摘要:
The invention relates to the use of partly silanized compounds based on polyisocyanate as crosslinking agents with heightened refractive index in curable coating compositions, more particularly in clearcoat materials for automotive finishing. The invention likewise relates to a coating composition which comprises these compounds as crosslinking agents, and to the use of the coating composition to produce a coating.
摘要:
Disclosed herein is a silane-functional mixture, comprising at least one phosphonic diester (A), at least one diphosphonic diester (A), or at least one phosphonic diester and one diphosphonic diester (A), and at least one compound (B) comprising at least two condensable silane groups.
摘要:
Disclosed are coating compositions comprising at least one hydroxyl-containing compound (A) and at least one isocyanato-containing compound (B), wherein one or more of the constituents of the coating composition comprise between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (I) —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (I) and between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (II) —Z—(X—SiR″x(OR′)3-x) (II).
摘要:
Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, said catalyst (D) comprising phosphorus. It is an aspect of the disclosed coating compositions that (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (ii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network.
摘要:
Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, where (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (iii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network. The finally cured coating obtained from the coating composition has a post-crosslinking index (PCI) of less than 2, wherein (PCI) is defined as the ratio of the storage modulus E′(200) at 200° C. to the minimum of the storage modulus E′(min) at a temperature above the measured glass transition temperature Tg.
摘要:
Liquid, thermally curable mixtures comprising, (A) low molecular weight polyols having at least three hydroxyl groups and a hydroxyl group content corresponding to a theoretical OH number of 800 to 1900 mg KOH/g, (B) compounds selected from the group consisting of cyclic and acyclic C9-C16 alkanes functionalized with hydroxyl groups or hydroxyl and at least one thiol group, and (C) low molecular weight or oligomeric compounds having reactive functional groups (c1) complementary to hydroxyl groups and thiol groups, processes for preparing them, and their use.
摘要:
The invention relates to the use of partly silanized compounds based on polyisocyanate as crosslinking agents with heightened refractive index in curable coating compositions, more particularly in clearcoat materials for automotive finishing. The invention likewise relates to a coating composition which comprises these compounds as crosslinking agents, and to the use of the coating composition to produce a coating.
摘要:
Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, said catalyst (D) comprising phosphorus. It is an aspect of the disclosed coating compositions that (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (ii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network.
摘要:
The invention relates to a coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material, of at least one compound (A1) containing at least one reactive group of the formula(I) —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (I) where R=hydrogen, alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, with Ra=alkyl, cycloalkyl, aryl or aralkyl, R′=hydrogen, alkyl or cycloalkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, X, X′=linear and/or branched alkylene or cycloalkylene radical of 2 to 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2, (B) a catalyst for the crosslinking of the —Si(OR′)3-X(y) units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要:
Disclosed are coating compositions comprising at least one hydroxyl-containing compound (A) and at least one isocyanato-containing compound (B), wherein one or more of the constituents of the coating composition comprise between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (I) —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (I) and between 2.5 and 97.5 mol %, based on the entirety of structural units (I) and (II), of at least one structural unit of the formula (II) —Z—(X—SiR″x(OR′)3-x) (II).