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1.发明申请Composite polymer film with graphene nanosheets as highly effective barrier property enhancers 审中-公开具有石墨烯纳米片的复合聚合物膜作为高效阻隔性能增强剂公开(公告)号：US20130295367A1
公开(公告)日：2013-11-07
申请号：US13986011
申请日：2013-03-22
摘要： Composite polymer films or layers have graphene-based nanosheets dispersed in the polymer for the reduction of gas permeability and light transmittance.
摘要翻译： 复合聚合物膜或层具有分散在聚合物中的石墨烯纳米片，以降低透气性和透光率。
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公开(公告)号：US20100323177A1
公开(公告)日：2010-12-23
申请号：US12152283
申请日：2008-05-13
CPC分类号： B32B9/04 , B32B9/007 , B32B2307/54 , B32B2307/726 , B32B2457/00
摘要： A macroscale sheet laminate includes individual graphene oxide sheets layered one on another in a manner to form a self-supporting paper-like laminated product. The product can be fabricated by making a suspension of individual graphene oxide sheets and assembling the graphene oxide sheets as a laminate on a fluid-permeable support by flow-directed assembly. The laminate is dried and released from the membrane filter as a self-supporting sheet laminate.
摘要翻译： 宏观层压板包括以形成自支撑纸状层压产品的方式彼此层叠的单独的石墨烯氧化物片材。 可以通过制备单独的石墨烯氧化物片的悬浮液并通过流动组装将石墨烯氧化物片作为层压体组装在流体可渗透的载体上来制造产品。 将层压体作为自支撑片材层压体从膜过滤器干燥并释放。
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公开(公告)号：US08604141B2
公开(公告)日：2013-12-10
申请号：US13454244
申请日：2012-04-24
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
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公开(公告)号：US07914844B2
公开(公告)日：2011-03-29
申请号：US11600679
申请日：2006-11-16
CPC分类号： H01B1/24 , C01B32/225
摘要： A method of making a dispersion of reduced graphite oxide nanoplatelets involves providing a dispersion of graphite oxide nanoplatelets and reducing the graphite oxide nanoplatelets in the dispersion in the presence of a reducing agent and a polymer. The reduced graphite oxide nanoplatelets are reduced to an extent to provide a higher C/O ratio than graphite oxide. A stable dispersion having polymer-treated reduced graphite oxide nanoplatelets dispersed in a dispersing medium, such as water or organic liquid is provided. The polymer-treated, reduced graphite oxide nanoplatelets can be distributed in a polymer matrix to provide a composite material.
摘要翻译： 制备还原性氧化石墨纳米片的分散体的方法包括在还原剂和聚合物的存在下提供石墨氧化物纳米片的分散体并还原分散体中的氧化石墨纳米片。 还原的氧化石墨纳米片减少到提供比氧化石墨更高的C / O比的程度。 提供了分散在分散介质如水或有机液体中的具有聚合物处理的还原性氧化石墨纳米片的稳定分散体。 聚合物处理的还原性氧化石墨纳米片可以分布在聚合物基质中以提供复合材料。
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公开(公告)号：US20100323178A1
公开(公告)日：2010-12-23
申请号：US12152284
申请日：2008-05-13
CPC分类号： C04B35/624 , C04B35/14 , C04B2235/422 , H01L51/442
摘要： A ceramic composite thin film or layer includes individual graphene oxide and/or electrically conductive graphene sheets dispersed in a ceramic (e.g. silica) matrix. The thin film or layer can be electrically conductive film or layer depending the amount of graphene sheets present. The composite films or layers are transparent, chemically inert and compatible with both glass and hydrophilic SiOx/silicon substrates. The composite film or layer can be produced by making a suspension of graphene oxide sheet fragments, introducing a silica-precursor or silica to the suspension to form a sol, depositing the sol on a substrate as thin film or layer, at least partially reducing the graphene oxide sheets to conductive graphene sheets, and thermally consolidating the thin film or layer to form a silica matrix in which the graphene oxide and/or graphene sheets are dispersed.
摘要翻译： 陶瓷复合薄膜或层包括分散在陶瓷（例如二氧化硅）基体中的单独的石墨烯氧化物和/或导电石墨烯薄片。 根据存在的石墨烯片的量，薄膜或层可以是导电膜或层。 复合膜或层是透明的，化学惰性的并且与玻璃和亲水性SiO x /硅衬底兼容。 可以通过制备氧化石墨烯片片段的悬浮液，将二氧化硅前体或二氧化硅引入悬浮液以形成溶胶，将溶胶沉积在基材上作为薄膜或层，来制备复合膜或层，至少部分地减少 氧化石墨烯片与导电石墨烯片，并且热固化该薄膜或层以形成其中分散有氧化石墨烯和/或石墨烯片的二氧化硅基质。
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公开(公告)号：US07288666B2
公开(公告)日：2007-10-30
申请号：US11472137
申请日：2006-06-20
IPC分类号： C07F15/00
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X are independently selected from any anionic ligand; and L and L are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物具有下式：其中M是Os或Ru; R 1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性电子给体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。
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公开(公告)号：US06806325B2
公开(公告)日：2004-10-19
申请号：US10325998
申请日：2002-12-19
IPC分类号： C08F442
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X1 are independently selected from any anionic ligand; and L and L1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物是M为Os或Ru的化合物; R 1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性电子给体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。
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公开(公告)号：US06111121A
公开(公告)日：2000-08-29
申请号：US7498
申请日：1998-01-15
IPC分类号： B01J31/24 , B01J31/22 , C07F9/50 , C07F15/00 , C07F19/00 , C08F4/42 , C08F4/80 , C08F8/50 , C08F32/00 , C08G61/02 , C08G61/08
CPC分类号： C08F4/80 , B01J31/2265 , B01J31/24 , B01J31/2404 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , B01J31/18
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula ##STR1## where M is Os or Ru; R.sup.1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译： 公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。 还公开了制备卡宾化合物的方法。 卡宾化合物具有下式：其中M是Os或Ru; R1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性给电子体。 本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。 本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。
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9.发明授权High activity ruthenium and osmium metal carbene complexes for olefin metathesis reactions 失效用于烯烃复分解反应的高活性钌和锇金属卡宾络合物
公开(公告)号：US5969170A
公开(公告)日：1999-10-19
申请号：US862615
申请日：1997-05-23
IPC分类号： B01J23/46 , B01J31/22 , C07C51/353 , C07C67/475 , C07F15/00 , C08F4/80 , C08F8/50 , C08F10/00 , C08F32/00 , C08F210/02 , C08G61/08 , C08G61/12 , C07F9/28
CPC分类号： B01J31/2265 , B01J31/24 , B01J31/2404 , C07C51/353 , C07C67/333 , C07C67/475 , C07F15/002 , C07F15/0046 , C08C19/08 , C08F10/00 , C08F32/00 , C08F8/50 , C08G61/08 , C08G61/128 , B01J2231/14 , B01J2231/543 , B01J23/462 , B01J23/466 , B01J2531/821 , B01J2531/825 , C07C2101/10 , C08C2019/09 , C08F210/02 , Y10S525/938
摘要： Disclosed are ruthenium and osmium carbene compounds which are stable in the presence of a variety of functional groups and which can be used to catalyze olefin metathesis reactions on strained and unstrained cyclic and acyclic olefins. Specifically, the present invention relates to carbene compounds of the formula ##STR1## wherein: M is Os or Ru; R and R.sup.1 are independently selected from hydrogen and substituent groups C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.2 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl or C.sub.1 -C.sub.20 alkylsulfinyl; each substituent group optionally substituted with C.sub.1 -C.sub.5 alkyl, a halogen, C.sub.1 -C.sub.5 alkoxy or with a phenyl group optionally substituted with a halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are each trialkyl phosphine ligands where at least one of the alkyl groups on the phosphine is a secondary alkyl or a cycloalkyl. A broad array of metathesis reactions are enabled including ring-opening metathesis polymerization of cyclic olefins, ring closing metathesis of acyclic dienes, cross metathesis involving at least one acyclic or unstrained cyclic olefin, depolymerization of unsaturated polymers and synthesis of telechelic polymers.
摘要翻译： 公开了在各种官能团存在下稳定的钌和咔卡因化合物，其可用于催化在应变和未应变的环状和无环烯烃上的烯烃复分解反应。 具体地说，本发明涉及下式的卡宾化合物其中：M是Os或Ru; R和R 1独立地选自氢和取代基C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷基，芳基，C 1 -C 20羧酸酯，C 2 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基， C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基或C 1 -C 20烷基亚磺酰基; 任选被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基或任选被卤素，C 1 -C 5烷基或C 1 -C 5烷氧基取代的苯基取代的取代基; X和X 1独立地选自任何阴离子配体; L和L1各自为三烷基膦配体，其中膦上的至少一个烷基是仲烷基或环烷基。 可以进行广泛的复分解反应，包括环烯烃的开环易位聚合，无环二烯的闭环复分解，涉及至少一个无环或非应变的环烯烃的交叉复分解，不饱和聚合物的解聚和遥爪聚合物的合成。
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公开(公告)号：US08709213B2
公开(公告)日：2014-04-29
申请号：US12931407
申请日：2011-01-31
CPC分类号： D21H13/46 , B01D69/148 , B01D71/021 , B32B5/16 , B32B9/04 , B32B19/00 , B32B27/00 , B32B2264/108 , B32B2307/50 , B32B2307/546 , B32B2307/728 , B32B2307/73 , B32B2307/732 , D21F13/00 , D21H5/008 , D21H13/36 , Y10T428/31504 , Y10T428/31536
摘要： A macroscale, self-supporting, composite laminate sheet includes individual, layered graphene oxide sheets and a polymer in spaces between the sheets. This composite product can be fabricated by combining a suspension of individual graphene oxide sheets and a solution of polymer, passing the resulting fluid through a fluid-permeable support, and assembling the graphene oxide sheets and polymer as a laminate sheet by flow-directed assembly. The laminate is dried and released from the membrane filter as a self-supporting thin films.
摘要翻译： 大尺寸，自支撑的复合层压板包括单独的层状石墨烯氧化物片和在片之间的空间中的聚合物。 该复合产品可以通过将单独的石墨烯氧化物片和聚合物溶液的悬浮液组合而制成，使得所得流体通过流体可渗透的载体，并且通过流动组装将氧化石墨烯和聚合物作为层压片组装。 将层压体作为自支撑薄膜从膜过滤器干燥并释放。
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