摘要:
The present invention relates to a process for the coating of polycarbonate substrates, in particular of transparent polycarbonate substrates, by applying a transparent coating composition encompassing at least one radiation-curing binder resin (A) and/or reactive diluent (C), nanoparticles (B), optionally solvent and at least one light stabilizer (L), to a polycarbonate substrate, wherein the coating composition comprises at least one light stabilizer (L) which comprises, per molecule, an average of at least one ethylenically unsaturated group bonded by way of a urethane group.The present invention also relates to the coating compositions used in said process, and to the coated polycarbonate substrates obtainable via is the process, and to their use.
摘要:
The present invention relates to a process for the coating of polycarbonate substrates, in particular of transparent polycarbonate substrates, by applying a transparent coating composition encompassing at least one radiation-curing binder resin (A) and/or reactive diluent (C), nanoparticles (B), optionally solvent and at least one light stabilizer (L), to a polycarbonate substrate, wherein the coating composition comprises at least one light stabilizer (L) which comprises, per molecule, an average of at least one ethylenically unsaturated group bonded by way of a urethane group.The present invention also relates to the coating compositions used in said process, and to the coated polycarbonate substrates obtainable via the process, and to their use.
摘要:
The disclosed method comprises applying a transparent coating composition to a plastics substrate, the composition comprising30% to 60% by weight of a nanoparticles (B), 15% to 40% by weight, of urethane (meth)acrylates (A1) having 3 to 5 (meth)/acrylate groups per molecule, 0% to less than 10% by weight of urethane (meth)acrylates (A2) having more than 5 (meth)/acrylate groups per molecule, 0% to less than 10% by weight of urethane (meth)acrylates (A3) having less than 3 (meth)/acrylate groups per molecule, 55% to 80% by weight of compounds (C1) having 4 (meth)/acrylate groups per molecule, 0% to 15% by weight of compounds (C2) having 2 (meth)/acrylate groups per molecule, and 0% to 15% by weight of compounds (C3) having 3 (meth)/acrylate groups per molecule, the sum of the weight fractions of film-forming components (A1), (A2), (A3), (C1), (C2), and (C3) being in each case 100% by weight.
摘要:
A thermosetting coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material of (A1) from 0% to 50% by weight, based on the entirety of components (A1) and (A2), of a polymethacrylate copolymer containing more than 50% by weight, based on the entirety of comonomers in the copolymer (A1), of free-radically polymerizable, ethylenically unsaturated compounds (a1) containing at least one reactive group of the formula I —X—SiR″x(OR′)3-x (I) and (A2) from 50% to 100% by weight, based on the entirety of components (A1) and (A2), of an adduct of polyisocyanate and alkoxysilane, (A2) containing at least one reactive group of the formula II: —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II) (B) a catalyst for the crosslinking of the —Si(OR′)3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要:
The disclosed method comprises applying a transparent coating composition to a plastics substrate, the composition comprising30% to 60% by weight of a nanoparticles (B), 15% to 40% by weight, of urethane (meth)acrylates (A1) having 3 to 5 (meth)/acrylate groups per molecule, 0% to less than 10% by weight of urethane (meth)acrylates (A2) having more than 5 (meth)/acrylate groups per molecule, 0% to less than 10% by weight of urethane (meth)acrylates (A3) having less than 3 (meth)/acrylate groups per molecule, 55% to 80% by weight of compounds (C1) having 4 (meth)/acrylate groups per molecule, 0% to 15% by weight of compounds (C2) having 2 (meth)/acrylate groups per molecule, and 0% to 15% by weight of compounds (C3) having 3 (meth)/acrylate groups per molecule, the sum of the weight fractions of film-forming components (A1), (A2), (A3), (C1), (C2), and (C3) being in each case 100% by weight.
摘要:
A thermosetting transparent coating material, its preparation and use. The coating includes (meth)acrylate (co)polymer having a number-average molecular weight of from 1,000 to 6,000 daltons, a glass transition temperature of −15 to +70° C., and a hydroxyl number of from 80 to 200 mg KOH/g; polyester having a number-average molecular weight of from 800 to 6,000 daltons, a hydroxyl number of from 80 to 200 mg KOH/g and an acid number of from 1 to 50 mg KOH/g, comprising, based on the polyester, from 30 to 70% by weight of cycloaliphatic structural units; a blocked polyisocyanate in which the blocked polyisocyanate groups are attached to flexibilizing structural units which, as part of a three-dimensional network, lower its glass transition temperature; and blocked polyisocyanate in which the blocked polyisocyanate groups are attached to hardening structural units which, as part of a three-dimensional network, raise its glass transition temperature.
摘要:
A thermosetting transparent coating material, its preparation and use. The coating includes (meth)acrylate (co)polymer having a number-average molecular weight of from 1,000 to 6,000 daltons, a glass transition temperature of −15 to +70° C., and a hydroxyl number of from 80 to 200 mg KOH/g; polyester having a number-average molecular weight of from 800 to 6,000 daltons, a hydroxyl number of from 80 to 200 mg KOH/g and an acid number of from 1 to 50 mg KOH/g, comprising, based on the polyester, from 30 to 70% by weight of cycloaliphatic structural units; a blocked polyisocyanate in which the blocked polyisocyanate groups are attached to flexibilizing structural units which, as part of a three-dimensional network, lower its glass transition temperature; and blocked polyisocyanate in which the blocked polyisocyanate groups are attached to hardening structural units which, as part of a three-dimensional network, raise its glass transition temperature.
摘要:
The invention relates to a coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material, of at least one compound (A1) containing at least one reactive group of the formula(I) —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (I) where R=hydrogen, alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, with Ra=alkyl, cycloalkyl, aryl or aralkyl, R′=hydrogen, alkyl or cycloalkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, X, X′=linear and/or branched alkylene or cycloalkylene radical of 2 to 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2, (B) a catalyst for the crosslinking of the —Si(OR′)3-X(y) units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要:
A thermosetting coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material of (A1) from 0% to 50% by weight, based on the entirety of components (A1) and (A2), of a polymethacrylate copolymer containing more than 50% by weight, based on the entirety of comonomers in the copolymer (A1), of free-radically polymerizable, ethylenically unsaturated compounds (a1) containing at least one reactive group of the formula I —X—SiR″x(OR″)3-x (I) and (A2) from 50% to 100% by weight, based on the entirety of components (A1) and (A2), of an adduct of polyisocyanate and alkoxysilane, (A2) containing at least one reactive group of the formula II: —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II) (B) a catalyst for the crosslinking of the —Si(OR′)3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要翻译:一种热固性涂料,其包含(A)至少50重量%,基于组合物(A1)和(A1)的总成分(A1)中(A1)的涂料中的非挥发性物质的量为0重量%至50重量% A2),含有基于共聚物(A1)中共聚单体总共的50重量%以上的含有至少一个式I的反应性基团的可自由基聚合的烯属不饱和化合物(a1)的聚甲基丙烯酸酯共聚物 <?in-line-formula description =“In-line Formulas”end =“lead”?> X-SiR“x”(OR“)3-x SUB (A1)和(A1)和(A1)的全部组成成分(A1)和(A2)以重量百分比计,从50%到100% A2),包含至少一个式II的反应性基团的(A2)的聚异氰酸酯和烷氧基硅烷的加合物:<?in-line-formula description =“In-line formula”end =“lead”→> C(O)-N-(X-SiR“x”(OR')3-x N)(X'-SiR' ' y SUB (OR')3-y sub> m(II)<?in-line-formula description =“In-line Formulas”end =“tail”?>( B)用于交联-Si(OR')3-x sub>单元的催化剂,和(C)非质子溶剂或非质子传递溶剂的混合物。