Synthetic porous crystalline material, EMM-1, its synthesis and use
    1.
    发明授权
    Synthetic porous crystalline material, EMM-1, its synthesis and use 失效
    合成多孔结晶材料,EMM-1,其合成与应用

    公开(公告)号:US06787124B2

    公开(公告)日:2004-09-07

    申请号:US10367295

    申请日:2003-02-14

    IPC分类号: C01B3948

    摘要: A new synthetic porous crystalline material, designated EMM-1, is disclosed having, in its calcined form, the X-ray diffraction pattern of Table 2 above. Also disclosed are methods of making EMM-1 in the presence of HF using various organic nitrogen compounds as directing agents. Aluminum-containing EMM-1 can be produced either by inclusion of Al in the synthesis, or by incorporation of B or Ga in the synthesis, followed by post treatment with aluminum nitrate or other sources of Al. EMM-1 is useful as an acid catalyst and as an adsorbent.

    摘要翻译: 公开了一种名为EMM-1的新的合成多孔结晶材料,其以其煅烧形式具有上述表2的X射线衍射图。 还公开了使用各种有机氮化合物作为引导剂在HF存在下制备EMM-1的方法。 含铝的EMM-1可以通过在合成中包含Al或通过在合成中并入B或Ga,然后用硝酸铝或其它Al源进行后处理来制备。 EMM-1可用作酸催化剂和吸附剂。

    Synthesis of porous crystalline materials in fluoride media
    4.
    发明授权
    Synthesis of porous crystalline materials in fluoride media 失效
    氟化物介质中多孔结晶材料的合成

    公开(公告)号:US06723300B2

    公开(公告)日:2004-04-20

    申请号:US10367292

    申请日:2003-02-14

    IPC分类号: C01B3942

    摘要: In a process for synthesizing a porous crystalline material, a mixture capable of forming said material is prepared wherein the mixture comprises sources of water, an oxide of a tetravalent element Y, preferably silicon, an oxide of a trivalent element X, wherein X is selected from the group consisting of aluminum, boron, gallium, iron, and indium, fluoride ions, and an organonitrogen cation RNm+ capable of directing the synthesis of said material, wherein the molar ratio of fluoride ions to organonitrogen cations RNm+ in said mixture is greater than 1.15 m but less than 2.5 m. The mixture is maintained under crystallization conditions until crystals of said material are formed and the resultant crystalline material is recovered.

    摘要翻译: 在合成多孔结晶材料的方法中,制备能够形成所述材料的混合物,其中所述混合物包含水源,四价元素Y的氧化物,优选硅,三价元素X的氧化物,其中X被选择 从由铝,硼,镓,铁和铟组成的组,氟离子和能够引导所述材料的合成的有机氮阳离子RN m +,其中氟离子与有机氮阳离子的摩尔比RN