摘要:
A new synthetic porous crystalline material, designated EMM-1, is disclosed having, in its calcined form, the X-ray diffraction pattern of Table 2 above. Also disclosed are methods of making EMM-1 in the presence of HF using various organic nitrogen compounds as directing agents. Aluminum-containing EMM-1 can be produced either by inclusion of Al in the synthesis, or by incorporation of B or Ga in the synthesis, followed by post treatment with aluminum nitrate or other sources of Al. EMM-1 is useful as an acid catalyst and as an adsorbent.
摘要:
The present invention includes a microporous or mesoporous composition of matter in which the composition is formed continuously or semi-continuously in a heated reactor zone, including a rotary calciner or a rotary screw as a means for conveying the synthesis mixture, at a temperature between 200° C. and 500° C. with a residence time less than 24 hours. The reagents are solid and liquid reagents in which the solid reagents have a weight percent between 45% and 98% of the total reagents.The invention also includes a continuous or semi-continuous process for the hydrothermal manufacture of the microporous or mesoporous composition.
摘要:
This invention relates to a novel synthetic porous crystalline molecular sieve material, MCM-65, to a reaction mixture and method for its preparation, and to use of the MCM-65 in catalytic conversion of organic compounds. The crystalline material exhibits a distinctive X-ray diffraction pattern as shown in Table 1.
摘要:
In a process for synthesizing a porous crystalline material, a mixture capable of forming said material is prepared wherein the mixture comprises sources of water, an oxide of a tetravalent element Y, preferably silicon, an oxide of a trivalent element X, wherein X is selected from the group consisting of aluminum, boron, gallium, iron, and indium, fluoride ions, and an organonitrogen cation RNm+ capable of directing the synthesis of said material, wherein the molar ratio of fluoride ions to organonitrogen cations RNm+ in said mixture is greater than 1.15 m but less than 2.5 m. The mixture is maintained under crystallization conditions until crystals of said material are formed and the resultant crystalline material is recovered.
摘要翻译:在合成多孔结晶材料的方法中,制备能够形成所述材料的混合物,其中所述混合物包含水源,四价元素Y的氧化物,优选硅,三价元素X的氧化物,其中X被选择 从由铝,硼,镓,铁和铟组成的组,氟离子和能够引导所述材料的合成的有机氮阳离子RN m +,其中氟离子与有机氮阳离子的摩尔比RN