公开(公告)号：US5525684A

公开(公告)日：1996-06-11

申请号：US376146

申请日：1995-01-20

申请人： Tomoyuki Kawabata ,  Shigeru Iimuro ,  Teruo Yuasa

发明人： Tomoyuki Kawabata ,  Shigeru Iimuro ,  Teruo Yuasa

IPC分类号： C08L61/06 ,  C08L63/00 ,  C08L65/00 ,  C08L61/04 ,  C08L61/10 ,  C08L63/02

CPC分类号： C08L65/00 ,  C08L63/00 ,  C08L61/06

摘要： A phenolic resin composition comprises a mixture of 100 parts by weight of a phenol aralkyl resin and 5 to 60 parts by weight of a novolak type phenolic resin having a content of binuclear components of not more than 10% by area, and a content of trinuclear components of not less than 50% by area and a sum content of tri- and tetra-nuclear components of 75% by area based on the total novolak phenolic resin except for the binuclear components, and an epoxy-cured product obtained by curing an epoxy resin while using the phenolic resin composition as set forth in claim 1 as a curing agent. The phenolic resin composition has a low viscosity and, when it is used as a curing agent for epoxy resins, the resulting epoxy-cured product has a low water absorption rate, is excellent in resistance to moisture and has a high glass transition temperature as compared with the cured product obtained using a novolak type phenolic resin as a curing agent.

摘要翻译： 酚醛树脂组合物包含100重量份苯酚芳烷基树脂和5至60重量份具有不超过10面积％的双核成分含量的酚醛清漆型酚醛树脂和三核含量的混合物 基于除双核成分以外的总酚醛清漆酚醛树脂的面积为面积的不小于50％的三组分和四核组分的总含量为75％的环氧树脂固化产物，以及通过固化环氧树脂 树脂，同时使用如权利要求1所述的酚醛树脂组合物作为固化剂。 酚醛树脂组合物具有低粘度，当用作环氧树脂的固化剂时，得到的环氧固化产物的吸水率低，耐湿性优异，玻璃化转变温度高 使用酚醛清漆型酚醛树脂获得的固化产物作为固化剂。

公开(公告)号：US4374272A

公开(公告)日：1983-02-15

申请号：US92175

申请日：1979-11-07

申请人： Teruo Yuasa ,  Noboru Yamazaki ,  Yoshio Morimoto

发明人： Teruo Yuasa ,  Noboru Yamazaki ,  Yoshio Morimoto

IPC分类号： C07C215/74 ,  B01J27/00 ,  B01J31/00 ,  C07C20060101 ,  C07C67/00 ,  C07C213/00 ,  C07C213/08 ,  C07C219/34 ,  C07C225/22 ,  C07C255/59 ,  C07C87/64

CPC分类号： C07C213/08

摘要： A process for preparing 2-(4'-hydroxyaryl)-2-(4'-aminoaryl)-propanes of the general formula ##STR1## wherein R represents a hydrogen or halogen atom or an alkyl, aryl, nitro, nitrile, acyl, acyloxy or amino group, R.sup.1 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and R.sup.2 and R.sup.3, independently from each other, represent a hydrogen or halogen atom, a nitro group or an alkyl group having 1 to 4 carbon atoms,which comprises reacting (A) at least one isopropenyl phenol compound selected from the group consisting of isopropenyl phenol derivatives of the general formula ##STR2## wherein R is as defined, and di- to eicosa-mers of said isopropenyl phenol derivatives with (B) an aromatic amine of the general formula ##STR3## wherein R.sup.1 , R.sup.2 and R.sup.3 are as defined, in the presence of 0.00001 to 0.008 mole, per mole of said isopropenylphenol compound (A) calculated as a monomer, of a acid catalyst and in the presence or absence of a phenolic solvent.

摘要翻译： 制备通式为（III）的2-（4'-羟基芳基）-2-（4'-氨基芳基） - 丙烷的方法，其中R表示氢或卤素原子或烷基，芳基，硝基，腈 ，酰基，酰氧基或氨基，R 1表示氢原子或碳原子数1〜4的烷基，R 2和R 3彼此独立地表示氢或卤素原子，硝基或具有1个 包括使（A）至少一种选自下列通式的异丙烯基苯酚衍生物（I）中的R定义的异丙烯基苯酚化合物与（A）至少一种异丙烯基苯酚化合物的反应，和 所述异丙烯基苯酚衍生物与（B）通式为其中R 1，R 2和R 3如所定义的芳族胺在0.00001至0.008摩尔存在下，每摩尔所述异丙烯基苯酚化合物（A）计算得到的 作为单体，由酸催化剂和酚类溶剂存在或不存在。

公开(公告)号：US5618984A

公开(公告)日：1997-04-08

申请号：US490507

申请日：1995-06-14

申请人： Tomoyuki Kawabata ,  Teruo Yuasa ,  Shigeru Iimuro

发明人： Tomoyuki Kawabata ,  Teruo Yuasa ,  Shigeru Iimuro

IPC分类号： C08G61/02 ,  C08L63/00 ,  C07C39/21 ,  C07C37/055

CPC分类号： C08G61/02 ,  C08L63/00

摘要： An allyletherificated phenol aralkyl resin is obtained through the reaction of a phenol aralkyl resin with an allyl halide in the presence of a base in an organic solvent at room temperature to 100.degree. C. and changed into an allylated phenol aralkyl resin at 160.degree.-250.degree. C. through Claisen rearrangement. The two resins are low in melt viscosity. Epoxy resin compositions containing the allylated phenol aralkyl resin as the curing agent give cured products being excellent in heat and moisture resistances.

摘要翻译： 在碱存在下，在有机溶剂中，在室温至100℃下，通过苯酚芳烷基树脂与烯丙基卤反应获得烯丙醚化的酚芳烷基树脂，并在160-250℃下变成烯丙基化苯酚芳烷基树脂 DEGC通过Claisen重排。 两种树脂的熔融粘度低。 含有烯丙基化酚芳烷基树脂作为固化剂的环氧树脂组合物得到耐热和耐湿性优异的固化产物。

公开(公告)号：US4387210A

公开(公告)日：1983-06-07

申请号：US333358

申请日：1981-12-22

申请人： Nobukatsu Katoh ,  Yoshio Morimoto ,  Takashi Kataoka ,  Teruo Yuasa

发明人： Nobukatsu Katoh ,  Yoshio Morimoto ,  Takashi Kataoka ,  Teruo Yuasa

IPC分类号： C08G69/44

CPC分类号： C08G69/44

摘要： An aromatic polyester amide is produced by reacting hydroxyphenyl-aminophenyl-propane with aromatic dicarboxylic acid dihalide in the presence of an inert organic solvent, and bringing the organic solvent phase containing the mixture of the reaction products of the above reaction into contact with an aqueous phase containing an acid-acceptor, whereby completing polycondensation reaction. In order to control the dissolution of water into the organic solvent phase while maintaining an adequate level of miscibility between the organic solvent phase and the aqueous phase, a neutral salt of inorganic electrolyte, such as sodium chloride, is added to the aqueous phase containing the acid-acceptor.

摘要翻译： 通过羟基苯基 - 氨基苯基 - 丙烷与芳族二羧酸二卤化物在惰性有机溶剂的存在下反应制备芳族聚酯酰胺，并使含有上述反应产物的混合物的有机溶剂相与水相接触 含有酸受体，从而完成缩聚反应。 为了控制水在有机溶剂相中的溶解，同时保持有机溶剂相和水相之间足够的混溶水平，将无机电解质如氯化钠的中性盐加入到含有 酸受体。

公开(公告)号：US4298720A

公开(公告)日：1981-11-03

申请号：US59758

申请日：1979-07-23

申请人： Noboru Yamazaki ,  Tsutomu Takase ,  Yoshio Morimoto ,  Teruo Yuasa

发明人： Noboru Yamazaki ,  Tsutomu Takase ,  Yoshio Morimoto ,  Teruo Yuasa

IPC分类号： C08F22/40 ,  C08L79/08 ,  H01B3/30

CPC分类号： C08F22/40 ,  C08L79/085 ,  H01B3/306 ,  Y10T428/31721

摘要： Disclosed is a heat-resistant and fast-curing thermosetting resin composition suitably for insulating materials and comprising (a) a bismaleimide and/or a polymaleimide compound and (b) at least one compound selected from alkenylphenol derivatives, linear dimers thereof, and polymers thereof. In addition to components (a) and (b), this resin composition can contain (c) a polymerizable unsaturated compound.

摘要翻译： 公开了一种适用于绝缘材料的耐热和快速固化的热固性树脂组合物，其包含（a）双马来酰亚胺和/或聚马来酰亚胺化合物和（b）至少一种选自烯基酚衍生物，其线性二聚体及其聚合物的化合物 。 除了组分（a）和（b）之外，该树脂组合物可以含有（c）可聚合的不饱和化合物。

公开(公告)号：US6127511A

公开(公告)日：2000-10-03

申请号：US204552

申请日：1998-12-03

申请人： Tomoyuki Kawabata ,  Yuzo Ono ,  Teruo Yuasa ,  Yukio Fukui

发明人： Tomoyuki Kawabata ,  Yuzo Ono ,  Teruo Yuasa ,  Yukio Fukui

IPC分类号： C08G65/38

CPC分类号： C08G65/38

摘要： A preparation process of phenol aralkyl resin from phenol compound and aralkyl compound by controlling the temperature of reaction mass in the range of 70 to 240.degree. C. and simultaneously controlling the temperature of vapor phase potion and vapor-liquid interface portion of manufacturing equipment so as to keep the wall surface of the vapor phase portion and vapor-liquid interface portion in a wet state. The invention can prevent scale adhesion to the interior of manufacturing equipment, remarkably reduce the number of washing and scale removing procedures on the manufacturing equipment, and enable efficient manufacture of phenol aralkyl resin. When the phenol aralkyl resin obtained is used for a molding material, molded articles having excellent heat resistance and high reliability can be provided.

摘要翻译： 通过将反应物质的温度控制在70〜240℃的范围内，由苯酚化合物和芳烷基化合物制备苯酚芳烷基树脂，同时控制制造设备的气相药液和气 - 液界面部分的温度，以便 以保持气相部分和汽液界面部分的壁表面处于湿润状态。 本发明能够防止水垢附着在制造装置的内部，显着地减少了制造装置的洗涤和除垢程序，能够高效地制造苯酚芳烷基树脂。 得到的苯酚芳烷基树脂用于成型材料时，可以提供耐热性优异，可靠性高的成型品。

公开(公告)号：US4245128A

公开(公告)日：1981-01-13

申请号：US62810

申请日：1979-08-01

申请人： Nobukatu Kato ,  Tsutomu Takase ,  Yoshio Morimoto ,  Teruo Yuasa ,  Minoru Hattori

发明人： Nobukatu Kato ,  Tsutomu Takase ,  Yoshio Morimoto ,  Teruo Yuasa ,  Minoru Hattori

IPC分类号： C07C39/04 ,  B01J23/00 ,  B01J31/00 ,  C07B61/00 ,  C07C27/00 ,  C07C37/52 ,  C07C39/06 ,  C07C39/19 ,  C07C39/205 ,  C07C39/23 ,  C07C67/00

CPC分类号： C07C37/52 ,  C07C2101/14 ,  Y02P20/52

摘要： A novel process for producing alkenyl phenols, which comprises continuously feeding a dihydroxydiphenyl alkane such as 2,2-(4,4'-dihydroxydiphenyl)propane, 2,2-(4,4'-dihydroxy-3,3'-dimethyldiphenyl)propane, 2,2-(4,4'-dihydroxydiphenyl)butane, 2,2-(4,4'-dihydroxydiphenyl)-4-methylpentane, 1,1,1-(4,4'-dihydroxytriphenyl)ethane and 1,1-(4,4'-dihydroxydiphenyl)cyclohexane into a high-boiling inert organic reaction medium such as an alkylnaphthalene containing a basic catalyst and heated at 150.degree. to 250.degree. C. under 10 to 100 mmHg while maintaining the concentration of the dihydroxydiphenyl alkane in the reaction medium at not more than 30% by weight, thereby cleaving it in the reaction medium; and continuously distilling off the cleavage product out of the reaction system and recovering it. This process can afford the corresponding highly pure alkenyl phenol as a monomer and/or its polymer almost quantitatively.

摘要翻译： 一种制备烯基酚的新方法，其包括连续进料二羟基二苯基烷烃如2,2-（4,4'-二羟基二苯基）丙烷，2,2-（4,4'-二羟基-3,3'-二甲基二苯基） 丙烷，2,2-（4,4'-二羟基二苯基）丁烷，2,2-（4,4'-二羟基二苯基）-4-甲基戊烷，1,1,1-（4,4'-二羟基三苯基）乙烷和1 ，1-（4,4'-二羟基二苯基）环己烷加入到高沸点惰性有机反应介质如含有碱性催化剂的烷基萘中，并在150-250℃下加热至10至100mmHg，同时保持 二羟基二苯基烷烃在反应介质中不超过30重量％，从而在反应介质中裂解; 并将裂解产物连续蒸馏出反应体系并回收。 该方法可以几乎定量地提供作为单体和/或其聚合物的相应的高纯度烯基苯酚。

公开(公告)号：US4242528A

公开(公告)日：1980-12-30

申请号：US62811

申请日：1979-08-01

申请人： Nobukatu Kato ,  Tsutomu Takase ,  Yoshio Morimoto ,  Teruo Yuasa ,  Minoru Hattori

发明人： Nobukatu Kato ,  Tsutomu Takase ,  Yoshio Morimoto ,  Teruo Yuasa ,  Minoru Hattori

IPC分类号： C07C27/00 ,  C07C37/52 ,  C07C39/19 ,  C07C67/00 ,  C07C39/06

CPC分类号： C07C37/52

摘要： A novel process for producing isopropenyl phenol such as p-isopropenyl phenol which comprises continuously feeding oligomers of isopropenyl phenol having a degree of polymerization of 2 to 5 into a high-boiling inert organic reaction medium such as an alkylnaphthalene heated at 150.degree. to 250.degree. C. under a pressure of 10 to 100 mmHg while maintaining the concentration of the oligomers in the reaction medium at not more than 30% by weight, thereby thermally decomposing the oligomers in the reaction medium; and continuously distilling off the resulting isopropenyl phenol out of the reaction system and recovering it. The process almost quantitatively gives isopropenyl phenol having reduced contents of impurities.

摘要翻译： 一种制备异丙烯基苯如对异丙烯基苯酚的新方法，其包括将聚合度为2至5的异丙烯基苯酚的低聚物连续加入到高沸点惰性有机反应介质如加热至150°至250°的烷基萘中 在10至100mmHg的压力下，同时将反应介质中的低聚物的浓度保持在不超过30重量％，从而热分解反应介质中的低聚物; 并将所得的异丙烯基苯酚从反应体系中连续蒸馏除去。 该方法几乎定量地得到具有降低的杂质含量的异丙烯基苯酚。

公开(公告)号：US06642345B2

公开(公告)日：2003-11-04

申请号：US10032476

申请日：2002-01-02

申请人： Teruo Yuasa ,  Hiroaki Narisawa ,  Masahiro Kaneko

发明人： Teruo Yuasa ,  Hiroaki Narisawa ,  Masahiro Kaneko

IPC分类号： C08G1404

CPC分类号： C08G8/28 ,  C08L61/14

摘要： Preparation process for a novolak aralkyl resin having excellent heat resistance and curing property by reacting 0.4 to 0.8 mol of an aralkyl compound based on one mol of the low molecular weight novolak containing 90% by weight or more of bi-nuclear novolak in the presence of an acidic catalyst, the process comprising at first melting the low molecular weight novolak, heating it up to a reaction temperature, then adding 0.001 to 0.05% by weight of the acidic catalyst to the total amount of the low molecular weight novolak and the aralkyl compound, then continuously adding the aralkyl compound for reaction, neutralizing the residual acidic catalyst after the completion of the reaction, a novolak aralkyl resin obtained by the preparation process and a novolak aralkyl resin composition containing said resin.

公开(公告)号：US4366328A

公开(公告)日：1982-12-28

申请号：US97147

申请日：1979-11-26

申请人： Satoshi Numata ,  Kiyoshi Nakatani ,  Noboru Yamazaki ,  Teruo Yuasa

发明人： Satoshi Numata ,  Kiyoshi Nakatani ,  Noboru Yamazaki ,  Teruo Yuasa

IPC分类号： C07C37/52 ,  C07C39/23

CPC分类号： C07C37/52 ,  C07C2102/08

摘要： Indene compounds of the formula ##STR1## wherein X represents a hydrogen atom, a halogen atom, a hydroxyl group or a methyl group, andy is 0 or an integer of 1 to 3,are produced by either heat-decomposing indene compounds of the formula ##STR2## wherein X and y are as defined, in the presence of an acid or alkaline catalyst; or heat-decomposing isopropenyl phenols of the formula ##STR3## wherein X and y are as defined,or oligomers or polymers thereof in the presence of an acid catalyst. 5-Hydroxy-1,1,3-trimethyl-2-indene corresponding to formula (III) is a novel compound.

摘要翻译： 其中X表示氢原子，卤素原子，羟基或甲基，y为0或1〜3的整数的式（III）的茚化合物是通过热分解茚 在酸或碱性催化剂的存在下，其中X和y如上所定义的式（II）的化合物; 或其中X和y如上所定义的式（IV）的热分解异丙烯基酚或其酸催化剂存在下的低聚物或聚合物。 对应于式（III）的5-羟基-1,1,3-三甲基-2-茚是新化合物。