摘要:
Film-forming compositions which are substantially free of organic solvent and capable of forming a generally continuous film at ambient temperature are provided. The film-forming composition includes at least one thermosettable aqueous dispersion of polymeric microparticles having functionality adapted to react with a crosslinking agent. The polymeric microparticles are prepared by mixing under high shear conditions (1) at least one hydrophobic polymer having reactive functional groups; and (2) at least one hydrophobic crosslinking agent containing functional groups which are reactive with the functional groups of the polymer. Further provided is a multi-component composite coating composition which includes a pigmented base coat and a transparent topcoat of the substantially organic solvent-free film-forming composition described above. Substrates coated with the same are also provided. Additionally, a method for preparing the aqueous dispersion of polymeric microparticles is provided. The substantially organic solvent-free film-forming compositions of the invention are storage stable at room temperature and provide coatings with excellent appearance and performance properties such as adhesion and scratch resistance. The film-forming compositions are suitable for wet-on-wet application over a base coat with little or no mud-cracking.
摘要:
A film-forming composition, typically a topcoat, having improved adhesion to certain commercially available adhesives. The composition includes a curable film-forming polymer, typically an acrylic and/or a polyester polymer, with carbamate and/or urea groups. The composition further includes a material containing one or more hydrolyzable silyl groups. The hydrolyzable silyl group-containing material optionally can be a polymeric or oligomeric. Also disclosed are a method of applying the above-described film-forming composition to a substrate and the coated article prepared by such a method.
摘要:
A copolymer having utility in coating compositions comprises the addition polymerization product of an alpha-olefin monocarboxylic acid having at least 8 carbon atoms (particularly undecylenic acid) and a mono- or di-ester of an unsaturated dicarboxylic acid or anhydride (e.g., dialkyl maleat). The copolymer may be provided with hydroxy functionality by reacting the carboxylic acid functionality with an epoxy compound to permit use in curable coatings. Alternatively the copolymer may be base neutralized to serve as a surfactant in aqueous dispersion polymerization.
摘要:
An amphoteric, hair fixative polymer for use in hair sprays, gels, and the like contains 40-90 percent of a hydroxyl-containing ethylenically unsaturated monomer, 1-20 percent of an acid-containing ethylenically unsaturated monomer, and 1-20 percent of an amine-containing ethylenically unsaturated monomer. The polymer has hydroxyl, acid and amine functionalities and, while being insoluble in water, can be solubilized in water by the use of amine neutralizers, acidic neutralizers, or by solubilizing in alcohol-water mixtures. The polymers provide hair fixatives that are fast drying, and have excellent curl retention with low curl droop.
摘要:
An organic colloidal dispersion of polar polymeric microparticles synthesized directly in a non-aqueous polar medium is disclosed. The dispersion is particularly useful for controlling rheological properties such as sag and metallic flake orientation in coating compositions.
摘要:
Acid etch resistant coating compositions and their use as clear coats in color-plus-clear composite coatings is disclosed. The compositions comprise acrylic polymers prepared with high levels of cycloaliphatic ester of (meth)acrylic acid and hydroxypropyl- or hydroxybutyl(meth)acrylates and aminoplast crosslinking agents.
摘要:
A two-component thermosetting coating composition is disclosed wherein the binder components comprise: (a) an amino component comprising an aqueous solution and/or dispersion of at least one polyacrylate containing amino groups in a quantity sufficient to make said polyacrylate soluble and/or dispersible in water; and (b) a polyisocyanate component containing free isocyanate groups. Also disclosed is the method of emulsifying component (b) into component (a).
摘要:
A stable aqueous dispersion containing cellulose ester, the dispersion being polymeric microparticles comprised of cellulose ester and a polymer formed from at least two different vinyl monomers of which at least one vinyl monomer is polyethylenically unsaturated. The dispersion of microparticles is formed by a high stress technique prior to polymerization of the vinyl monomers in the presence of the cellulose ester. Typically the dispersion also contains surfactant. A method of making the stable, cellulose ester-containing aqueous dispersion by (a) mixing together a cellulose ester, at least two vinyl monomers of which at least one vinyl monomer is polyethylenically unsaturated, surfactant, and water to form an emulsion; (b) particulating the emulsified mixture of (a) into microparticles by a high stress technique; and (c) copolymerizing the vinyl monomers in the cellulose ester-containing particulated emulsion of (b) to form a crosslinked polymer within the microparticles of the dispersion. Also aqueous coating compositions formed from the stable cellulose ester containing aqueous dispersion; crosslinking material; and, optionally, additional film forming resins. The aqueous coating compositions can also contain pigments. The coating compositions are very advantageous, particularly in automotive base coats containing metallic pigments and exhibit good humidity resistance, appearance, adhesion and chip resistance when used in an automotive "low bake repair" process.
摘要:
Acid etch resistant coating compositions and their use as clear coats in color-plus-clear composite coatings is disclosed. The compositions comprise acrylic polymers prepared with high levels of cycloaliphatic or aromatic ester of (meth)acrylic acid and hydroxypropyl- or hydroxybutyl(meth)acrylates and aminoplast crosslinking agents.
摘要:
Coatings for microporous printing sheets are disclosed. The coatings comprise an acrylic resin and a dye fixative material. The coated microporous sheets may be inkjet printed with good image characteristics. The printed sheets may be laminated, and possess high peel strengths while maintaining favorable optical characteristics. The coated microporous printing sheets are useful for many applications such as laminated security cards, tags and labels, as well as wide format printing applications.