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公开(公告)号：US09296619B2
公开(公告)日：2016-03-29
申请号：US12865679
申请日：2009-01-19
Applicant: Wieslaw Jerzy Roth , Carrie L. Kennedy , Thomas Yorke
Inventor： Wieslaw Jerzy Roth , Carrie L. Kennedy , Thomas Yorke
Abstract: A process for the manufacture of large crystal size synthetic porous crystalline molecular sieve requires an aqueous reaction mixture that is organic structure directing agent-free, has a H2O/MOH molar ratio (M is an alkali metal) of 75 or less, a source of X2O3 (X is a trivalent element) and a source of YO2 (Y is a tetravalent element). The source of X2O3 and YO2 is an amorphous material containing both X2O3 and YO2 and having a YO2/X2O3 molar ratio of 15 to 40. The resultant highly crystalline novel materials have crystals with at least one dimension greater than 1 μm, such as greater than 3 μm.
Abstract translation: 制造大晶体合成多孔结晶分子筛的方法需要一种无机结构导向剂的水性反应混合物，其H 2 O / MOH摩尔比（M为碱金属）为75以下， X 2 O 3（X为三价元素）和YO 2（Y为四价元素）的源。 X 2 O 3和YO 2的源是含有X 2 O 3和YO 2并且YO 2 / X 2 O 3摩尔比为15至40的无定形材料。所得高结晶的新型材料具有至少一个尺寸大于1μm的晶体，例如大于 3μm。
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2.发明授权Molecular sieve composition EMM-13, a method of making and a process of using the same 有权分子筛组合物EMM-13，制备方法及其使用方法公开(公告)号：US08704023B2
公开(公告)日：2014-04-22
申请号：US12999589
申请日：2009-07-15
Applicant: Wieslaw J. Roth , Douglas L. Dorset , Gordon J. Kennedy , Thomas Yorke , Terry Eugene Helton , Prasenjeet Ghosh , Joshi V. Yogesh
Inventor： Wieslaw J. Roth , Douglas L. Dorset , Gordon J. Kennedy , Thomas Yorke , Terry Eugene Helton , Prasenjeet Ghosh , Joshi V. Yogesh
IPC: C07C2/12
CPC classification number: B01J29/7676 , B01J29/70 , B01J29/7038 , B01J29/7276 , B01J29/7476 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C2/66 , C07C2/74 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C15/085 , C07C13/28
Abstract: This disclosure relates to a molecular sieve comprising a framework of tetrahedral atoms bridged by oxygen atoms, the tetrahedral atom framework being defined by a unit cell with atomic coordinates in nanometers shown in Table 3.
Abstract translation: 本公开涉及包含由氧原子桥接的四面体原子的骨架的分子筛，四面体原子框架由具有如表3所示的纳米的原子坐标的单元电池定义。
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3.发明申请Molecular Sieve Composition (EMM-10-P), Its Method of Making, and Use for Hydrocarbon Conversions 有权分子筛组成（EMM-10-P），其制备和用于烃转化的方法公开(公告)号：US20120269718A1
公开(公告)日：2012-10-25
申请号：US13536159
申请日：2012-06-28
Applicant: Wieslaw J Roth , Thomas Yorke , Michael Charles Kerby , Simon C. Weston
Inventor： Wieslaw J Roth , Thomas Yorke , Michael Charles Kerby , Simon C. Weston
IPC: C01B39/48
CPC classification number: C01B39/46 , B01J29/70 , B01J29/7038 , B01J29/7276 , B01J37/0009 , B01J2229/42 , C01B37/02 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , Y02P20/52 , Y10S208/02 , C07C15/085
Abstract: This invention relates to a crystalline molecular sieve having, in its as-synthesized form, an X-ray diffraction pattern including d-spacing maxima at 13.18±0.25 and 12.33±0.23 Angstroms, wherein the peak intensity of the d-spacing maximum at 13.18±0.25 Angstroms is at least as great as 90% of the peak intensity of the d-spacing maximum at 12.33±0.23 Angstroms. This invention also relates to a method of making thereof.
Abstract translation: 本发明涉及一种结晶分子筛，其以其合成形式具有包括在13.18±0.25和12.33±0.23埃处的d间距最大值的X射线衍射图，其中d间距最大值的峰值强度为13.18 ±0.25埃至少高达12.33±0.23埃处d间距最大峰值强度的90％。 本发明还涉及其制备方法。
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公开(公告)号：US20110207983A1
公开(公告)日：2011-08-25
申请号：US12865679
申请日：2009-01-19
Applicant: Wieslaw Jerzy Roth , Carrie L. Kennedy , Thomas Yorke
Inventor： Wieslaw Jerzy Roth , Carrie L. Kennedy , Thomas Yorke
Abstract: A process for the manufacture of large crystal size synthetic porous crystalline molecular sieve requires an aqueous reaction mixture that is organic structure directing agent-free, has a H2O/MOH molar ratio (M is an alkali metal) of 75 or less, a source of X2O3 (X is a trivalent element) and a source of YO2 (Y is a tetravalent element). The source of X2O3 and YO2 is an amorphous material containing both X2O3 and YO2 and having a YO2/X2O3 molar ratio of 15 to 40. The resultant highly crystalline novel materials have crystals with at least one dimension greater than 1 μm, such as greater than 3 μm.
Abstract translation: 制造大晶体合成多孔结晶分子筛的方法需要一种无机结构导向剂的水性反应混合物，其H 2 O / MOH摩尔比（M为碱金属）为75以下， X 2 O 3（X为三价元素）和YO 2（Y为四价元素）的源。 X 2 O 3和YO 2的源是含有X 2 O 3和YO 2并且YO 2 / X 2 O 3摩尔比为15至40的无定形材料。所得高结晶的新型材料具有至少一个尺寸大于1μm的晶体，例如大于 3μm。
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5.发明申请Novel Molecular Sieve Composition EMM-13, A Method of Making and a Process of Using the Same 有权新型分子筛组合物EMM-13，制备方法及其使用方法公开(公告)号：US20110166402A1
公开(公告)日：2011-07-07
申请号：US12999589
申请日：2009-07-15
Applicant: Wieslaw J. Roth , Douglas L. Dorset , Gordon J. Kennedy , Thomas Yorke , Terry Eugene Helton , Prasenjeet Ghosh , Yogesh V. Joshi
Inventor： Wieslaw J. Roth , Douglas L. Dorset , Gordon J. Kennedy , Thomas Yorke , Terry Eugene Helton , Prasenjeet Ghosh , Yogesh V. Joshi
CPC classification number: B01J29/7676 , B01J29/70 , B01J29/7038 , B01J29/7276 , B01J29/7476 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C2/66 , C07C2/74 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C15/085 , C07C13/28
Abstract: This disclosure relates to a molecular sieve comprising a framework of tetrahedral atoms bridged by oxygen atoms, the tetrahedral atom framework being defined by a unit cell with atomic coordinates in nanometers shown in Table 3.
Abstract translation: 本公开涉及包含由氧原子桥接的四面体原子的骨架的分子筛，四面体原子框架由具有如表3所示的纳米的原子坐标的单元电池定义。
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Patent Agency Ranking
6.发明授权Molecular sieve composition (EMM-10), its method of making, and use for hydrocarbon conversions 有权分子筛组成（EMM-10），其制备方法和用于碳氢化合物转化公开(公告)号：US08110176B2
公开(公告)日：2012-02-07
申请号：US11824742
申请日：2007-07-02
Applicant: Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
Inventor： Wieslaw J. Roth , Thomas Yorke , Douglas Lewis Dorset , Mohan Kalyanaraman , Michael Charles Kerby , Simon Christopher Weston
CPC classification number: B01J29/70 , B01J29/7038 , B01J29/7276 , B01J35/002 , B01J2229/18 , B01J2229/20 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C10G29/205 , C10G45/68 , C10G47/02 , C10G49/08 , C10G50/00 , Y10S208/02
Abstract: This invention relates to a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, comprising unit cells with MWW topology, said crystalline molecular sieve is characterized by diffraction streaking from the unit cell arrangement in the c direction. The crystalline molecular sieve is further characterized by the arced hk0 patterns of electron diffraction pattern. The crystalline molecular sieve is further characterized by the unit cells streaking along c direction. This invention also relates to a method of making thereof.
Abstract translation: 本发明涉及以铵交换形式或其煅烧形式的包含具有MWW拓扑结构的单元电池的结晶分子筛，所述结晶分子筛的特征在于沿c方向从单元电池排列衍射衍射。 结晶分子筛的特征还在于电子衍射图案的弧形hk0图案。 结晶分子筛的特征还在于沿c方向分布的单位细胞。 本发明还涉及其制备方法。
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7.发明申请Molecular Sieve Composition (EMM-10-P), Its Method of Making, and Use for Hydrocarbon Conversions 审中-公开分子筛组成（EMM-10-P），其制备和用于烃转化的方法公开(公告)号：US20110190114A1
公开(公告)日：2011-08-04
申请号：US13004991
申请日：2011-01-12
Applicant: Wieslaw J. ROTH , Thomas YORKE , Michael Charles KERBY , Simon C. WESTON
Inventor： Wieslaw J. ROTH , Thomas YORKE , Michael Charles KERBY , Simon C. WESTON
CPC classification number: C01B39/46 , B01J29/70 , B01J29/7038 , B01J29/7276 , B01J37/0009 , B01J2229/42 , C01B37/02 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , Y02P20/52 , Y10S208/02 , C07C15/085
Abstract: This invention relates to a crystalline molecular sieve having, in its as-synthesized form, an X-ray diffraction pattern including d-spacing maxima at 13.18±0.25 and 12.33±0.23 Angstroms, wherein the peak intensity of the d-spacing maximum at 13.18±0.25 Angstroms is at least as great as 90% of the peak intensity of the d-spacing maximum at 12.33±0.23 Angstroms. This invention also relates to a method of making thereof.
Abstract translation: 本发明涉及一种结晶分子筛，其以其合成形式具有包括在13.18±0.25和12.33±0.23埃处的d间距最大值的X射线衍射图，其中d间距最大值的峰值强度为13.18 ±0.25埃至少高达12.33±0.23埃处d间距最大峰值强度的90％。 本发明还涉及其制备方法。
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8.发明申请Molecular sieve composition (EMM-10), its method of making, and use for hydrocarbon conversions 有权分子筛组成（EMM-10），其制备方法和用于碳氢化合物转化公开(公告)号：US20080027256A1
公开(公告)日：2008-01-31
申请号：US11824742
申请日：2007-07-02
Applicant: Wieslaw Roth , Thomas Yorke , Douglas Dorsei , Mohan Kalyanaraman , Michael Kerby , Simon Weston
Inventor： Wieslaw Roth , Thomas Yorke , Douglas Dorsei , Mohan Kalyanaraman , Michael Kerby , Simon Weston
CPC classification number: B01J29/70 , B01J29/7038 , B01J29/7276 , B01J35/002 , B01J2229/18 , B01J2229/20 , C01B39/48 , C07C2/66 , C07C2/864 , C07C4/06 , C07C5/02 , C07C5/10 , C07C5/412 , C07C5/52 , C07C7/13 , C07C2529/70 , C07C2529/72 , C07C2529/74 , C10G29/205 , C10G45/68 , C10G47/02 , C10G49/08 , C10G50/00 , Y10S208/02
Abstract: This invention relates to a crystalline molecular sieve, in its ammonium exchanged form or in its calcined form, comprising unit cells with MWW topology, said crystalline molecular sieve is characterized by diffraction streaking from the unit cell arrangement in the c direction. The crystalline molecular sieve is further characterized by the arced hk0 patterns of electron diffraction pattern. The crystalline molecular sieve is further characterized by the unit cells streaking along c direction. This invention also relates to a method of making thereof.
Abstract translation: 本发明涉及以铵交换形式或其煅烧形式的包含具有MWW拓扑结构的单元电池的结晶分子筛，所述结晶分子筛的特征在于沿c方向从单元电池排列衍射衍射。 结晶分子筛的特征还在于电子衍射图案的弧形hk0图案。 结晶分子筛的特征还在于沿c方向分布的单位细胞。 本发明还涉及其制备方法。
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9.发明申请Novel Molecular Sieve Composition EMM-12, A Method of Making and a Process of Using the Same 有权新型分子筛组合物EMM-12，制备方法及其使用方法公开(公告)号：US20110166401A1
公开(公告)日：2011-07-07
申请号：US12999585
申请日：2009-07-15
Applicant: Wieslaw J Roth , Douglas Dorset , Gordon Kennedy , Thomas Yorke , Terry Eugene Bethlehem
Inventor： Wieslaw J Roth , Douglas Dorset , Gordon Kennedy , Thomas Yorke , Terry Eugene Bethlehem
CPC classification number: B01J29/70 , B01J29/7038 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C2/66 , C07C6/123 , C07C6/126 , C07C29/36 , C07C37/11 , C07C37/20 , C07C41/06 , C07C45/53 , C07C51/235 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/14 , C07C2523/02 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C15/107 , C07C33/20 , C07C39/06 , C07C39/16 , C07C43/04 , C07C49/10 , C07C57/30
Abstract: This disclosure relates to an EMM-12 molecular sieve having, in its as-synthesized form and in calcined form, an X-ray diffraction pattern including peaks having a d-spacing maximum in the range of 14.17 to 12.57 Angstroms, a d-spacing maximum in the range of 12.1 to 12.56 Angstroms, and non-discrete scattering between about 8.85 to 11.05 Angstroms or exhibit a valley in between the peaks having a d-spacing maximum in the range of 10.14 to 12.0 Angstroms and a d-spacing maximum in the range from 8.66 to 10.13 Angstroms with measured intensity corrected for background at the lowest point being not less than 50% of the point at the same XRD d-spacing on the line connecting maxima in the range of 10.14 to 12.0 Angstroms and in the range from 8.66 to 10.13 Angstroms
Abstract translation: 本公开涉及一种EMM-12分子筛，其以其合成形式和煅烧形式具有X射线衍射图，其包括d-间距最大值在14.17至12.57埃范围内的峰，d-间距 在12.1至12.56埃的范围内的最大值，以及在约8.85至11.05埃之间的非离散散射，或在具有10.14至12.0埃范围内的d间距最大值的峰之间呈现出谷值， 在最低点处校正背景的测量强度的8.66至10.13埃的范围不小于连接最大值在10.14至12.0埃范围内的线上的相同XRD d间距处的点的50％ 从8.66到10.13埃
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公开(公告)号：US20090041658A1
公开(公告)日：2009-02-12
申请号：US11891408
申请日：2007-08-10
Applicant: Wieslaw J. Roth , Thomas Yorke
Inventor： Wieslaw J. Roth , Thomas Yorke
IPC: C01B39/02
CPC classification number: C01B39/46 , B01D53/02 , B01D53/261 , B01D2253/108 , B01J20/18 , B01J29/70
Abstract: The crystalline molecular sieve material EMM-7 has, in its as-synthesized form, an X-ray diffraction pattern including d-spacing maxima substantially as set forth in Table 1: TABLE 1 Interplanar d-Spacing (Å)Relative Intensity, I/Io × 100 8.40 ± 0.2w-m 6.80 ± 0.2w-s 4.46 ± 0.1m-s 3.73 ± 0.1m-s 3.68 ± 0.1m-s 3.40 ± 0.1 s-vs wherein “vs” means very strong (greater than 60 to 100), “s” means strong (greater than 40 to 60), “m” means medium (greater than 20 to 40) and “w” means weak (0 to 20).
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