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    Copolymer of monocarboxylic acid with at least 8C and unsaturated dicarboxylic ester
    1.
    发明授权
    Copolymer of monocarboxylic acid with at least 8C and unsaturated dicarboxylic ester 失效
    一元羧酸与至少8C的共聚物和不饱和二羧酸酯

    公开(公告)号：US06284855B1

    公开(公告)日：2001-09-04

    申请号：US09537540

    申请日：2000-03-29

    申请人： Karl F. Schimmel ,  Suryya K. Das ,  Soner Kilic

    发明人： Karl F. Schimmel ,  Suryya K. Das ,  Soner Kilic

    IPC分类号： C08F814

    CPC分类号： C08F8/14 ,  C08F2810/20 ,  C08F2810/30

    摘要： A copolymer having utility in coating compositions comprises the addition polymerization product of an alpha-olefin monocarboxylic acid having at least 8 carbon atoms (articularly undecylenic acid) and a mono- or di-ester of an unsaturated dicarboxylic acid or anhydride (e.g., dialkyl maleate). The copolymer may be provided with hydroxy functionality by reacting the carboxylic acid functionality with an epoxy compound to permit use in curable coatings. Alternatively the copolymer may be base neutralized to serve as a surfactant in aqueous dispersion polymerization.

    摘要翻译： 一种在涂料组合物中有用的共聚物包括具有至少8个碳原子的α-烯烃单羧酸（主要是十一烯酸）和不饱和二羧酸或酸酐的单酯或二酯的加成聚合产物（例如马来酸二烷基酯 ）。 可以通过使羧酸官能团与环氧化合物反应以使其在可固化涂层中使用来使共聚物具有羟基官能度。 或者，共聚物可以碱中和以用作水分散体聚合中的表面活性剂。

    Hydroxy-functional copolymer by reacting epoxy with .gtoreq.C8 monocarboxylic acid/dicarboxylic ester copolymer
    2.
    发明授权
    Hydroxy-functional copolymer by reacting epoxy with .gtoreq.C8 monocarboxylic acid/dicarboxylic ester copolymer 失效
    羟基官能共聚物通过使环氧与> / = C8一元羧酸/二羧酸酯共聚物反应

    公开(公告)号：US6090894A

    公开(公告)日：2000-07-18

    申请号：US215945

    申请日：1998-12-18

    申请人： Karl F. Schimmel ,  Suryya K. Das ,  Soner Kilic

    发明人： Karl F. Schimmel ,  Suryya K. Das ,  Soner Kilic

    IPC分类号： C08F8/14 ,  C08F20/04 ,  C08L33/02

    CPC分类号： C08F8/14 ,  C08F2810/20 ,  C08F2810/30

    摘要： A copolymer having utility in coating compositions comprises the addition polymerization product of an alpha-olefin monocarboxylic acid having at least 8 carbon atoms (particularly undecylenic acid) and a mono- or di-ester of an unsaturated dicarboxylic acid or anhydride (e.g., dialkyl maleat). The copolymer may be provided with hydroxy functionality by reacting the carboxylic acid functionality with an epoxy compound to permit use in curable coatings. Alternatively the copolymer may be base neutralized to serve as a surfactant in aqueous dispersion polymerization.

    摘要翻译： 用于涂料组合物的共聚物包括具有至少8个碳原子的α-烯烃单羧酸（特别是十一碳烯酸）和不饱和二羧酸或酸酐的单酯或二酯的加成聚合产物（例如，二烷基马来酸 ）。 可以通过使羧酸官能团与环氧化合物反应以使其在可固化涂层中使用来使共聚物具有羟基官能度。 或者，共聚物可以碱中和以用作水性分散体聚合中的表面活性剂。

    Pigment dispersions containing dispersants prepared by controlled radical polymerization
    5.
    发明授权
    Pigment dispersions containing dispersants prepared by controlled radical polymerization 失效
    含有通过控制自由基聚合制备的分散剂的颜料分散体

    公开(公告)号：US06326420B1

    公开(公告)日：2001-12-04

    申请号：US09464947

    申请日：1999-12-16

    申请人： Kevin C. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Karl F. Schimmel

    发明人： Kevin C. Olson ,  Simion Coca ,  James B. O'Dwyer ,  Karl F. Schimmel

    IPC分类号： C08L300

    CPC分类号： C09B67/009 ,  C09D17/001

    摘要： A pigment dispersion which includes a pigment, an aqueous carrier and a pigment dispersant. The pigment dispersant is prepared by controlled radical polymerization initiated in the presence of a monomeric initiator having at least two radically transferable groups. The pigment dispersant has at least one of the following polymer chain structures: &phgr;-[(G)p—(E)s—T]z and &phgr;-[(E)3—(G)p—T]z where G is a hydrophobic residue of at least one radically polymerizable ethylenically unsaturated monomer; E is a hydrophilic residue of at least one radically polymerizable ethylenically unsaturated monomer; &phgr; is a residue of or derived from the initiator, and is free of the radically transferable group; T is or is derived from the radically transferable group of the initiator; z is 2 to 10; p and s are at least one and are selected such that the pigment dispersant has a number average molecular weight of at least 500.

    摘要翻译： 颜料分散体，其包含颜料，水性载体和颜料分散剂。 在具有至少两个可自由基转移基团的单体引发剂的存在下引发的受控自由基聚合来制备颜料分散剂。 颜料分散剂具有以下聚合物链结构中的至少一种：其中G是至少一个可自由基聚合的烯属不饱和单体的疏水残基; E是至少一种可自由基聚合的烯属不饱和单体的亲水性残基; phi是引发剂的残基或衍生自起始物，不含可自由基转移基团; T衍生自引发剂的可自由转移基团; z为2〜10; p和s是至少一个，并且被选择为使得颜料分散剂的数均分子量为至少500。

    Block copolymers
    6.
    发明授权
    Block copolymers 失效
    嵌段共聚物

    公开(公告)号：US06288173B1

    公开(公告)日：2001-09-11

    申请号：US09325227

    申请日：1999-06-03

    申请人： Karl F. Schimmel ,  Karen A. Barkac ,  Kurt A. Humbert ,  Jonathan D. Goetz ,  James B. O'Dwyer

    发明人： Karl F. Schimmel ,  Karen A. Barkac ,  Kurt A. Humbert ,  Jonathan D. Goetz ,  James B. O'Dwyer

    IPC分类号： C08F29700

    CPC分类号： C08L53/00 ,  C08F293/005 ,  C09D153/00

    摘要： Block copolymers containing at least two blocks are provided and comprise: (a) a first block containing residues of at least one first ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., 2-ethylhexyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer, e.g., hydroxypropyl methacrylate; and (b) a second block containing residues of at least one second ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., iso-butyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer. The calculated Tg of the second monomer of the block copolymer is at least 20° C. greater than the calculated Tg of the first monomer.

    摘要翻译： 提供含有至少两个嵌段的嵌段共聚物，其包含：（a）含有至少一种不含羟基官能团的至少一种第一烯属不饱和自由基可聚合单体的残基的第一嵌段，例如甲基丙烯酸2-乙基己基酯和少量的 至少一种羟基官能的烯属不饱和自由基聚合单体，例如甲基丙烯酸羟丙酯; 和（b）含有至少一种不含羟基官能团的第二烯属不饱和自由基可聚合单体残基的第二嵌段，例如甲基丙烯酸异丁酯和少量至少一种羟基官能烯属不饱和自由基聚合单体。 嵌段共聚物的第二单体的计算的Tg比第一单体的计算的Tg大至少20℃。

    Polyurethane polyanhydride oligomers and method of preparation
    8.
    发明授权
    Polyurethane polyanhydride oligomers and method of preparation 失效
    聚氨酯聚酐低聚物及其制备方法

    公开(公告)号：US5182355A

    公开(公告)日：1993-01-26

    申请号：US829706

    申请日：1991-09-30

    申请人： Jonathan T. Martz ,  Karl F. Schimmel ,  Padmanabhan Sundararaman ,  David N. Walters

    发明人： Jonathan T. Martz ,  Karl F. Schimmel ,  Padmanabhan Sundararaman ,  David N. Walters

    IPC分类号： C08G18/67 ,  C08G18/83

    CPC分类号： C08G18/831 ,  C08G18/671 ,  Y10S525/939

    摘要： A polyurethane polyanhydride oligomer is disclosed as well as a process for its preparation. The process involves the following steps:(a) reacting a hydroxyl functional 2,4-dienoate ester with a polyisocyanate under conditions sufficient to react essentially all of the isocyanate groups to form a polyurethane polyene; and(b) reacting by Diels Alder addition the unsaturated double bonds of the polyurethane polyene with an unsaturated polycarboxylic acid anhydride containing material. Also disclosed is a curable composition containing hydroxyl functional material and the aforedescribed polyurethane polyanhydride oligomer.

    摘要翻译： 公开了聚氨酯聚酐低聚物及其制备方法。 该方法包括以下步骤：（a）使羟基官能的2,4-二烯酸酯与多异氰酸酯在足以使基本上所有异氰酸酯基团反应形成聚氨酯多烯的条件下反应; 和（b）由Diels Alder反应，加入聚氨酯多烯的不饱和双键与含不饱和多元羧酸酐的材料。 还公开了含有羟基官能材料和上述聚氨酯聚酐低聚物的可固化组合物。