions containing the second metal and, optionally, (c) a sulfur-containing compound to form sulfides of the first and second metals adsorbed by the polymeric material.

    摘要翻译: 一种导电材料,其包括具有吸附的选自铜,钴,锡,汞和铅的第一金属的硫化物和选自银,金和铂族元素的第二金属的聚合物材料。 聚合物材料为粉末或成形体的形式,如纤维,薄膜或线,由不含氰基的合成聚合物形成,如聚酯或聚酰胺或天然存在的聚合物质如丝或羊毛。 导电材料可以通过用硫化氢处理聚合材料,然后用(a)含有第一金属的离子源来处理具有吸附的硫化氢的所得材料,(b)含有第二金属的离子源 和(c)含硫化合物以形成由聚合物材料吸附的第一和第二金属的硫化物。

    Method of making electrically conducting fiber
    8.
    发明授权
    Method of making electrically conducting fiber 失效
    制造导电纤维的方法

    公开(公告)号:US4364739A

    公开(公告)日:1982-12-21

    申请号:US249416

    申请日:1981-03-31

    摘要: Electrically conducting acrylic and modacrylic fibers are prepared by subjecting the fibers to a first heat-treatment in a bath containing a copper compound and a reducing agent to adsorb monovalent copper ions within the fibers. The heat-treated fibers are washed thoroughly and then subjected to a second heat-treatment in the presence of a sulfur-containing compound to convert the adsorbed monovalent copper ions to copper sulfide. The electrically conducting fibers have superior conductivity which is not lost in repeated washings. The electrically conductive fibers can be dyed readily with cationic dyes without loss of electrical conductivity. The electrically conductive fibers of the present invention possess the touch and other physical characteristics of the starting acrylic or modacrylic fibers.

    摘要翻译: 通过在含有铜化合物和还原剂的浴中对纤维进行第一次热处理以吸附纤维内的一价铜离子来制备导电丙烯酸和改性聚丙烯腈纤维。 将经热处理的纤维充分洗涤,然后在含硫化合物的存在下进行第二次热处理,将吸附的一价铜离子转化成硫化铜。 导电纤维具有优异的导电性,其在反复洗涤中不会损失。 导电纤维可以用阳离子染料容易地染色而不损失导电性。 本发明的导电纤维具有起始丙烯酸或改性聚丙烯腈纤维的触感和其它物理特性。