公开(公告)号：US07329468B2

公开(公告)日：2008-02-12

申请号：US10935643

申请日：2004-09-07

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B9/04

CPC分类号： B05D7/57 ,  B05D7/574 ,  C08J5/12 ,  C08K3/38 ,  C08K5/55 ,  C09D7/60 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

摘要翻译： 本发明提供了两种或更多种聚合物层的改进的多层复合材料，其中至少一种由热固性组合物形成。 所述复合材料包括形成在基材上的至少第一聚合物层和在所述第一聚合物层上的第二聚合物层，其中在不存在含硼化合物的情况下，所述第一和第二聚合物层具有差的层间粘合性。 改进在于在足以改善第一和第二聚合物层之间的层间粘合力的量中将至少一种含硼化合物包含在第一和第二聚合物层的一个或两个中。 还提供了一种改进的可固化涂料组合物，其用于形成两层或多层固化涂层的多层复合涂层，其中至少一层由热固性组合物形成。 还提供了相关方法和涂覆的基底。

公开(公告)号：US07172809B2

公开(公告)日：2007-02-06

申请号：US10642826

申请日：2003-08-19

申请人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

发明人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

IPC分类号： B32B5/16

CPC分类号： C09D201/06 ,  C08G18/4692 ,  C08G18/792 ,  C09D167/00 ,  C09D175/04 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/254 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L2666/28 ,  C08L2666/16

摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.

摘要翻译： 由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。 本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。 本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。 本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。 本发明的其它实施方案涉及用上述固化组合物涂覆的基材。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。 本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

公开(公告)号：US06635341B1

公开(公告)日：2003-10-21

申请号：US09629421

申请日：2000-07-31

申请人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

发明人： Steven V. Barancyk ,  John W. Burgman ,  James B. O'Dywer ,  Laura A. Kiefer-Liptak ,  Michael Allen Mayo ,  Gregory J. McCollum ,  Shiryn Tyebjee

IPC分类号： B32B516

CPC分类号： C09D201/06 ,  C08G18/4692 ,  C08G18/792 ,  C09D167/00 ,  C09D175/04 ,  Y10T428/25 ,  Y10T428/251 ,  Y10T428/254 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2998 ,  Y10T428/31511 ,  Y10T428/31551 ,  C08L2666/28 ,  C08L2666/16

摘要： Coating compositions formed from at least one hydroxyl functional non-vinyl material comprising at least one alcoholic hydroxyl group blocked with a hydrolyzable silyl group, and at least one curing agent are provided by the present invention. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carbamate functional material comprising at least one carbamate group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition formed from components comprising at least one carboxyl functional material comprising at least one carboxyl group blocked with a hydrolyzable silyl group, and at least one curing agent. Another embodiment of the present invention is directed to a coating composition, formed from components comprising at least one amide functional material comprising at least one amide blocked with a hydrolyzable silyl group, and at least one curing agent. Other embodiments of the present invention are directed to substrates coated with the aforementioned cured compositions. Also provided are multi-component composite coatings which include a cured basecoat deposited from a pigmented coating composition and a cured topcoat deposited from a topcoating composition. The multi-component composite coatings of the invention provide highly scratch resistant color-plus-clearcoatings. Further embodiments of the present invention are directed to methods for improving scratch resistance of a substrate.

摘要翻译： 由至少一种包含至少一个用可水解甲硅烷基封端的醇羟基的羟基官能非乙烯基材料形成的涂料组合物和至少一种固化剂由本发明提供。 本发明的另一个实施方案涉及由包含至少一种氨基甲酸酯官能材料的组分形成的涂料组合物，所述氨基甲酸酯官能材料包含至少一个被可水解甲硅烷基封端的氨基甲酸酯基团和至少一种固化剂。 本发明的另一个实施方案涉及由包含至少一种包含至少一个被可水解甲硅烷基封端的羧基的羧基官能材料和至少一种固化剂的组分形成的涂料组合物。 本发明的另一个实施方案涉及由包含至少一种酰胺官能材料的组分形成的涂料组合物，所述酰胺官能材料包含至少一个用可水解甲硅烷基封端的酰胺和至少一种固化剂。 本发明的其它实施方案涉及用上述固化组合物涂覆的基材。 还提供了多组分复合涂层，其包括由着色涂料组合物沉积的固化底涂层和从表面涂层组合物沉积的固化顶涂层。 本发明的多组分复合涂层提供高耐刮擦的彩色 - 透明涂层。 本发明的其它实施方案涉及用于改善基材的耐刮擦性的方法。

公开(公告)号：US5709950A

公开(公告)日：1998-01-20

申请号：US770196

申请日：1996-12-19

申请人： John W. Burgman ,  Gina M. Terrago ,  Christopher A. Verardi

发明人： John W. Burgman ,  Gina M. Terrago ,  Christopher A. Verardi

IPC分类号： C08G18/46 ,  C08G18/50 ,  C08G65/333 ,  C08G71/00 ,  C08L61/20 ,  C08L71/02 ,  C09D171/02 ,  C09D201/06 ,  C08L61/32 ,  C08L71/08

CPC分类号： C09D171/02 ,  C08G18/4615 ,  C08G18/5045 ,  C08G65/33344 ,  C08G71/00 ,  C08L71/02 ,  C09D201/06 ,  C08L61/20 ,  Y10T428/31551 ,  Y10T428/31565 ,  Y10T428/31573 ,  Y10T428/31786 ,  Y10T428/31794 ,  Y10T428/31797 ,  Y10T428/31855 ,  Y10T428/31909 ,  Y10T428/31942

摘要： Flexible, aminoplast-curable film-forming compositions and multi-component composite coating compositions comprising at least one pigmented or colored base coat and at least one transparent clear coat are disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a clear coat to the base coat. Both the colored base coat and the clear coat are flexible, curable film-forming compositions having an aminoplast crosslinking agent, and the base coat and optionally the clear coat has carbamate functional polymers. The flexible, multi-component composite coating compositions provide improved durability, water spotting resistance, and/or acid etch resistance, making the composite coatings particularly useful for plastic automotive parts.

摘要翻译： 公开了柔性的氨基塑料固化成膜组合物和包含至少一种着色或着色底涂层和至少一个透明透明涂层的多组分复合涂料组合物。 首先将着色或着色的底涂层施加到基底上，然后向基底涂层施加透明涂层。 着色底涂层和透明涂层均为具有氨基塑料交联剂的柔性可固化成膜组合物，底涂层和任选的透明涂层具有氨基甲酸酯官能聚合物。 柔性多组分复合涂料组合物提供改进的耐久性，耐水渍性和/或耐酸蚀性，使复合涂料对塑料汽车部件特别有用。

公开(公告)号：US06451930B1

公开(公告)日：2002-09-17

申请号：US09524830

申请日：2000-03-14

申请人： John W. Burgman ,  David C. Martin ,  Soner Kilic ,  Jane N. Valenta

发明人： John W. Burgman ,  David C. Martin ,  Soner Kilic ,  Jane N. Valenta

IPC分类号： C08G7718

CPC分类号： C08G18/6295 ,  C09D175/04 ,  C09D201/025 ,  C09D201/10 ,  C08L2666/16

摘要： A film-forming composition, typically a topcoat, having improved adhesion to certain commercially available adhesives. The composition includes a curable film-forming polymer, typically an acrylic and/or a polyester polymer, with carbamate and/or urea groups. The composition further includes a material containing one or more hydrolyzable silyl groups. The hydrolyzable silyl group-containing material optionally can be a polymeric or oligomeric. Also disclosed are a method of applying the above-described film-forming composition to a substrate and the coated article prepared by such a method.

摘要翻译： 一种成膜组合物，通常为顶涂层，具有改进的粘合性。 该组合物包括具有氨基甲酸酯和/或脲基团的可固化成膜聚合物，通常为丙烯酸和/或聚酯聚合物。 组合物还包含含有一个或多个可水解甲硅烷基的材料。 可水解的含甲硅烷基的材料任选地可以是聚合的或低聚的。 还公开了将上述成膜组合物施用于通过这种方法制备的基材和涂布制品的方法。

公开(公告)号：US06268055B1

公开(公告)日：2001-07-31

申请号：US09187698

申请日：1998-11-06

申请人： Robert W. Walters ,  Cletus N. Welch ,  John W. Burgman ,  Debra L. Singer ,  Shanti Swarup

发明人： Robert W. Walters ,  Cletus N. Welch ,  John W. Burgman ,  Debra L. Singer ,  Shanti Swarup

IPC分类号： C08G5942

CPC分类号： C09D163/00 ,  G02B5/23 ,  Y10T428/31511 ,  C08L2666/28

摘要： Described are photochromic epoxy resin coatings that meet commercially acceptable “cosmetic” standards for optical coatings. Also described are articles having such coatings. The coatings exhibit a Fischer microhardness of from 50 to 150 Newtons per mm2 and desirable photochromic properties, i.e., the formation of darker activated colors and faster rates of photochromic activation and fade when irradiated with ultraviolet light.

摘要翻译： 描述了满足商业上可接受的用于光学涂层的“化妆品”标准的光致变色环氧树脂涂料。 还描述了具有这种涂层的制品。 涂层表现出每毫米50至150牛顿的菲舍尔显微硬度和所需的光致变色性质，即，当用紫外线照射时，形成更暗的活化颜色和更快的光致变色激活速率和褪色。

公开(公告)号：US5965670A

公开(公告)日：1999-10-12

申请号：US72472

申请日：1998-05-04

申请人： George W. Mauer ,  William E. Michael ,  John W. Burgman ,  Leigh-Ann Humbert

发明人： George W. Mauer ,  William E. Michael ,  John W. Burgman ,  Leigh-Ann Humbert

IPC分类号： C08L33/14 ,  C08K5/3492 ,  C08L61/20 ,  C08L61/32 ,  C09D133/00 ,  C09D133/06 ,  C09D133/14 ,  C09D161/20 ,  C08G79/02

CPC分类号： C09D133/066 ,  C08L61/20 ,  C08L61/32

摘要： Curable film-forming compositions comprising acrylic polyols, aminoplast and carbamoyl triazines are disclosed. The compositions are useful as clear coats in composite color-plus-clear coatings.

摘要翻译： 公开了包含丙烯酸多元醇，氨基塑料和氨基甲酰基三嗪的可固化成膜组合物。 该组合物可用作复合颜色 - 透明涂层中的透明涂层。

公开(公告)号：US06592999B1

公开(公告)日：2003-07-15

申请号：US09919200

申请日：2001-07-31

申请人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

发明人： Lawrence G. Anderson ,  John W. Burgman ,  Karen A. Morow ,  Richard J. Sadvary ,  Shiryn Tyebjee ,  Dennis A. Simpson ,  Thomas R. Hockswender

IPC分类号： B32B904

CPC分类号： B05D7/57 ,  B05D7/574 ,  C08J5/12 ,  C08K3/38 ,  C08K5/55 ,  C09D7/60 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31935

摘要： The present invention provides an improved multi-layer composite of two or more polymeric layers at least one of which is formed from a thermosetting composition. The composite includes at least a first polymeric layer formed on a substrate and a second polymeric layer over the first polymeric layer, wherein in the absence of a boron-containing compound, the first and second polymeric layers have poor interlayer adhesion. The improvement resides in the inclusion of at least one boron-containing compound in one or both of the first and second polymeric layers in an amount sufficient to improve the interlayer adhesion between the first and second polymeric layers. Also provided is an improved curable coating composition used to form a multi-layer composite coating of two or more cured coating layers, at least one of which is formed from the thermosetting composition. Related methods and coated substrates are also provided.

公开(公告)号：US6111001A

公开(公告)日：2000-08-29

申请号：US198837

申请日：1998-11-24

申请人： Steven V. Barancyk ,  Michael A. Mayo ,  Daniel E. Rardon ,  John W. Burgman ,  Robert L. Auger

发明人： Steven V. Barancyk ,  Michael A. Mayo ,  Daniel E. Rardon ,  John W. Burgman ,  Robert L. Auger

IPC分类号： C08L101/02 ,  C08K5/205 ,  C08K5/21 ,  C08L61/20 ,  C08L101/00 ,  C09D5/04 ,  C09D201/02

CPC分类号： C09D201/025 ,  C09D5/04

摘要： Disclosed are compositions comprised of (a)a polymer containing pendant and/or functional groups selected from the group consisting of carbamate, urethane and/or amide functional groups; and (b) a rheology modifier comprising the reaction product of an amine and an isocyanate; and, optionally, a polymer which is different from the polymer (a) which contains carbamate, urethane and/or amide functional groups. Also disclosed are curable compositions comprised of the compositions described above which further comprise (c) a curing agent having functional groups reactive with the functional groups of the polymer (a). The curable compositions are useful for a variety of applications such as adhesives, sealants and surface coatings where the presence of a carbamate, urethane and/or amide functional polymer in conjunction with the rheology modifier provides improved thixotropy and superior sag resistance.

摘要翻译： 公开了包含（a）含有选自氨基甲酸酯，氨基甲酸酯和/或酰胺官能团的侧基和/或官能团的聚合物的组合物; 和（b）包含胺和异氰酸酯的反应产物的流变改性剂; 和任选的不同于含有氨基甲酸酯，氨基甲酸酯和/或酰胺官能团的聚合物（a）的聚合物。 还公开了包含上述组合物的可固化组合物，其还包含（c）具有与聚合物（a）的官能团反应的官能团的固化剂。 可固化组合物可用于各种应用，例如粘合剂，密封剂和表面涂层，其中氨基甲酸酯，氨基甲酸酯和/或酰胺官能聚合物与流变改性剂的结合提供了改善的触变性和优异的抗流挂性。

公开(公告)号：US5969058A

公开(公告)日：1999-10-19

申请号：US997284

申请日：1997-12-23

申请人： Lawrence G. Anderson ,  Gerald W. Gruber ,  Kurt A. Humbert ,  Gregory J. McCollum ,  Karen A. Barkac ,  John W. Burgman ,  Robert D. Lippert

发明人： Lawrence G. Anderson ,  Gerald W. Gruber ,  Kurt A. Humbert ,  Gregory J. McCollum ,  Karen A. Barkac ,  John W. Burgman ,  Robert D. Lippert

IPC分类号： C08G59/42 ,  C08G59/68 ,  C09D133/06 ,  C09D163/00 ,  C08F283/00

CPC分类号： C09D133/068 ,  C08G59/42 ,  C08G59/68 ,  C09D163/00

摘要： Curable film-forming compositions containing epoxy functional copolymers, polycarboxylic acid crosslinking agents, and triaryltin compound having the chemical structure of (Ar).sub.3 SnOR wherein the aryl groups are the same or different and at least one aryl group is substituted with at least one atom or group selected from the group consisting of carbon, nitrogen, oxygen, sulfur, phosphorous, silicon and halogen and R is selected from the group consisting of hydrogen, alkyl, and acyl groups are disclosed. The compositions do not release benzene during cure. The compositions may be powder or liquid and are useful as clear coats, particularly in a color-plus-clear composite coating system.

摘要翻译： 含有环氧官能共聚物，多元羧酸交联剂和具有（Ar）3SnOR化学结构的三芳基锡化合物的可固化成膜组合物，其中芳基相同或不同，至少一个芳基被至少一个原子或 选自碳，氮，氧，硫，磷，硅和卤素的基团，R选自氢，烷基和酰基。 组合物在固化过程中不释放苯。 组合物可以是粉末或液体，并且可用作透明涂层，特别是在彩色 - 透明复合涂层体系中。